Characterization and control of the fiber-matrix interface in ceramic ...
Characterization and control of the fiber-matrix interface in ceramic ...
Characterization and control of the fiber-matrix interface in ceramic ...
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CWCTERIZATION AND CONTROL OF THE FIBER-MATRIX INTERFACE<br />
IN CERAMIC MATRIX COMPOSITE?<br />
R. A. Lowden<br />
ABSTRACT<br />
Fiber-re<strong>in</strong>forced Sic composites fabricated by <strong>the</strong>rmal-gradient<br />
forced-flow chemical-vapor <strong>in</strong>filtration (FCVI) have exhibited both<br />
composite (toughened) <strong>and</strong> brittle behavior dur<strong>in</strong>g meehanlcal property<br />
evaluation. Detailed analysis <strong>of</strong> <strong>the</strong> <strong>fiber</strong>-<strong>matrix</strong> <strong><strong>in</strong>terface</strong> revealed<br />
that a silica layer on <strong>the</strong> surface <strong>of</strong> Nicalon Si-C-0 <strong>fiber</strong>s ti.ghtly<br />
bonds <strong>the</strong> <strong>fiber</strong> to <strong>the</strong> <strong>matrix</strong>. The strongly bonded <strong>fiber</strong> <strong>and</strong> <strong>matrix</strong>,<br />
comb<strong>in</strong>ed wi.th <strong>the</strong> reduction <strong>in</strong> <strong>the</strong> strength <strong>of</strong> <strong>the</strong> <strong>fiber</strong>s that occurs<br />
dur<strong>in</strong>g process<strong>in</strong>g, resulted <strong>in</strong> <strong>the</strong> observed brittle behavior.<br />
The mechanical behavior <strong>of</strong> Nical.on/SiC composites has been<br />
improved by apply<strong>in</strong>g th<strong>in</strong> coat<strong>in</strong>gs to <strong>the</strong> <strong>fiber</strong>s, prior to<br />
densification, to <strong>control</strong> <strong>the</strong> <strong>in</strong>terfacial bond. Vary<strong>in</strong>g degrees <strong>of</strong><br />
bond<strong>in</strong>g have been achieved with different coat<strong>in</strong>g materials <strong>and</strong> film<br />
thicknesses.<br />
Fiber-<strong>matrix</strong> bond strengths have been quantitatively<br />
evaluated us<strong>in</strong>g an <strong>in</strong>dentation method <strong>and</strong> a simple tensile test.<br />
The<br />
effects <strong>of</strong> bond<strong>in</strong>g <strong>and</strong> friction on <strong>the</strong> mechanical behavior <strong>of</strong> this<br />
composite system have been <strong>in</strong>vestigated.<br />
Fiber coat<strong>in</strong>gs not only weaken <strong>the</strong> <strong>fiber</strong>-<strong>matrix</strong> bond, <strong>in</strong>creas<strong>in</strong>g<br />
toughness, but can protect <strong>the</strong> <strong>fiber</strong>s from chemical attack <strong>and</strong> h<strong>in</strong>der<br />
*Research sponsored by <strong>the</strong> U. S . Department <strong>of</strong> Energy, AR&TD<br />
Fossil Energy Materials Program [DOE/FE AA 15 10 10 0, Work Breakdown<br />
Structure Element ORNL-l(c)] under contract DE-AC05-840K21400 with<br />
Mart<strong>in</strong> Marietta Energy Systems, Inc,<br />
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