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Characterization and control of the fiber-matrix interface in ceramic ...

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40<br />

In <strong>the</strong> analysis <strong>of</strong> <strong>the</strong> mechanical relationships that <strong>control</strong> <strong>the</strong><br />

performance <strong>of</strong> <strong>fiber</strong>-re<strong>in</strong>forced materials, it was assumed that a perfect<br />

bond exists between <strong>the</strong> <strong>fiber</strong> re<strong>in</strong>forcement <strong>and</strong> <strong>matrix</strong>. The condition<br />

ensures complete load transfer <strong>in</strong> <strong>the</strong> system <strong>and</strong> simplifies <strong>the</strong><br />

calculations. The formulations <strong>in</strong>dicate that a high ratio <strong>of</strong> <strong>fiber</strong> to<br />

<strong>matrix</strong> Young’s modulus, Ef/Em, is desirable for <strong>ceramic</strong> <strong>matrix</strong><br />

composites, where <strong>the</strong> <strong>matrix</strong> has <strong>the</strong> lower ultimate stra<strong>in</strong>. As noted<br />

earlier, <strong>the</strong> moduli <strong>of</strong> <strong>the</strong> components <strong>of</strong> <strong>ceramic</strong>-<strong>ceramic</strong> composites are<br />

much closer than <strong>in</strong> polymer- <strong>and</strong> metal-<strong>matrix</strong> systems; <strong>the</strong>refore, it is<br />

obvious that <strong>the</strong>se expressions do not real-istically expla<strong>in</strong> <strong>the</strong> behavior<br />

<strong>of</strong> many brittle <strong>matrix</strong> composites.<br />

It has been demonstrated that <strong>the</strong><br />

failure stra<strong>in</strong> <strong>of</strong> <strong>the</strong> <strong>matrix</strong> can be <strong>in</strong>creased by <strong>the</strong> addition <strong>of</strong> <strong>fiber</strong><br />

re<strong>in</strong>forcement <strong>and</strong> that <strong>matrix</strong> fracture does not necessarily constitute<br />

<strong>the</strong> upper limit <strong>of</strong> load capacity <strong>of</strong> <strong>the</strong> composite.<br />

The range <strong>in</strong> which <strong>the</strong> l<strong>in</strong>ear representations for stress <strong>and</strong> stra<strong>in</strong><br />

are accurate is limited by <strong>the</strong> condition <strong>of</strong> <strong>matrix</strong> fracture. The first<br />

deviation from l<strong>in</strong>ear behavior occurs immediately upon <strong>matrix</strong> failure,<br />

<strong>and</strong> beyond <strong>the</strong> po<strong>in</strong>t <strong>of</strong> <strong>matrix</strong> fracture, <strong>the</strong> mechanical behavior <strong>of</strong> a<br />

composite is governed by <strong>the</strong> properties <strong>of</strong> <strong>the</strong> <strong>fiber</strong>s <strong>and</strong> by <strong>the</strong> adhesion<br />

<strong>and</strong> frictional stresses at <strong>the</strong> fi-ber-<strong>matrix</strong> <strong><strong>in</strong>terface</strong> (Figures 6.2 <strong>and</strong><br />

6.3). The effect <strong>of</strong> <strong>the</strong> <strong>fiber</strong>-matrx bond on <strong>the</strong> failure stra<strong>in</strong> <strong>of</strong> <strong>the</strong><br />

<strong>matrix</strong> <strong>in</strong> a composite has been exam<strong>in</strong>ed. Aveston, Cooper, <strong>and</strong> Kelly<br />

(81,82) developed a model relat<strong>in</strong>g <strong>the</strong> failure stra<strong>in</strong> <strong>of</strong> <strong>the</strong> <strong>matrix</strong> to<br />

material <strong>and</strong> composite parameters.<br />

The ACK (Aveston, Cooper, <strong>and</strong>. Kelly) model is based on energetics<br />

<strong>and</strong> employs an energy balance to predict <strong>the</strong> po<strong>in</strong>t <strong>of</strong> <strong>matrix</strong> failure

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