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EN and Oxidation Number (O.N.)<br />

Delta EN vs Bond Type<br />

For example in NaCl (Sodium Chloride or table salt), Cl is more electronegative (EN = 3.0) than Na<br />

(EN = 0.9). Therefore, according to the rules above, we assign both (2) shared electrons to Cl and<br />

0 shared electrons to Na.<br />

Cl has 7 valence electrons and 6 unshared electrons in its outer shell. Na has 1 valence electron<br />

and 0 unshared electrons in its outer shell.<br />

Using the equation above for Cl: O.N. = 7-(2+6) = 7-8 = -1. Using the equation above for Na: O.N.<br />

= 1-(0-0) = 1-0 = +1.<br />

Delta EN and Bond Type<br />

When you look at a bond between any two elements X and Y and ask "Is the X-Y bond ionic or<br />

covalent?", the answer in almost every case is "Partly Ionic and Partly Covalent".<br />

The partial-ionic/partial-covalent character of any given bond X-Y is directly related to the<br />

Electronegativity Difference (Delta EN), which is the arithmetic difference between the EN values<br />

of X and Y.<br />

The relationship between Delta EN and Bond Type is shown in the picture below.<br />

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