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PP-II-153Data obtained can be used for theoretical and practical bases for creation of efficient nonplatinumcatalysts for ammonia oxidation.References:1. Zakharchenko N.I. Questions of chemistry and chemical technology.2004.№4.P.67-712. Zakharchenko N.I. Mechanism and regularities about reactions of the oxidation of ammonia bymolecular oxygen on the oxide catalysts. VII Russian conference:” Mechanisms of the catalyticreactions”. (With 3-8 July 2006,Saint-Petersburg).2006.p.II.P.44-47.3. Zakharchenko N.I. Kinetics and catalys.2002.V.43.1.P.104-107448
RE - CONTENTING HC OXIDATION CATALYSTS OBTAINED BY THEAUTOCLAVE THERMOLYSIS METHODPP-II-154Fesik E.V., Zarazhevskij V.I., Morozov A.B., Grebnev V.V., Malchikov G.D.Samara State Aerospace University named after Korolev S.P., Samara, RussiaE-mail: malchikow.chem@mail.ruThere are some samples of catalysts containing Pt – Re and Pd – Re on the steelX18H10Т prepared by the autoclave thermolysis method and the catalytic activity of thesecatalysts was tested.Double metal coated heterogeneous catalysts often show synergetic effect and are moreactive than monometallic one. Binary catalysts containing platinum and nonferrous metals asan active component are widely used. Ways of metal coating, nature of inters, technologicalprocedures have decisive importance for obtaining the active catalyst.For coating of metals on ceramic and metal substrates we have developed the procedureof autoclave thermolysis of complex ammine in the alkaline medium. This method is based onthe irreversible process of intramolecular reduction of metal’s ion - complexing intrasphericalammonia according to the equation of reaction (1):[М(NH 3 ) i Cl i ] + OH - → M 0 + N 2 ↑ + NH 3 ↑ +H 2 O + Cl - , (1)where М = Pt, Pd, Rh, Ir, Ru etc.In this work, we offer to broaden the autoclave thermolysis method for Re-containingsystems. As a basic process, we offer to use the reaction proceeding by the following equation(2):3[Pt(NH 3 ) 4 ]Cl 2 + 6КOH + 6NH 4 ReO 4 → 3Pt 0 + 6Re 0 + 8N 2 + 6КCl + 2NH 3 + 30H 2 O (2)Samples of catalysts containing Pt – Re and Pd – Re, on the steel X18H10Т were testedon the laboratory facility of the flowing type with isothermal reactor and in conditions similarto the ideal displacement mode. We have studied catalytic activity and stability of samples inthe process of the deep oxidation of the model hydrocarbon (n- hexane). The composition ofthe reaction mixture was analyzed by gas chromatography method.We have determined that in processes of the deep oxidation of n-hexane, the catalyticactivity of Pt /Re and Pd/Re catalysts is close to the activity of Pt/Pd catalysts obtained by theautoclave thermolysis method.449
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"Catalysis is not a branch of chemi
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Siberian Branch of Russian Academy
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INTERNATIONAL ADVISORY COMMITTEE:A.
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POSTER PRESENTATIONSSECTION IMECHAN
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PP-I-1more time in the oxidised sta
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PP-I-2Study of chemical reactions p
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PP-I-3It is suggested that during p
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PP-I-4reaction conditions, 100% con
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PP-I-5Catalytic properties of synth
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PP-I-6iii) The magnitude of above m
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PP-I-8ONE-DIMENSIONAL AND THREE-DIM
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PP-I-8This work was carried out at
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PP-I-9formed on their place. The PI
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PP-I-10CatalystЕа 1 ,kJ/mol(77÷1
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PP-I-11to increase of selectivity t
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PP-I-12The nanostructure of CS (clu
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PP-I-13The exchange in high-tempera
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PP-I-15ROLE OF CARBON DIOXIDE IN TH
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PP-I-16DIRECT OXIDATION OF BENZENE
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PP-I-17DFT STUDY OF REDUCTION REACT
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PP-I-18ORIGINAL MONTE CARLO METHOD
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PP-I-19STUDY ON THE MECHANISM OF TH
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PP-I-20NANOSIZED METAL OXIDES AS ST
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PP-I-21THE STUDYING OF THE NATURE O
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PP-I-22SYNTHESIS OF ETHYLENE-BUTADI
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PP-I-24REACTION OF PHENYLACETYLENE
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PP-I-25EFFECT OF THE PRESSURE ON TH
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PP-I-26INTERPRETATION OF THE ETHYLE
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PP-I-27STUDY OF ONE-POT REDUCTIVE D
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PP-I-28TUNING SURFACE MORPHOLOGY OF
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PP-I-29HIGHLY POROUS BLOCK CELLULAR
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PP-I-30STRUCTURE OF PHOTOCATALYTIC
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PP-I-31According to the 13 C MAS NM
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PP-I-32Conversion and selectivity a
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PP-I-34STUDY OF THE MECHANISM OF CA
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PP-I-35COMPARISON CATALYTIC ACTIVIT
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PP-I-36CRITICAL PHENOMENA FOR LANGM
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PP-I-37ISOTHERMS FOR STEPPED SURFAC
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PP-I-38RESOLUTION OF CHIRAL SULFOXI
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PP-I-39INVESTIGATION OF AMINO-CONTA
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PP-I-40APPLICATION OF POSITRON ANNI
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PP-I-41large pores (15-100 μm) of
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PP-I-42 Pd(1x2) Pd(1x1) Pd(1x2)-c
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PP-I-43the Al/Zr molar ratio has an
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PP-I-44transferred on nickel throug
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PP-I-45S BET , XRD, TPR, SEM, TEM a
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PP-I-46normal and branched alkanes
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PP-I-47growth stages (2) and (3) -
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PP-I-48system operated at frequenci
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PP-I-49The reactivity of these mate
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PP-I-51RECONSTRUCTION OF THE Pd(pol
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PP-I-53INTERMEDIATE PRODUCTS IN PAR
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PP-I-55MOLECULAR MECHANISM OF LOW T
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PP-I-56size of metals encapsulated
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PP-I-57activity of synthetic cataly
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PP-I-58us to suggest that oxidation
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PP-I-59characteristics are as follo
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PP-I-60surfaces changes at 50% cove
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PP-I-611) using the parameter conti
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PP-I-62atoms to PhePA molecule. In
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PP-I-63interaction of CO molecule b
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PP-I-64cases method of Coats-Redfer
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PP-I-65adsorbates and metal atoms.
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PP-I-66were extrapolated then to th
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PP-I-67account an influence of oxyg
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PP-I-68been considered. With this a
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PP-I-70MODIFICATION OF ELECTRONIC S
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PP-I-71most of described methods ch
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PP-I-72Table 1Polymeric active carb
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PP-I-73lower than 450 °C with prac
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PP-I-74Fig. 1. Optimized structure
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PP-I-75(Zn Z d ). The catalytic cyc
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PP-I-76Photocatalytic reaction was
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PP-I-78FRAGMENT COMPOSITION OF DIES
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PP-I-79QUANTUM-CHEMICAL STUDIES OF
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PP-I-80INFUENCE OF CHEMICAL TREATME
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PP-I-81ADSORPTION OF SMALL SILVER S
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PP-I-82EXPLOSION SAFETY IN GAS TRAN
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PP-I-83(ONNO) ad → N 2 O ad + O a
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CATALYTIC ACTIVATION OF UNFAVOURABL
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PP-II-1Therefore, the observed incr
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PP-II-2The samples of uranium oxide
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PP-II-3catalysts prepared by hydrot
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PP-II-4[(C 6 H 5 ) 2 (CH 2 =CHSi] 2
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PP-II-6THE NEW Ni, Zr, Ti-CONTAININ
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PP-II-7SPATIALLY RESOLVED UV-VIS MI
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PP-II-8POLYOL MEDIATED SYNTHESIS OF
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PP-II-8CuO phase were detected, sug
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PP-II-9SHS-INTERMETALLIDES ON THE B
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PP-II-10CO OXIDATION IN HYDROGEN ST
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PP-II-11CATALYTIC PERFORMANCE OF CO
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PP-II-12FORMATION OF RADICAL CATION
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CATALYSTS MOLECULAR DESIGN BY SURFA
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PP-II-14THE CATALYTIC ACTIVITY OF F
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OXIDATION TRIMETHYLHYDROHYNONE IN T
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PP-II-16TECHNOLOGY CONCEPTS ON DEVE
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ACTIVATION OF POST-TITANOCENE OLEFI
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STRUCTURE FEATURES OF NANOCRYSTALLI
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THE H 2 ROLE IN SELECTIVE NO X REDU
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PP-II-20THE IN SITU FTIR STUDY OF T
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PP-II-21LUMINESCENT DIAGNOSTICS OF
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PP-II-22MODIFICATION OF PROPERTIES
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PP-II-23FTIR STUDY OF THE REACTION
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PP-II-24pores (the average diameter
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PP-II-25and the amount of the disso
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PP-II-27ACTIVITY OF PALLADIUM CATAL
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MODIFIED POLYOXIDE CATALYSTS FOR SY
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PP-II-29PRODUCTION OF HYDROGENCONTA
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INFLUENCE OF COMPOSITION AND STRUCT
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PP-II-311NEW COMPOSITE OF A POLYACE
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SOME ASPECTS OF THE SELECTION OF ST
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PP-II-33HYDROTREATING CATALYSTS MOD
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PP-II-34NORBORNADIENE IN NEW SHAPE-
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PP-II-36CATALYTIC SYSTEMS BASED ON
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PP-II-37EFFECT OF PHYSIOCHEMICAL PR
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PP-II-38INVESTIGATION OF STRUCTURE
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PP-II-38As a result of the combined
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PP-II-39synthesized by deposition-p
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PP-II-40halogen in NiX 2 (PPh 3 ) 2
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PP-II-41fell cell - with the requir
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PP-II-42SYNTHESIS OF CATALYSTS ON T
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PP-II-43-crucial role play peroxide
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PP-II-44According to the obtained d
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PP-II-46CYCLOALUMINATION OF α,ω-D
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PP-II-47ETHYLENE OLIGOMERIZATION TO
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PP-II-48aluminas are in the range o
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PP-II-49synthesis methods such as s
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PP-II-50Here, we report the first s
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PP-II-51hydrogenation. This peculia
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PP-II-524% and higher. Apparently t
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PP-II-53The secondary methods are b
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PP-II-55NOVEL CHIRAL NITROGEN CONTA
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PP-II-56NON-OXIDATIVE METHANE CONVE
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PP-II-57THE CATALYTIC ACTIVITY OF P
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PP-II-58The analysis of the raw mat
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PP-II-59analysis. Specific surface
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PP-II-60Ni-U catalysts were shown t
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PP-II-61Deep oxidation of CB vapors
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PP-II-62precipitate at 100 o C favo
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PP-II-63Х X n-С н-C 6 , %1008060
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PP-II-64mixture by microwave radiat
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PP-II-65and 99.995 % mass.) were sa
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PP-II-66CATALYTIC SYSTEMS BASED ON
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PHASE ANALYSIS OF MULTIELEMENT CATA
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PP-II-68EFFECT OF THE LIGAND SUBSTI
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PP-II-69Results and discussion: The
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PP-II-70tests in POM reaction and T
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PP-II-71The acidity, measured by tw
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PP-II-72The effect of nature and ac
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PP-II-74STUDY OF METHANE DEHYDROARO
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PP-II-75CATALYTIC OXIDATION OF ORGA
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Knowledge of the surface VO x speci
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PP-II-77propylene polymerization on
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THE EFFECT OF THE SUPPORT ON THE PE
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THE ACIDIC CATALYSIS IN REACTION OF
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HYDROGEN-RICH GAS PURIFICATION FROM
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PP-II-82During the stage of combine
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PP-II-83higher H 2 /propane ratios
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NANOSTRUCTURED MATERIALS BASED ON Z
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ELECTROCATALYTIC REDUCTION OF NITRO
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PP-II-87with CuKα radiation (λ ~
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PP-II-88The properties of the catal
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PP-II-89The stereospecificity of po
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PP-II-91SYNTHESIS AND CHARACTERIZAT
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PP-II-92INFLUENCE OF NATURE OF HETE
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PP-II-93OPTICALLY ACTIVE AMMONIUM S
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PP-II-94THE INFLUENCE OF FORMING CO
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PP-II-95NEW CATALYST OF LOW-TEMPERA
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PP-II-96DRIFTS AND UV-VIS STUDY OF
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PP-II-97NANOSTRUCTURED COMPLEX OXID
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PLATINUM CATALYSTS AND THEIR ACTIVI
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PP-II-99DESIGN OF STRUCTURED CATALY
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PP-II-100THE INFLUENCE OF CARBON ON
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PP-II-100sp 2 -carbon samples (Sibu
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PP-II-101Undoped LaMnO 3 has a stru
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PP-II-102The redox mechanisms of ca
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PP-II-103weak surface complexes of
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PP-II-104Ellipsometric, LA-XRD, TEM
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357PP-II-105It follows that MAO (or
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PP-II-106For the description of met
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361PP-II-1070.75, 1) were prepared
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PP-II-108(K⋅10 6 l/mole⋅mg⋅eq
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PP-II-110EFFECTS OF THE PROPERTIES
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PP-II-111CATALYTIC ACTIVITY OF POLY
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SYNTHESIS OF OXIRANES FROM RENEWABL
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PP-II-113SELECTIVE OXIDATION OF FOR
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BIODIESEL PRODUCTION FROM OLEIC ACI
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PP-II-115THE MECHANISM OF PHENOL OX
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PP-II-116THERMOSTABILITY OF Pd-ZEOL
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PP-II-117CO OXIDATION ON CuO-CeO 2
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PP-II-118THE ROLE OF I-CONTAINING P
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PP-II-119THE BULK POROUS ELECTRODE
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PP-II-120Methanol was suggested to
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PP-II-121Synthesis of catalysts on
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Yield, %PP-II-122Dynamics of variat
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PP-II-123The analysis of the hydroc
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PP-II-125THE MECHANISM OF COPPER CO
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PP-II-126The problem of the low act
Page 399 and 400: PP-II-127size of hydrocatalytic pro
Page 401 and 402: PP-II-128enhanced stability against
Page 403 and 404: PP-II-130HYDROGEN PRODUCTION BY MET
Page 405 and 406: CATALYTIC HYDROALKOXYCARBONYLATION
Page 407 and 408: NANOSTRUCTURED METAL-POLYMERIC CATA
Page 409 and 410: PP-II-133THE EFFECT OF THE SUPPORT
Page 411 and 412: PP-II-134АLTERNATIVE APPROACH TO D
Page 413 and 414: PP-II-135THE LOW-TEMPERATURE CATALY
Page 415 and 416: CATALYTIC PROPERTIES OF LAYERED OF
Page 417 and 418: PP-II-138EFFECT OF Zr ON THE OXIDAT
Page 419 and 420: PP-II-139THE NATURE OF ACTION OF TH
Page 421 and 422: PP-II-140CYCLOHEXANE OXIDATION OVER
Page 423 and 424: PP-II-141Mo AND W HETEROPOLYACID-CO
Page 425 and 426: HYDROCARBON CONVERSION CATALYSTS BA
Page 427 and 428: PP-II-142selectivity of the hexene-
Page 429 and 430: PP-II-143XPS, XRD and UV-Vis DRS st
Page 431 and 432: PP-II-144from the surface of sample
Page 433 and 434: PP-II-146THE INFLUENCE OF THE ACIDI
Page 435 and 436: PP-II-147CHARACTERISATION OF NEW GO
Page 437 and 438: STUDY ON THE REGULARITIES OF THE FO
Page 439 and 440: PP-II-148Platinum catalysts support
Page 441 and 442: PP-II-149selectivity to LHC, moreov
Page 443 and 444: PP-II-150steamed until a gel format
Page 445 and 446: PP-II-151ELECTRONIC STATE OF Cr n+
Page 447 and 448: PP-II-152METAL SUPPORTED CATALYSTS
Page 449: PP-II-153FORECASTING CATALYTIC CHAR
Page 453 and 454: PP-II-155reaction are shown on the
Page 455 and 456: PP-II-156The product of stereoselec
Page 457 and 458: PP-II-157Supporting Pd on ZnO coate
Page 459 and 460: PP-II-158relating to acetone. With
Page 461 and 462: PP-II-159At the same time, catalyst
Page 463 and 464: PP-II-160The aim of our work is to
Page 465 and 466: PP-II-161crystallization state of t
Page 467 and 468: PP-II-162several carbon materials a
Page 469: PP-II-1625. J. M. H. Dirkx, H. S. v
Page 473 and 474: PP-III-1INFLUENCE OF DISSOLVED OXYG
Page 475 and 476: PP-III-2and microstructure, oxidati
Page 477 and 478: PP-III-3Aerosol, vapour of toxiccom
Page 479 and 480: PP-III-4inserted in PAn either in t
Page 481 and 482: PP-III-5The mechanism of pyrolysis
Page 483 and 484: ELECTROCATALYSTS WITH LOW PLATINUM
Page 485 and 486: PP-III-8VERY PURE SILICA FIBROUS AS
Page 487 and 488: PP-III-9METAL CONTAINING ZEOLITES -
Page 489 and 490: THE INFLUENCE OF TREATMENT METHOD O
Page 491 and 492: PARA-HYDROGEN INDUCED POLARIZATION
Page 493 and 494: PP-III-12NOVEL CHITOSAN-BASED CATAL
Page 495 and 496: PP-III-13Fig. 1. Dark adsorption (1
Page 497 and 498: PP-III-14residual pressure of 0.67
Page 499 and 500: PP-III-15using the same feedstock.
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PP-III-16Fig. 2. SEM-images of surf
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EPOXIDATION OF RAPESEED OIL BY HYDR
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PP-III-19THE PECULIARITIES OF CATAL
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PP-III-20CATALYTIC MEMBRANE CONTACT
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PP-III-21CATALYTIC ACTIVE LAYERS ON
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PP-III-22MODIFICATION OF COMPOUNDED
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EFFECT OF LIQUID POLYKETONE ON THE
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CATALYSTS SEARCH FOR α-METYLBENZYL
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PP-III-25PARTIAL OXIDATION OF PROPA
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PP-III-27BIODIESEL SYNTHESIS BY CAT
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PP-III-28PRODUCTION OF BIO-SYNGAS V
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PP-III-28Fig. 1. Changes in Н 2 an
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PP-III-29Table 1: Texture and adsor
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PP-III-30dimensionless front veloci
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PP-III-31synthesized. Experiments h
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PP-III-32It is established, that cr
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PP-III-33adsorptive catalysts in ad
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PP-III-34turbocompressor and two ca
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PP-III-35The Cu, Ni/ γ -Al 2 O 3 c
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PP-III-36pressure at 800-900 o C. T
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PP-III-370,50Concentration / Vol.-%
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PP-III-38HETEROGENEOUS-CATALYTIC DE
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PP-III-39HYDROISOMERIZATION OF CATA
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METHOD OF CATALYTIC UTILIZATION OF
Page 549 and 550:
PP-III-41Catalytic properties of Fe
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PP-III-42heat in a steam-power unit
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PP-III-43In this way, the content o
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PP-III-45THE ECOLOGIC AND ECONOMIC
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PP-III-46INFLUENCE OF SUPPORT NATUR
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PP-III-47MIGRATION OF SUPPORTED PLA
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Table 2.PP-III-47The [Pt]/[Al] atom
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PP-III-48Under nitrogen atmosphere
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PP-III-49With aim to achieve the ho
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PP-III-50clinoptilolite (Aydag depo
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PP-III-51References1. Balzhinimaev
Page 571 and 572:
PP-III-52Black light UV lamps. The
Page 573 and 574:
USE OF THE NITROGEN-CONTAINING CARB
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PP-III-54CATALYTIC BEHAVIOUR OF VAR
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PP-III-55and sulfur, was spent (fig
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PP-III-56Specific reaction rates of
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PP-III-57special catalyst system wi
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PP-III-59UTILIZATION OF WASTE BIOMA
Page 585 and 586:
MECHANOCHEMISTRY AND MECHANO-CATALY
Page 587 and 588:
PP-III-62CATALYTIC INTENSIFICATION
Page 589 and 590:
PP-III-64ABOUT WHAT MANUFACTURE OF
Page 591 and 592:
PP-III-65OXDATIVE CONVERSION OF HYD
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PP-III-66COMPLEX QUALITY CONTROL SY
Page 595 and 596:
PP-III-67INFLUENCE OF DIFFUSION, SI
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PP-III-68ONE STEP PROCESS FOR HYDRO
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FEATURES OF DRAG FACTOR FOR COMPLEX
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FIXED BED REACTORS WITH GRADIENT CA
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PP-III-70respective variational pro
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PP-III-71Operation at high volumetr
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PP-III-72It was performed the optim
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PP-III-73production stages of refin
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pik⎛N= fi ⎜∑j ∑⎝ j=1Nik,
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PP-III-75three MCP’s. In the seco
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PP-III-76during the reaction. The i
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PP-III-77enthalpy calculated for va
Page 619 and 620:
PP-III-78calculating kinetics of pa
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PP-III-79ventilators 7 and 10, flam
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PP-III-801) C 6 H 5 CH 3 + 2 [YO]
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PP-III-81Δm/m coating, %204060V=0.
Page 627 and 628:
PP-III-82• diameter of its genera
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PP-III-83ΔP,1mm H 2 O/m40023003420
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Concentration, vol.%PP-III-84The ef
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PP-III-85autocatalyst of thermoconv
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PP-III-86The influence of such para
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PP-III-87hydrocarbons increases wit
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AUTOWAVE PROCESSES IN A STATIC CATA
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PP-III-90KINETIC AND THERMODYNAMIC
Page 643 and 644:
PP-III-91which mathematical descrip
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PP-III-93UTILIZATION OF LARGE-SCALE
Page 647 and 648:
CATALYTIC TECHNOLOGY OF UTILIZATION
Page 649 and 650:
PP-III-95PROPERTIES AND ACTIVITY OF
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PREPARATION AND CHARACTERIZATION OF
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PP-III-98The comparison of TPR runs
Page 655:
ADVERTISEMENT
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PerformancePassionSuccessAutomotive
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Обслуживаемые рынк
Page 662:
Polyurethanes are an integral part
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− prehydrotreating of gasolines a
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Kovalyov E. 123Kovtunov K. 489Kozlo
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List ofparticipantsABRAMOVA Anna Vs
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BOEVA Olga AnatolievnaD.I. Mendelee
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DJEKIC TanjaEindhoven University of
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GIMUNDINOV Shamil AbzalovichD.V. So
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KACHEVSKY Stanislav AndreevichLomon
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KONEV Vasily NikolayevichBoreskov I
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LEDOUX Marc-JacquesCNRS DPI3 Rue Mi
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MIERCZYŃSKI PawełInstitute of Gen
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OBYSKALOVA Elina AnatolievnaBoresko
Page 688 and 689:
REBROV EvgenyEindhoven University o
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SHALAGINA Anastasia EvgenievnaBores
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SPIRIDONOV Alexey AlexeevichBoresko
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VEDYAGIN Alexei Anatol'evichBoresko
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ZAKHARENKO Valery SemenovitchBoresk
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Volume IVolume IICONTENTPOSTER PRES
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PP-I-25 Hocine S., Cherifi O., Bett
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PP-I-52 Timoshenkov S.P., Artemov E
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PP-I-80 Shinkarev V.V., Kuvshinov G
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PP-II-21 Chistoforova N.V., Yelkina
Page 708 and 709:
PP-II-45 Khachani M., Boucetta C.,
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PP-II-68 Malinskaya M.Ju., Sviridov
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PP-II-90 Nikitin V., Mikenas T., Za
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PP-II-114 Sepúlveda J., Santarosa
Page 716 and 717:
PP-II-139 Tkach V.S., Suslov D.S.,
Page 718 and 719:
Section III. Environmental and indu
Page 720 and 721:
PP-III-28 Yakovlev V.A., Kirillov V
Page 722 and 723:
PP-III-52 Shelimov B., Tolkachev N.
Page 724 and 725:
PP-III-77 Mel’gunov M., Kovalev M
Page 726:
III International Conference“Cata
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