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Proceedings e report - Firenze University Press

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SORPTION OF MOISTURE AND DIMENSIONAL CHANGE OF WOOD SPECIES USED IN HISTORIC OBJECTS<br />

The three parameter sigmoid function was used to interpret the individual swelling and shrinkage data:<br />

n<br />

EMC<br />

dEMC ( ) = dmax<br />

(2)<br />

n n<br />

k + EMC<br />

where EMC is the equilibrium amount of water vapour sorbed, d the relative dimensional change at a<br />

given EMC and dmax reflects the maximum dimensional change for wood saturated with water.<br />

The function shows an early exponential growth at low EMC, then slows to a linear growth for the<br />

broad medium part between approximately 5-15%, and then approaches a constant value as the<br />

capillary system of wood is saturated with water. The dimensional change coefficients were<br />

determined by the linear fit across the linear range of the plots and are given in Table 1.<br />

5. Conclusions<br />

In addition to individual sorptive characteristics and dimensional responses of wood species,<br />

constituting cultural heritage objects, ‘general’ moisture sorption and swelling/shrinkage patterns<br />

which would apply as a first approximation to any wooden furnishings and collections were proposed.<br />

They were obtained from the experimental data measured for 21 historically important wood species<br />

used in the past for panel paintings and woodcarving. Information on further wood species of interest<br />

to the wood conservation community can be added to the database and used to constantly improve the<br />

general relationships.<br />

Acknowledgements<br />

A substantial part of this research was done within the project ‘Sensor systems for detection of<br />

harmful environments in pipe organs’ (SENSORGAN), supported financially by the European<br />

Commission 6th Framework Programme.<br />

References<br />

1. Grosser, D. and Geier, E. (1975): Die in der Tafelmalerei und Bildschnitzerei verwendeten<br />

Holzarten und ihre Bestimmung nach mikroskopischen Merkmalen. Teil 1. Nadelhölzer.<br />

Maltechnik/Restauro: 127-148.<br />

2. Grosser, D. and Grässle, E. (1976): Die in der Tafelmalerei und Bildschnitzerei verwendeten<br />

Holzarten und ihre Bestimmung nach mikroskopischen Merkmalen. Teil 2. Die Europäische<br />

Laubhölzer. Maltechnik/Restauro: 40-54.<br />

3. Sing, K.S.W., Everett, D.H., Haul, R.A.W., Moscou, L., Pierotti, R.A., Rouquerol, J., and<br />

Siemieniewska, T. (1985): Reporting physisorption data for gas solid systems with special<br />

reference to the determination of surface area and porosity. Pure and Applied Chemistry. 57: 603-<br />

619.<br />

4. Timmermann, E.O. (2003): Multilayer sorption parameters: BET or GAB values? Colloids and<br />

Surfaces A: Eng Aspects. 220: 235-260.<br />

5. Hartley, I.D. (2000): Application of the Guggenheim-Anderson-de Boer sorption isotherm model<br />

to Klinki pine (Araucaria klinkii Lauterb.). Holzforschung. 54: 661-663.<br />

6. Chauhan, S.S. and Aggarwal, P. (2004): Effect of moisture sorption state on transverse<br />

dimensional changes in wood. Holz Roh Werkstoff. 62: 50-55.<br />

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