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Characterization and control of the fiber-matrix interface in ceramic ...

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11<br />

isostatic press<strong>in</strong>g (HIP), can be applied to more complex geometries with<br />

comparable results. Hot press<strong>in</strong>g is ideal for <strong>the</strong> fabrication <strong>of</strong> short<strong>fiber</strong><br />

or whisker-re<strong>in</strong>forced <strong>ceramic</strong>s (such as <strong>the</strong> Sic-re<strong>in</strong>forced alum<strong>in</strong>a)<br />

<strong>and</strong> unidirectional lay-ups, but it is expensive. Its application to<br />

multidimensional cont<strong>in</strong>uous-<strong>fiber</strong>-re<strong>in</strong>forced composites is also limited;<br />

<strong>the</strong>refore, o<strong>the</strong>r techniques for <strong>the</strong> fabrication <strong>of</strong> <strong>fiber</strong>-re<strong>in</strong>forced<br />

<strong>ceramic</strong> composites have been explored.<br />

3.3 S<strong>in</strong>ter<strong>in</strong>g<br />

Alternative powder-process<strong>in</strong>g techniques <strong>in</strong>corporate a form<strong>in</strong>g step<br />

<strong>and</strong> a subsequent s<strong>in</strong>ter<strong>in</strong>g/fir<strong>in</strong>g densification stage. "Greenware"<br />

preforms are fabricated by cold press<strong>in</strong>g, slip cast<strong>in</strong>g, or extrud<strong>in</strong>g a<br />

<strong>fiber</strong>-powder-b<strong>in</strong>der mixture or slurry. The b<strong>in</strong>ders are removed by lowtemperature<br />

heat treatments, <strong>and</strong> <strong>the</strong> components are consolidated by<br />

fir<strong>in</strong>g to high temperatures.<br />

The major disadvantage <strong>of</strong> <strong>the</strong>se processes<br />

is <strong>the</strong> large degree <strong>of</strong> shr<strong>in</strong>kage that occurs dur<strong>in</strong>g s<strong>in</strong>ter<strong>in</strong>g. The<br />

shr<strong>in</strong>kage produces cracks <strong>and</strong> porosity <strong>in</strong> <strong>the</strong> composite <strong>matrix</strong>, result<strong>in</strong>g<br />

<strong>in</strong> poor properties.<br />

The high s<strong>in</strong>ter<strong>in</strong>g temperatures can also damage <strong>the</strong><br />

<strong>fiber</strong> re<strong>in</strong>forcement.<br />

3.4 Unconventional Techniques<br />

Most <strong>of</strong> <strong>the</strong> aforementioned fabricatLon techniques are more suited to<br />

short <strong>fiber</strong>s or whiskers than to cont<strong>in</strong>uous <strong>fiber</strong>s OK filaments. Many<br />

composites processed us<strong>in</strong>g <strong>the</strong> methods described here<strong>in</strong> have exhibited<br />

iqroved mechanical behavior over monolithic <strong>ceramic</strong>s, but <strong>the</strong> processes<br />

are not easily adaptable to <strong>the</strong> manufacture <strong>of</strong> cont<strong>in</strong>uous-<strong>fiber</strong><br />

composites. The form<strong>in</strong>g <strong>and</strong> press<strong>in</strong>g steps cannot be used for large

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