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THESISPRESENTED ATNATIONAL GRADUATE
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As the human civilization progress
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CHAPTER - 1 SELF-HEALING POLYMERIC
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8.1.5 Atomic Force Microscopy …
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Synthetic engineering materials in
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esponse to a specific external stim
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The first work based on this approa
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een prepared from urea-formaldehyde
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monomer systems. The addition of EN
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Figure - 1.10: Self-healing process
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was required to reach healing effic
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In addition to above works, some ot
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that have been identified to be tak
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part of the chapter, these material
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Figure - 1.17: Self-healing of the
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commercialized under tradenames; Nu
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joined together at temperature high
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Inspired by these findings, the fir
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temperature greater than 80 o C in
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Figure - 1.27: Sulfur chemistry bas
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A different kind of sulfur chemistr
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Figure - 1.29: Dynamic covalent che
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cracks. The recovered droplets afte
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23 White, S. R. et al. Autonomic he
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65 Taber, D. F. & Frankowski, K. J.
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107 Kushner, A. M., Vossler, J. D.,
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148 Park, J. S., Kim, H. S. & Hahn,
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The value of subscripts “n”,
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The formation of spherical micelles
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the micelle assembly showed the pre
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gain onto the electrodes by buildin
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The resistance R can be further exp
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empty-tower velocity U only depends
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This apparent morphological switchi
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In a further qualitative analysis,
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noteworthy and though its feasibili
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Furthermore within this range, lowe
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Figure - 2.22: Scanning Electron Mi
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While the resistance measurements g
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In conclusion, a self-healing membr
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23 Giacomelli, F. C., Riegel, I. C.
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micelles enabled the membrane to se
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The second class is represented by
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To avoid the probable clogging of t
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181614SP2 - iNumber of Particles121
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1000900800y = 3E+06xR² = 0,9911y =
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very high value of 1.5 g.l -1 . Thi
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Since the only change in the membra
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100Retention (%)8060400,100,20,40,6
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Figure - 3.18: Scanning Electron Mi
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(Figure - 3.20). A cursory look at
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When compared to poly(styrene) NPs,
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Figure - 3.24: Scanning Electron Mi
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REFERENCES1 Metzler, R. & Klafter,
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46 Bemporad, D., Luttmann, C. & Ess
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In this chapter, preparation of 3D
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