Characterization and control of the fiber-matrix interface in ceramic ...
Characterization and control of the fiber-matrix interface in ceramic ...
Characterization and control of the fiber-matrix interface in ceramic ...
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<strong>fiber</strong>-<strong>matrix</strong> bond<strong>in</strong>g; thus, a fundamental underst<strong>and</strong><strong>in</strong>g <strong>of</strong> <strong>the</strong> <strong>fiber</strong><strong>matrix</strong><br />
<strong><strong>in</strong>terface</strong> is necessary to design <strong>and</strong> produce composites that<br />
possess <strong>the</strong> optimum comb<strong>in</strong>ation <strong>of</strong> strength <strong>and</strong> fracture resistance.<br />
The study <strong>of</strong> <strong><strong>in</strong>terface</strong>s is not limited to <strong>the</strong> mechanical aspects,<br />
but is <strong>in</strong>terdiscipl<strong>in</strong>ary, a comb<strong>in</strong>ation <strong>of</strong> materials evaluation <strong>and</strong><br />
mechanical relationships.<br />
A practical correlation relat<strong>in</strong>g <strong><strong>in</strong>terface</strong>s to<br />
composite properties is impossible without an underst<strong>and</strong><strong>in</strong>g <strong>of</strong> <strong>the</strong><br />
mechanical, physical, <strong>and</strong> chemical <strong>in</strong>teractions that are present <strong>in</strong> a<br />
given system.<br />
Chemical, physical, <strong>and</strong> mechanical bond<strong>in</strong>g are present at<br />
<strong>the</strong> <strong><strong>in</strong>terface</strong>s <strong>in</strong> all composite systems.<br />
These factors comb<strong>in</strong>ed with <strong>the</strong><br />
mechanical properties <strong>of</strong> <strong>the</strong> <strong>in</strong>dividual components can be used to expla<strong>in</strong><br />
<strong>the</strong> observed behavior <strong>of</strong> A rnulticomponcnt composite material.<br />
6.2 Role <strong>of</strong> tk!e Interface<br />
The mechanical properties <strong>of</strong> filamentary composites are <strong>in</strong>fluenced<br />
strongly by <strong>the</strong> <strong>fiber</strong>-<strong>matrix</strong> <strong><strong>in</strong>terface</strong>.<br />
The <strong>in</strong>terfacial bond affects<br />
<strong>matrix</strong>-crack<strong>in</strong>g <strong>and</strong> composite-fracture behavior (57,78-80).<br />
For<br />
composites hav<strong>in</strong>g a very strong <strong>in</strong>terfacial bond, a crack propagat<strong>in</strong>g <strong>in</strong><br />
<strong>the</strong> <strong>matrix</strong> will pass undisturbed through <strong>the</strong> <strong>fiber</strong>s <strong>and</strong> <strong>the</strong> composite<br />
will fail <strong>in</strong> a brittle manner, much <strong>the</strong> same as <strong>the</strong> unre<strong>in</strong>forced <strong>matrix</strong><br />
material does (Figure 6.1).<br />
For composi.tes hav<strong>in</strong>g poorly bonded<br />
<strong><strong>in</strong>terface</strong>s, <strong>the</strong> fracture process beg<strong>in</strong>s progressively with debond<strong>in</strong>g at:<br />
<strong>the</strong> <strong>fiber</strong>-<strong>matrix</strong> <strong><strong>in</strong>terface</strong>, followed by subsequent <strong>matrix</strong> failure, <strong>fiber</strong><br />
slip <strong>and</strong> pull-out, <strong>and</strong> f<strong>in</strong>ally, <strong>fiber</strong> failure (81,82). These energyabsorb<strong>in</strong>g<br />
mechanisms all contribute to improve fracture toughness <strong>and</strong> are<br />
<strong>control</strong>led by <strong>the</strong> strength <strong>of</strong> <strong>the</strong> <strong>fiber</strong>-<strong>matrix</strong> bond.