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Proceedings e report - Firenze University Press

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4. Conclusions<br />

chrome yellow<br />

WOOD SCIENCE FOR CONSERVATION OF CULTURAL HERITAGE<br />

mars red<br />

minium<br />

raw Sienna<br />

0 2 4 6<br />

dE CMC<br />

Fig. 2. Colour shift over time (1 year) for samples (B)<br />

The agreement of the two inter-compared spectrophotometers is depending on the uniformity of the<br />

samples, but even for some samples of bad uniformity as Solferino lake the agreement is good in total<br />

colour differences values. Regarding the effect of irradiation on the colour of samples (A), total colour<br />

differences are lower than 5 dE* units (i.e. small colour differences) except cobalt blue, ochre yellow,<br />

and rabbit-skin glue.<br />

The influence of irradiation on the colour shift over time of samples (B) is specific for the type of<br />

sample and it is only quantitative in terms of lightness, chroma and hue. The colour shift increases<br />

with the dose ratio and it is not influenced by varnish except samples prepared with raw Sienna.<br />

Acknowledgments<br />

Acknowledgments are due to COST Action IE0601 for the STSM of M.Cutrubinis at ARC-Nucléart<br />

by which the collaboration was possible.<br />

References<br />

1. Tiano, P.: “Biodegradation of Cultural Heritage: Decay Mechanisms and Control Methods”.<br />

http://www.arcchip.cz/w09/w09_tiano.pdf.<br />

2. HunterLab (2008): Maximizing Inter-instrument Agreement.<br />

http://www.hunterlab.com/appnotes/an06_05.pdf.<br />

3. Brainard, D.H. (2003): “Color appearance and Color Difference Specification”. In Shevell, S.K.<br />

(Ed.), “The Science of Color (2 nd edition)”. Oxford UK: Elsevier.<br />

4. ISO 105 Part J03 (2006): Calculation of colour differences.<br />

5. Rizzo M.M., Machado L.D.B., Borrely S.I., Sampa M.H.O., Rela P.R., Farah J.P.S., Schumacher<br />

R.I. (2002): Effects of gamma rays on a restored painting from the XVIIth century. Rad Phys<br />

Chem. 63 (3-6): 259-262.<br />

6. Negut, D.C., Ponta, C.C., Georgescu, R.M., Moise, I.V., Niculescu, Gh., Lupu, A.I.M. (2007):<br />

Effects of gamma irradiation on the colour of pigments. Proc. of SPIE Vol. 6618: 66180R1-10.<br />

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