13.07.2015 Views

Technical Report for the Maricunga Gold Mine - Kinross Gold

Technical Report for the Maricunga Gold Mine - Kinross Gold

Technical Report for the Maricunga Gold Mine - Kinross Gold

SHOW MORE
SHOW LESS
  • No tags were found...

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

<strong>Kinross</strong> <strong>Gold</strong> Corporation<strong>Maricunga</strong> <strong>Mine</strong> <strong>Technical</strong> <strong>Report</strong>is removed by thickening and filtration. The HCN solution is <strong>the</strong>n neutralized with lime orcaustic soda, prior to recycling to leach.The overall chemical reactions applied to Cu, Zn and Ag cyanide complexes are:2Cu(CN) 32-+ S 2- + 6H + → Cu 2 S + 6HCN2Ag(CN) 2-Zn(CN) 42-+ S 2- + 4H + → Ag 2 S + 4HCN+ S 2- + 4H + → ZnS + 4HCNThe above sulphidization reactions occur rapidly in a first stage (primary) precipitationreactor from which sulphide precipitates are fed to a thickener. Recycle of thickened slurry ofsulphide precipitates back to <strong>the</strong> reactor is done until a suitable precipitate particle sizedevelops and sufficient bed depth in <strong>the</strong> thickener is achieved. A precipitate slurry of 10 –15% solids may <strong>the</strong>n be drawn off <strong>the</strong> thickener underflow and washed, filtered and dried.The Cu 2 S precipitate (with Zn, Ni and o<strong>the</strong>r metal sulphides, if present) is <strong>the</strong>n sold to asmelter as a valuable co-product.A second reactor is used to neutralize <strong>the</strong> aqueous HCN in <strong>the</strong> thickener overflow from pH 5back to pH 10. Lime or caustic soda may be used to produce CaCN 2 or NaCN <strong>for</strong> recycle to<strong>the</strong> heap or tank leaching circuit. The neutralization reactions are:2HCN + Ca(OH) 2→ CaCN 2 + H 2 O2HCN + NaOH → NaCN + H 2 OAll three process units (2 reactors and a thickener) are sealed and have vents to a limescrubber system to capture any evolved HCN or H 2 S gases. By acidifying with sulphuric acidin <strong>the</strong> primary reactor, <strong>the</strong> SART process leads to <strong>for</strong>mation of a gypsum type precipitate onneutralization of HCN in <strong>the</strong> neutralization reactor. This gypsum precipitate needs to beremoved from <strong>the</strong> neutralized CN solution prior to recovery of gold on carbon and recycle ofbarren CN solution to <strong>the</strong> leach circuit. To achieve this, a gypsum thickener is included in <strong>the</strong>circuit with <strong>the</strong> option of recycling <strong>the</strong> gypsum thickener underflow to enhance precipitationrates and settling / consolidation in <strong>the</strong> thickener.The SART process may be applied to pregnant gold solutions prior to carbon adsorption oron barren solutions after carbon adsorption. For a heap leach operation <strong>the</strong> inherent leach75

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!