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PP-II-10In Figure 1 is shown the CO conversion for 1%CO, 60%H 2 for different λ-vales.Figure 1: CO conversion for λ=1 (filled symbol) and λ=2 (open symbol).References:1 Son, I.H, Lane, A.M. (2001) Catal. Lett. 76, 3-4, 151-154.2 Kahlich, M.J., Gasteiger, H.A., Behm, R.J. (1997) J. Catal. 171, 93-105.3 Avgouropoulos, G., Ioannides, T, Papadopoulou, C, Batista, J, Hocevar S, Matralis, HK. (2002)Catal Today 75, 1574 Haruta, M, Kobayashi, T, Sano, H, Yamada, N. (1987) Chem Lett 2, 405.180
PP-II-11CATALYTIC PERFORMANCE OF COPPER CERRIUM OXIDE SYSTEMS FORTHE HYDROGEN PRODUCTION REACTIONSBadmaev S.D. 1 , Gulyaev R.V. 1, 2 , Snytnikov P.V. 1, 2 , Koscheev S.V. 1 , Volkova G.G. 1 ,Venyaminov S.A. 1 , Belyaev V.D. 1 , Boronin A.I. 1, 2 , Sobyanin V.A. 1, 21 Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia2 Novosibirsk State University, Novosibirsk, RussiaE-mail: pvsnyt@catalysis.ruCopper-cerium oxide systems have been studied as the catalysts for the reactions ofmethanol steam reforming and dimethyl ether steam reforming to hydrogen-rich gas mixtures.Hydrogen and carbon dioxide were the main reaction products, the CO content wasinsignificant. To provide CO cleanup to 10 ppm – a fuel cell tolerable level - the reaction ofpreferential CO oxidation has been used. Copper-cerium oxide catalysts were used for thisreaction as well.Based on the results obtained, the nature of active centers, reaction mechanisms andpotentials of cupper-cerium oxide catalysts for hydrogen production in two-stage reactorshave been discussed.Recently, copper-cerium oxide systems have been proved to be efficient catalysts fornumerous reactions and processes including fuel reforming to hydrogen-rich gas for fuel cellapplications.This report presents the results on the development and studies of cupper-cerium mixedoxide catalysts prepared by various methods for dimethyl ether steam reforming, methanolsteam reforming and preferential oxidation of carbon monoxide in hydrogen-rich gasmixtures. The catalyst performance was studied in a flow setup with on-line chromatographicanalysis of the reaction products. The dependencies of the catalyst performance on thetemperature, inlet composition and feed rate of the gas mixture have been determined. Theexperiments on dimethyl ether steam reforming and methanol steam reforming wereperformed at GHSV = 5000 ÷ 20000 h -1 and temperature 150-400 o С; experiments on COpreferential oxidation - at GHSV = 5000 ÷ 60000 h -1 and temperature 50 ÷ 250 о С.The fresh and spent cupper-cerium oxide systems were characterized by means of TPR,TPO, TPD, XRD, XPS and TEM techniques. The FTIR spectroscopy in situ was applied fordetailed characterization of the functioning catalysts.In our experiments, copper-cerium oxide catalysts showed excellent performance for thereaction of methanol steam reforming. At low temperatures (200-250 °C), the main reactionproducts were hydrogen and carbon dioxide. 100 % methanol conversion was achieved at181
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"Catalysis is not a branch of chemi
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Siberian Branch of Russian Academy
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INTERNATIONAL ADVISORY COMMITTEE:A.
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POSTER PRESENTATIONSSECTION IMECHAN
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PP-I-1more time in the oxidised sta
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PP-I-2Study of chemical reactions p
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PP-I-3It is suggested that during p
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PP-I-4reaction conditions, 100% con
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PP-I-5Catalytic properties of synth
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PP-I-6iii) The magnitude of above m
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PP-I-8ONE-DIMENSIONAL AND THREE-DIM
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PP-I-8This work was carried out at
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PP-I-9formed on their place. The PI
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PP-I-10CatalystЕа 1 ,kJ/mol(77÷1
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PP-I-11to increase of selectivity t
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PP-I-12The nanostructure of CS (clu
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PP-I-13The exchange in high-tempera
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PP-I-15ROLE OF CARBON DIOXIDE IN TH
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PP-I-16DIRECT OXIDATION OF BENZENE
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PP-I-17DFT STUDY OF REDUCTION REACT
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PP-I-18ORIGINAL MONTE CARLO METHOD
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PP-I-19STUDY ON THE MECHANISM OF TH
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PP-I-20NANOSIZED METAL OXIDES AS ST
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PP-I-21THE STUDYING OF THE NATURE O
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PP-I-22SYNTHESIS OF ETHYLENE-BUTADI
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PP-I-24REACTION OF PHENYLACETYLENE
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PP-I-25EFFECT OF THE PRESSURE ON TH
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PP-I-26INTERPRETATION OF THE ETHYLE
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PP-I-27STUDY OF ONE-POT REDUCTIVE D
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PP-I-28TUNING SURFACE MORPHOLOGY OF
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PP-I-29HIGHLY POROUS BLOCK CELLULAR
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PP-I-30STRUCTURE OF PHOTOCATALYTIC
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PP-I-31According to the 13 C MAS NM
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PP-I-32Conversion and selectivity a
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PP-I-34STUDY OF THE MECHANISM OF CA
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PP-I-35COMPARISON CATALYTIC ACTIVIT
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PP-I-36CRITICAL PHENOMENA FOR LANGM
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PP-I-37ISOTHERMS FOR STEPPED SURFAC
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PP-I-38RESOLUTION OF CHIRAL SULFOXI
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PP-I-39INVESTIGATION OF AMINO-CONTA
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PP-I-40APPLICATION OF POSITRON ANNI
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PP-I-41large pores (15-100 μm) of
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PP-I-42 Pd(1x2) Pd(1x1) Pd(1x2)-c
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PP-I-43the Al/Zr molar ratio has an
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PP-I-44transferred on nickel throug
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PP-I-45S BET , XRD, TPR, SEM, TEM a
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PP-I-46normal and branched alkanes
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PP-I-47growth stages (2) and (3) -
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PP-I-48system operated at frequenci
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PP-I-49The reactivity of these mate
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PP-I-51RECONSTRUCTION OF THE Pd(pol
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PP-I-53INTERMEDIATE PRODUCTS IN PAR
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PP-I-55MOLECULAR MECHANISM OF LOW T
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PP-I-56size of metals encapsulated
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PP-I-57activity of synthetic cataly
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PP-I-58us to suggest that oxidation
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PP-I-59characteristics are as follo
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PP-I-60surfaces changes at 50% cove
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PP-I-611) using the parameter conti
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PP-I-62atoms to PhePA molecule. In
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PP-I-63interaction of CO molecule b
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PP-I-64cases method of Coats-Redfer
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PP-I-65adsorbates and metal atoms.
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PP-I-66were extrapolated then to th
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PP-I-67account an influence of oxyg
Page 132 and 133: PP-I-68been considered. With this a
Page 134 and 135: PP-I-70MODIFICATION OF ELECTRONIC S
Page 136 and 137: PP-I-71most of described methods ch
Page 138 and 139: PP-I-72Table 1Polymeric active carb
Page 140 and 141: PP-I-73lower than 450 °C with prac
Page 142 and 143: PP-I-74Fig. 1. Optimized structure
Page 144 and 145: PP-I-75(Zn Z d ). The catalytic cyc
Page 146 and 147: PP-I-76Photocatalytic reaction was
Page 148 and 149: PP-I-78FRAGMENT COMPOSITION OF DIES
Page 150 and 151: PP-I-79QUANTUM-CHEMICAL STUDIES OF
Page 152 and 153: PP-I-80INFUENCE OF CHEMICAL TREATME
Page 154 and 155: PP-I-81ADSORPTION OF SMALL SILVER S
Page 156 and 157: PP-I-82EXPLOSION SAFETY IN GAS TRAN
Page 158 and 159: PP-I-83(ONNO) ad → N 2 O ad + O a
Page 161 and 162: CATALYTIC ACTIVATION OF UNFAVOURABL
Page 163 and 164: PP-II-1Therefore, the observed incr
Page 165 and 166: PP-II-2The samples of uranium oxide
Page 167 and 168: PP-II-3catalysts prepared by hydrot
Page 169 and 170: PP-II-4[(C 6 H 5 ) 2 (CH 2 =CHSi] 2
Page 171 and 172: PP-II-6THE NEW Ni, Zr, Ti-CONTAININ
Page 173 and 174: PP-II-7SPATIALLY RESOLVED UV-VIS MI
Page 175 and 176: PP-II-8POLYOL MEDIATED SYNTHESIS OF
Page 177 and 178: PP-II-8CuO phase were detected, sug
Page 179 and 180: PP-II-9SHS-INTERMETALLIDES ON THE B
Page 181: PP-II-10CO OXIDATION IN HYDROGEN ST
Page 185 and 186: PP-II-12FORMATION OF RADICAL CATION
Page 187 and 188: CATALYSTS MOLECULAR DESIGN BY SURFA
Page 189 and 190: PP-II-14THE CATALYTIC ACTIVITY OF F
Page 191 and 192: OXIDATION TRIMETHYLHYDROHYNONE IN T
Page 193 and 194: PP-II-16TECHNOLOGY CONCEPTS ON DEVE
Page 195 and 196: ACTIVATION OF POST-TITANOCENE OLEFI
Page 197 and 198: STRUCTURE FEATURES OF NANOCRYSTALLI
Page 199 and 200: THE H 2 ROLE IN SELECTIVE NO X REDU
Page 201 and 202: PP-II-20THE IN SITU FTIR STUDY OF T
Page 203 and 204: PP-II-21LUMINESCENT DIAGNOSTICS OF
Page 205 and 206: PP-II-22MODIFICATION OF PROPERTIES
Page 207 and 208: PP-II-23FTIR STUDY OF THE REACTION
Page 209 and 210: PP-II-24pores (the average diameter
Page 211 and 212: PP-II-25and the amount of the disso
Page 213 and 214: PP-II-27ACTIVITY OF PALLADIUM CATAL
Page 215 and 216: MODIFIED POLYOXIDE CATALYSTS FOR SY
Page 217 and 218: PP-II-29PRODUCTION OF HYDROGENCONTA
Page 219 and 220: INFLUENCE OF COMPOSITION AND STRUCT
Page 221 and 222: PP-II-311NEW COMPOSITE OF A POLYACE
Page 223 and 224: SOME ASPECTS OF THE SELECTION OF ST
Page 225 and 226: PP-II-33HYDROTREATING CATALYSTS MOD
Page 227 and 228: PP-II-34NORBORNADIENE IN NEW SHAPE-
Page 229 and 230: PP-II-36CATALYTIC SYSTEMS BASED ON
Page 231 and 232: PP-II-37EFFECT OF PHYSIOCHEMICAL PR
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PP-II-38INVESTIGATION OF STRUCTURE
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PP-II-38As a result of the combined
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PP-II-39synthesized by deposition-p
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PP-II-40halogen in NiX 2 (PPh 3 ) 2
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PP-II-41fell cell - with the requir
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PP-II-42SYNTHESIS OF CATALYSTS ON T
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PP-II-43-crucial role play peroxide
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PP-II-44According to the obtained d
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PP-II-46CYCLOALUMINATION OF α,ω-D
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PP-II-47ETHYLENE OLIGOMERIZATION TO
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PP-II-48aluminas are in the range o
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PP-II-49synthesis methods such as s
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PP-II-50Here, we report the first s
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PP-II-51hydrogenation. This peculia
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PP-II-524% and higher. Apparently t
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PP-II-53The secondary methods are b
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PP-II-55NOVEL CHIRAL NITROGEN CONTA
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PP-II-56NON-OXIDATIVE METHANE CONVE
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PP-II-57THE CATALYTIC ACTIVITY OF P
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PP-II-58The analysis of the raw mat
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PP-II-59analysis. Specific surface
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PP-II-60Ni-U catalysts were shown t
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PP-II-61Deep oxidation of CB vapors
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PP-II-62precipitate at 100 o C favo
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PP-II-63Х X n-С н-C 6 , %1008060
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PP-II-64mixture by microwave radiat
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PP-II-65and 99.995 % mass.) were sa
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PP-II-66CATALYTIC SYSTEMS BASED ON
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PHASE ANALYSIS OF MULTIELEMENT CATA
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PP-II-68EFFECT OF THE LIGAND SUBSTI
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PP-II-69Results and discussion: The
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PP-II-70tests in POM reaction and T
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PP-II-71The acidity, measured by tw
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PP-II-72The effect of nature and ac
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PP-II-74STUDY OF METHANE DEHYDROARO
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PP-II-75CATALYTIC OXIDATION OF ORGA
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Knowledge of the surface VO x speci
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PP-II-77propylene polymerization on
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THE EFFECT OF THE SUPPORT ON THE PE
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THE ACIDIC CATALYSIS IN REACTION OF
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HYDROGEN-RICH GAS PURIFICATION FROM
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PP-II-82During the stage of combine
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PP-II-83higher H 2 /propane ratios
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NANOSTRUCTURED MATERIALS BASED ON Z
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ELECTROCATALYTIC REDUCTION OF NITRO
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PP-II-87with CuKα radiation (λ ~
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PP-II-88The properties of the catal
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PP-II-89The stereospecificity of po
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PP-II-91SYNTHESIS AND CHARACTERIZAT
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PP-II-92INFLUENCE OF NATURE OF HETE
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PP-II-93OPTICALLY ACTIVE AMMONIUM S
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PP-II-94THE INFLUENCE OF FORMING CO
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PP-II-95NEW CATALYST OF LOW-TEMPERA
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PP-II-96DRIFTS AND UV-VIS STUDY OF
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PP-II-97NANOSTRUCTURED COMPLEX OXID
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PLATINUM CATALYSTS AND THEIR ACTIVI
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PP-II-99DESIGN OF STRUCTURED CATALY
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PP-II-100THE INFLUENCE OF CARBON ON
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PP-II-100sp 2 -carbon samples (Sibu
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PP-II-101Undoped LaMnO 3 has a stru
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PP-II-102The redox mechanisms of ca
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PP-II-103weak surface complexes of
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PP-II-104Ellipsometric, LA-XRD, TEM
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357PP-II-105It follows that MAO (or
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PP-II-106For the description of met
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361PP-II-1070.75, 1) were prepared
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PP-II-108(K⋅10 6 l/mole⋅mg⋅eq
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PP-II-110EFFECTS OF THE PROPERTIES
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PP-II-111CATALYTIC ACTIVITY OF POLY
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SYNTHESIS OF OXIRANES FROM RENEWABL
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PP-II-113SELECTIVE OXIDATION OF FOR
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BIODIESEL PRODUCTION FROM OLEIC ACI
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PP-II-115THE MECHANISM OF PHENOL OX
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PP-II-116THERMOSTABILITY OF Pd-ZEOL
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PP-II-117CO OXIDATION ON CuO-CeO 2
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PP-II-118THE ROLE OF I-CONTAINING P
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PP-II-119THE BULK POROUS ELECTRODE
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PP-II-120Methanol was suggested to
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PP-II-121Synthesis of catalysts on
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Yield, %PP-II-122Dynamics of variat
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PP-II-123The analysis of the hydroc
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PP-II-125THE MECHANISM OF COPPER CO
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PP-II-126The problem of the low act
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PP-II-127size of hydrocatalytic pro
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PP-II-128enhanced stability against
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PP-II-130HYDROGEN PRODUCTION BY MET
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CATALYTIC HYDROALKOXYCARBONYLATION
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NANOSTRUCTURED METAL-POLYMERIC CATA
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PP-II-133THE EFFECT OF THE SUPPORT
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PP-II-134АLTERNATIVE APPROACH TO D
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PP-II-135THE LOW-TEMPERATURE CATALY
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CATALYTIC PROPERTIES OF LAYERED OF
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PP-II-138EFFECT OF Zr ON THE OXIDAT
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PP-II-139THE NATURE OF ACTION OF TH
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PP-II-140CYCLOHEXANE OXIDATION OVER
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PP-II-141Mo AND W HETEROPOLYACID-CO
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HYDROCARBON CONVERSION CATALYSTS BA
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PP-II-142selectivity of the hexene-
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PP-II-143XPS, XRD and UV-Vis DRS st
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PP-II-144from the surface of sample
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PP-II-146THE INFLUENCE OF THE ACIDI
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PP-II-147CHARACTERISATION OF NEW GO
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STUDY ON THE REGULARITIES OF THE FO
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PP-II-148Platinum catalysts support
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PP-II-149selectivity to LHC, moreov
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PP-II-150steamed until a gel format
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PP-II-151ELECTRONIC STATE OF Cr n+
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PP-II-152METAL SUPPORTED CATALYSTS
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PP-II-153FORECASTING CATALYTIC CHAR
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RE - CONTENTING HC OXIDATION CATALY
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PP-II-155reaction are shown on the
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PP-II-156The product of stereoselec
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PP-II-157Supporting Pd on ZnO coate
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PP-II-158relating to acetone. With
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PP-II-159At the same time, catalyst
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PP-II-160The aim of our work is to
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PP-II-161crystallization state of t
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PP-II-162several carbon materials a
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PP-II-1625. J. M. H. Dirkx, H. S. v
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PP-III-1INFLUENCE OF DISSOLVED OXYG
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PP-III-2and microstructure, oxidati
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PP-III-3Aerosol, vapour of toxiccom
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PP-III-4inserted in PAn either in t
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PP-III-5The mechanism of pyrolysis
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ELECTROCATALYSTS WITH LOW PLATINUM
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PP-III-8VERY PURE SILICA FIBROUS AS
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PP-III-9METAL CONTAINING ZEOLITES -
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THE INFLUENCE OF TREATMENT METHOD O
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PARA-HYDROGEN INDUCED POLARIZATION
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PP-III-12NOVEL CHITOSAN-BASED CATAL
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PP-III-13Fig. 1. Dark adsorption (1
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PP-III-14residual pressure of 0.67
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PP-III-15using the same feedstock.
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PP-III-16Fig. 2. SEM-images of surf
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EPOXIDATION OF RAPESEED OIL BY HYDR
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PP-III-19THE PECULIARITIES OF CATAL
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PP-III-20CATALYTIC MEMBRANE CONTACT
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PP-III-21CATALYTIC ACTIVE LAYERS ON
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PP-III-22MODIFICATION OF COMPOUNDED
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EFFECT OF LIQUID POLYKETONE ON THE
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CATALYSTS SEARCH FOR α-METYLBENZYL
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PP-III-25PARTIAL OXIDATION OF PROPA
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PP-III-27BIODIESEL SYNTHESIS BY CAT
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PP-III-28PRODUCTION OF BIO-SYNGAS V
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PP-III-28Fig. 1. Changes in Н 2 an
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PP-III-29Table 1: Texture and adsor
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PP-III-30dimensionless front veloci
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PP-III-31synthesized. Experiments h
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PP-III-32It is established, that cr
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PP-III-33adsorptive catalysts in ad
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PP-III-34turbocompressor and two ca
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PP-III-35The Cu, Ni/ γ -Al 2 O 3 c
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PP-III-36pressure at 800-900 o C. T
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PP-III-370,50Concentration / Vol.-%
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PP-III-38HETEROGENEOUS-CATALYTIC DE
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PP-III-39HYDROISOMERIZATION OF CATA
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METHOD OF CATALYTIC UTILIZATION OF
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PP-III-41Catalytic properties of Fe
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PP-III-42heat in a steam-power unit
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PP-III-43In this way, the content o
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PP-III-45THE ECOLOGIC AND ECONOMIC
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PP-III-46INFLUENCE OF SUPPORT NATUR
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PP-III-47MIGRATION OF SUPPORTED PLA
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Table 2.PP-III-47The [Pt]/[Al] atom
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PP-III-48Under nitrogen atmosphere
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PP-III-49With aim to achieve the ho
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PP-III-50clinoptilolite (Aydag depo
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PP-III-51References1. Balzhinimaev
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PP-III-52Black light UV lamps. The
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USE OF THE NITROGEN-CONTAINING CARB
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PP-III-54CATALYTIC BEHAVIOUR OF VAR
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PP-III-55and sulfur, was spent (fig
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PP-III-56Specific reaction rates of
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PP-III-57special catalyst system wi
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PP-III-59UTILIZATION OF WASTE BIOMA
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MECHANOCHEMISTRY AND MECHANO-CATALY
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PP-III-62CATALYTIC INTENSIFICATION
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PP-III-64ABOUT WHAT MANUFACTURE OF
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PP-III-65OXDATIVE CONVERSION OF HYD
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PP-III-66COMPLEX QUALITY CONTROL SY
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PP-III-67INFLUENCE OF DIFFUSION, SI
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PP-III-68ONE STEP PROCESS FOR HYDRO
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FEATURES OF DRAG FACTOR FOR COMPLEX
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FIXED BED REACTORS WITH GRADIENT CA
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PP-III-70respective variational pro
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PP-III-71Operation at high volumetr
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PP-III-72It was performed the optim
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PP-III-73production stages of refin
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pik⎛N= fi ⎜∑j ∑⎝ j=1Nik,
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PP-III-75three MCP’s. In the seco
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PP-III-76during the reaction. The i
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PP-III-77enthalpy calculated for va
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PP-III-78calculating kinetics of pa
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PP-III-79ventilators 7 and 10, flam
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PP-III-801) C 6 H 5 CH 3 + 2 [YO]
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PP-III-81Δm/m coating, %204060V=0.
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PP-III-82• diameter of its genera
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PP-III-83ΔP,1mm H 2 O/m40023003420
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Concentration, vol.%PP-III-84The ef
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PP-III-85autocatalyst of thermoconv
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PP-III-86The influence of such para
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PP-III-87hydrocarbons increases wit
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AUTOWAVE PROCESSES IN A STATIC CATA
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PP-III-90KINETIC AND THERMODYNAMIC
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PP-III-91which mathematical descrip
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PP-III-93UTILIZATION OF LARGE-SCALE
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CATALYTIC TECHNOLOGY OF UTILIZATION
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PP-III-95PROPERTIES AND ACTIVITY OF
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PREPARATION AND CHARACTERIZATION OF
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PP-III-98The comparison of TPR runs
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ADVERTISEMENT
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PerformancePassionSuccessAutomotive
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Обслуживаемые рынк
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Polyurethanes are an integral part
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− prehydrotreating of gasolines a
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Kovalyov E. 123Kovtunov K. 489Kozlo
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List ofparticipantsABRAMOVA Anna Vs
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BOEVA Olga AnatolievnaD.I. Mendelee
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DJEKIC TanjaEindhoven University of
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GIMUNDINOV Shamil AbzalovichD.V. So
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KACHEVSKY Stanislav AndreevichLomon
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KONEV Vasily NikolayevichBoreskov I
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LEDOUX Marc-JacquesCNRS DPI3 Rue Mi
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MIERCZYŃSKI PawełInstitute of Gen
Page 686 and 687:
OBYSKALOVA Elina AnatolievnaBoresko
Page 688 and 689:
REBROV EvgenyEindhoven University o
Page 690 and 691:
SHALAGINA Anastasia EvgenievnaBores
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SPIRIDONOV Alexey AlexeevichBoresko
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VEDYAGIN Alexei Anatol'evichBoresko
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ZAKHARENKO Valery SemenovitchBoresk
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Volume IVolume IICONTENTPOSTER PRES
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PP-I-25 Hocine S., Cherifi O., Bett
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PP-I-52 Timoshenkov S.P., Artemov E
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PP-I-80 Shinkarev V.V., Kuvshinov G
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PP-II-21 Chistoforova N.V., Yelkina
Page 708 and 709:
PP-II-45 Khachani M., Boucetta C.,
Page 710 and 711:
PP-II-68 Malinskaya M.Ju., Sviridov
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PP-II-90 Nikitin V., Mikenas T., Za
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PP-II-114 Sepúlveda J., Santarosa
Page 716 and 717:
PP-II-139 Tkach V.S., Suslov D.S.,
Page 718 and 719:
Section III. Environmental and indu
Page 720 and 721:
PP-III-28 Yakovlev V.A., Kirillov V
Page 722 and 723:
PP-III-52 Shelimov B., Tolkachev N.
Page 724 and 725:
PP-III-77 Mel’gunov M., Kovalev M
Page 726:
III International Conference“Cata
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III International Conference

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