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Evaluation and Repair of Wrought Iron and - Purdue e-Pubs ...

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78strength from the existence <strong>of</strong> pearlite is negligible. Carbon in wrought iron typicallyexists as fine precipitates <strong>of</strong> iron carbide, or cementite intermixed with the ferrite(Gordon,1988). This is because the wrought iron was never fully heated to a liquid formduring the manufacturing process, <strong>and</strong> so the carbon is not heated fully enough to formpearlite.The dark, elongated areas in the micrograph in Figure 4.1 are inclusions whichconsist <strong>of</strong> a variety <strong>of</strong> impurities like phosphorous, sulfur or silicon. The majority <strong>of</strong>these impurities are iron silicate <strong>and</strong> other oxides which are commonly grouped together<strong>and</strong> known as slag. The slag was intertwined into the microstructure <strong>of</strong> the wrought ironduring the manufacturing process where the molten slag was used to help heat the ironore. Most <strong>of</strong> the molten slag was squeezed out <strong>of</strong> the material during rolling <strong>of</strong> thewrought iron into the eyebar shape.The slag inclusions that remained in the material were typically elongated <strong>and</strong>extended along only one direction in the material. These inclusions were larger thaninclusions that are typically found in other metals such as steel. Some <strong>of</strong> these inclusionsare large enough to be seen with the naked eye. Figure 4.2 shows a typical largeinclusion found throughout the material.Figure 4.3 is a photograph <strong>of</strong> a micrograph taken <strong>of</strong> the scrap piece <strong>of</strong> steel. Thismicrograph was used to compare the microstructure <strong>of</strong> the historic wrought iron to that <strong>of</strong>a common structural steel. The micrograph <strong>of</strong> the steel indicated that steel consisted <strong>of</strong> asmaller grain structure than wrought iron. It also shows a mixture <strong>of</strong> ferrite, pearlite <strong>and</strong>impurities that create the microstructure <strong>of</strong> steel. The impurities, or inclusions in the steelwere much smaller <strong>and</strong> more distributed, unlike the inclusions in wrought iron.The addition <strong>of</strong> carbon in the form <strong>of</strong> pearlite increases the strength <strong>and</strong> ductility<strong>of</strong> pure iron to form steel. Since the composition <strong>of</strong> wrought iron consists mainly <strong>of</strong>ferrite with widely dispersed areas <strong>of</strong> cementite <strong>and</strong> impurities, the mechanical properties

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