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PP-II-134reactions of selectivity oxidation take place on basal plane whereas the lateral plane of crystalfavours to oxidative dehydrogenation processes. It is necessary to note that proposed methodallows preparation of the samples with high specific surface area 50 - 150 m 2 /g and attractivepore structure (d = 20 - 70 nm).The catalytic tests of prepared supported catalysts in oxidative dehydrogenation propaneshow that obtained samples demonstrate the better catalytic properties than bulk VPOcatalysts.410
PP-II-135THE LOW-TEMPERATURE CATALYTIC OXIDATION OF VARIOUSSUBSTRATES BY OXYGEN IN THE PRESENCE OF NITROGEN OXIDES ANDTHE COMPLEXES OF TRANSITION METALSTaltenov A.A., Sarmurzina A.G., Emelyanova V.S.Scientific research institute of New chemical technologies and materials of Kazakh NationalUniversity, Almaty, KazakhstanE-mail: rinctm@kazsu.kzNitric acid very frequently is used in the industry of organic synthesis at oxidation oforganic compounds. Disadvantage of nitric acid is the evolution of sample quantity ofnitrogen oxides. The similar effect is observed at oxidizing metals manufacturing fromsulphidic ores. Practical interest is represented with recycling in such processes nitrogen(<strong>III</strong>-V) oxides not as oxidizers, but as catalysts of substrates oxidation by oxygen. It is shown, thatat the presence of transition metal complexes and nitrogen(II, IV) oxides it is carried out lowtemperatureoxidation of a lot of substrates by oxygen. The reactions kinetic is investigated bymodern methods (IR-, UF- spectrophotometry, GL-chromatography, redox-potentiometry,volumetry), quantum-chemical characteristics of the intermediate particles participating inreactions calculated by NDO method. The scheme of the mechanism is offered.Study of the processes kinetics specified in table 1, has shown, that oxidation rate ofvarious substrates by oxygen is described by the kinetic equation (1):WO2k2⋅ CNO⋅ CO⋅ k2 1 ⋅ CS⋅ CNO2= , (1)k ⋅ C + k ⋅ C ⋅ C1Swhere S – a substratum reacting with oxygen, k1 and k2 – rate constants of reactions (2, 3):2NOO2k1NO + S←⎯→NO SO(2)2+k2NO+ O2 ← 2⎯→2NO2(3)Table 1 – Low-temperature (40-60 °С) oxidation of various substratum by oxygen atpresence nitrogen oxides and complexes of transition metalsProcess Catalysts k 1 , mole/l⋅s k 1 , l 2 /mole 2 ⋅sC 6 H 5 OH + O 2 → C 6 H 4 O 2 NO, NO 2 , CuCl 2 7⋅10 -2 9,3⋅10 62H 2 S + O 2 → 2H 2 O + 2S2 (C 6 H 5 )S + O 2 → 2C 2 H 5 OH + 2SC 6 H 4 Cl 2 + O 2←⎯⎯O →H 2 C 6 H 5 O 2 + 2HClNO, NO 2 , I- 8,3⋅10 -1 8,7⋅10 6NO, NO 2 , CuCl 2 1,3⋅10 -1 8,8⋅10 6NO, NO 2 , I- 5⋅10 -2 8,6⋅10 6C 6 H 6 + HBr + O 2 → C 6 H 4 Br 2 + H 2O NO, NO 2 , Co(NO 3 ) 2 8,6⋅10 -3 8,7⋅10 6411
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"Catalysis is not a branch of chemi
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Siberian Branch of Russian Academy
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INTERNATIONAL ADVISORY COMMITTEE:A.
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POSTER PRESENTATIONSSECTION IMECHAN
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PP-I-1more time in the oxidised sta
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PP-I-2Study of chemical reactions p
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PP-I-3It is suggested that during p
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PP-I-4reaction conditions, 100% con
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PP-I-5Catalytic properties of synth
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PP-I-6iii) The magnitude of above m
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PP-I-8ONE-DIMENSIONAL AND THREE-DIM
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PP-I-8This work was carried out at
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PP-I-9formed on their place. The PI
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PP-I-10CatalystЕа 1 ,kJ/mol(77÷1
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PP-I-11to increase of selectivity t
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PP-I-12The nanostructure of CS (clu
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PP-I-13The exchange in high-tempera
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PP-I-15ROLE OF CARBON DIOXIDE IN TH
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PP-I-16DIRECT OXIDATION OF BENZENE
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PP-I-17DFT STUDY OF REDUCTION REACT
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PP-I-18ORIGINAL MONTE CARLO METHOD
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PP-I-19STUDY ON THE MECHANISM OF TH
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PP-I-20NANOSIZED METAL OXIDES AS ST
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PP-I-21THE STUDYING OF THE NATURE O
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PP-I-22SYNTHESIS OF ETHYLENE-BUTADI
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PP-I-24REACTION OF PHENYLACETYLENE
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PP-I-25EFFECT OF THE PRESSURE ON TH
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PP-I-26INTERPRETATION OF THE ETHYLE
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PP-I-27STUDY OF ONE-POT REDUCTIVE D
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PP-I-28TUNING SURFACE MORPHOLOGY OF
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PP-I-29HIGHLY POROUS BLOCK CELLULAR
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PP-I-30STRUCTURE OF PHOTOCATALYTIC
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PP-I-31According to the 13 C MAS NM
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PP-I-32Conversion and selectivity a
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PP-I-34STUDY OF THE MECHANISM OF CA
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PP-I-35COMPARISON CATALYTIC ACTIVIT
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PP-I-36CRITICAL PHENOMENA FOR LANGM
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PP-I-37ISOTHERMS FOR STEPPED SURFAC
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PP-I-38RESOLUTION OF CHIRAL SULFOXI
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PP-I-39INVESTIGATION OF AMINO-CONTA
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PP-I-40APPLICATION OF POSITRON ANNI
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PP-I-41large pores (15-100 μm) of
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PP-I-42 Pd(1x2) Pd(1x1) Pd(1x2)-c
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PP-I-43the Al/Zr molar ratio has an
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PP-I-44transferred on nickel throug
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PP-I-45S BET , XRD, TPR, SEM, TEM a
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PP-I-46normal and branched alkanes
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PP-I-47growth stages (2) and (3) -
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PP-I-48system operated at frequenci
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PP-I-49The reactivity of these mate
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PP-I-51RECONSTRUCTION OF THE Pd(pol
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PP-I-53INTERMEDIATE PRODUCTS IN PAR
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PP-I-55MOLECULAR MECHANISM OF LOW T
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PP-I-56size of metals encapsulated
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PP-I-57activity of synthetic cataly
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PP-I-58us to suggest that oxidation
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PP-I-59characteristics are as follo
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PP-I-60surfaces changes at 50% cove
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PP-I-611) using the parameter conti
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PP-I-62atoms to PhePA molecule. In
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PP-I-63interaction of CO molecule b
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PP-I-64cases method of Coats-Redfer
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PP-I-65adsorbates and metal atoms.
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PP-I-66were extrapolated then to th
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PP-I-67account an influence of oxyg
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PP-I-68been considered. With this a
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PP-I-70MODIFICATION OF ELECTRONIC S
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PP-I-71most of described methods ch
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PP-I-72Table 1Polymeric active carb
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PP-I-73lower than 450 °C with prac
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PP-I-74Fig. 1. Optimized structure
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PP-I-75(Zn Z d ). The catalytic cyc
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PP-I-76Photocatalytic reaction was
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PP-I-78FRAGMENT COMPOSITION OF DIES
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PP-I-79QUANTUM-CHEMICAL STUDIES OF
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PP-I-80INFUENCE OF CHEMICAL TREATME
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PP-I-81ADSORPTION OF SMALL SILVER S
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PP-I-82EXPLOSION SAFETY IN GAS TRAN
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PP-I-83(ONNO) ad → N 2 O ad + O a
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CATALYTIC ACTIVATION OF UNFAVOURABL
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PP-II-1Therefore, the observed incr
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PP-II-2The samples of uranium oxide
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PP-II-3catalysts prepared by hydrot
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PP-II-4[(C 6 H 5 ) 2 (CH 2 =CHSi] 2
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PP-II-6THE NEW Ni, Zr, Ti-CONTAININ
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PP-II-7SPATIALLY RESOLVED UV-VIS MI
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PP-II-8POLYOL MEDIATED SYNTHESIS OF
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PP-II-8CuO phase were detected, sug
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PP-II-9SHS-INTERMETALLIDES ON THE B
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PP-II-10CO OXIDATION IN HYDROGEN ST
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PP-II-11CATALYTIC PERFORMANCE OF CO
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PP-II-12FORMATION OF RADICAL CATION
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CATALYSTS MOLECULAR DESIGN BY SURFA
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PP-II-14THE CATALYTIC ACTIVITY OF F
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OXIDATION TRIMETHYLHYDROHYNONE IN T
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PP-II-16TECHNOLOGY CONCEPTS ON DEVE
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ACTIVATION OF POST-TITANOCENE OLEFI
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STRUCTURE FEATURES OF NANOCRYSTALLI
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THE H 2 ROLE IN SELECTIVE NO X REDU
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PP-II-20THE IN SITU FTIR STUDY OF T
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PP-II-21LUMINESCENT DIAGNOSTICS OF
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PP-II-22MODIFICATION OF PROPERTIES
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PP-II-23FTIR STUDY OF THE REACTION
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PP-II-24pores (the average diameter
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PP-II-25and the amount of the disso
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PP-II-27ACTIVITY OF PALLADIUM CATAL
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MODIFIED POLYOXIDE CATALYSTS FOR SY
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PP-II-29PRODUCTION OF HYDROGENCONTA
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INFLUENCE OF COMPOSITION AND STRUCT
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PP-II-311NEW COMPOSITE OF A POLYACE
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SOME ASPECTS OF THE SELECTION OF ST
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PP-II-33HYDROTREATING CATALYSTS MOD
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PP-II-34NORBORNADIENE IN NEW SHAPE-
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PP-II-36CATALYTIC SYSTEMS BASED ON
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PP-II-37EFFECT OF PHYSIOCHEMICAL PR
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PP-II-38INVESTIGATION OF STRUCTURE
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PP-II-38As a result of the combined
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PP-II-39synthesized by deposition-p
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PP-II-40halogen in NiX 2 (PPh 3 ) 2
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PP-II-41fell cell - with the requir
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PP-II-42SYNTHESIS OF CATALYSTS ON T
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PP-II-43-crucial role play peroxide
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PP-II-44According to the obtained d
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PP-II-46CYCLOALUMINATION OF α,ω-D
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PP-II-47ETHYLENE OLIGOMERIZATION TO
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PP-II-48aluminas are in the range o
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PP-II-49synthesis methods such as s
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PP-II-50Here, we report the first s
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PP-II-51hydrogenation. This peculia
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PP-II-524% and higher. Apparently t
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PP-II-53The secondary methods are b
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PP-II-55NOVEL CHIRAL NITROGEN CONTA
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PP-II-56NON-OXIDATIVE METHANE CONVE
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PP-II-57THE CATALYTIC ACTIVITY OF P
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PP-II-58The analysis of the raw mat
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PP-II-59analysis. Specific surface
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PP-II-60Ni-U catalysts were shown t
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PP-II-61Deep oxidation of CB vapors
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PP-II-62precipitate at 100 o C favo
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PP-II-63Х X n-С н-C 6 , %1008060
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PP-II-64mixture by microwave radiat
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PP-II-65and 99.995 % mass.) were sa
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PP-II-66CATALYTIC SYSTEMS BASED ON
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PHASE ANALYSIS OF MULTIELEMENT CATA
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PP-II-68EFFECT OF THE LIGAND SUBSTI
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PP-II-69Results and discussion: The
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PP-II-70tests in POM reaction and T
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PP-II-71The acidity, measured by tw
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PP-II-72The effect of nature and ac
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PP-II-74STUDY OF METHANE DEHYDROARO
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PP-II-75CATALYTIC OXIDATION OF ORGA
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Knowledge of the surface VO x speci
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PP-II-77propylene polymerization on
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THE EFFECT OF THE SUPPORT ON THE PE
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THE ACIDIC CATALYSIS IN REACTION OF
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HYDROGEN-RICH GAS PURIFICATION FROM
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PP-II-82During the stage of combine
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PP-II-83higher H 2 /propane ratios
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NANOSTRUCTURED MATERIALS BASED ON Z
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ELECTROCATALYTIC REDUCTION OF NITRO
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PP-II-87with CuKα radiation (λ ~
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PP-II-88The properties of the catal
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PP-II-89The stereospecificity of po
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PP-II-91SYNTHESIS AND CHARACTERIZAT
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PP-II-92INFLUENCE OF NATURE OF HETE
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PP-II-93OPTICALLY ACTIVE AMMONIUM S
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PP-II-94THE INFLUENCE OF FORMING CO
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PP-II-95NEW CATALYST OF LOW-TEMPERA
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PP-II-96DRIFTS AND UV-VIS STUDY OF
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PP-II-97NANOSTRUCTURED COMPLEX OXID
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PLATINUM CATALYSTS AND THEIR ACTIVI
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PP-II-99DESIGN OF STRUCTURED CATALY
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PP-II-100THE INFLUENCE OF CARBON ON
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PP-II-100sp 2 -carbon samples (Sibu
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PP-II-101Undoped LaMnO 3 has a stru
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PP-II-102The redox mechanisms of ca
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PP-II-103weak surface complexes of
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PP-II-104Ellipsometric, LA-XRD, TEM
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357PP-II-105It follows that MAO (or
Page 361 and 362: PP-II-106For the description of met
Page 363 and 364: 361PP-II-1070.75, 1) were prepared
Page 365 and 366: PP-II-108(K⋅10 6 l/mole⋅mg⋅eq
Page 367 and 368: PP-II-110EFFECTS OF THE PROPERTIES
Page 369 and 370: PP-II-111CATALYTIC ACTIVITY OF POLY
Page 371 and 372: SYNTHESIS OF OXIRANES FROM RENEWABL
Page 373 and 374: PP-II-113SELECTIVE OXIDATION OF FOR
Page 375 and 376: BIODIESEL PRODUCTION FROM OLEIC ACI
Page 377 and 378: PP-II-115THE MECHANISM OF PHENOL OX
Page 379 and 380: PP-II-116THERMOSTABILITY OF Pd-ZEOL
Page 381 and 382: PP-II-117CO OXIDATION ON CuO-CeO 2
Page 383 and 384: PP-II-118THE ROLE OF I-CONTAINING P
Page 385 and 386: PP-II-119THE BULK POROUS ELECTRODE
Page 387 and 388: PP-II-120Methanol was suggested to
Page 389 and 390: PP-II-121Synthesis of catalysts on
Page 391 and 392: Yield, %PP-II-122Dynamics of variat
Page 393 and 394: PP-II-123The analysis of the hydroc
Page 395 and 396: PP-II-125THE MECHANISM OF COPPER CO
Page 397 and 398: PP-II-126The problem of the low act
Page 399 and 400: PP-II-127size of hydrocatalytic pro
Page 401 and 402: PP-II-128enhanced stability against
Page 403 and 404: PP-II-130HYDROGEN PRODUCTION BY MET
Page 405 and 406: CATALYTIC HYDROALKOXYCARBONYLATION
Page 407 and 408: NANOSTRUCTURED METAL-POLYMERIC CATA
Page 409 and 410: PP-II-133THE EFFECT OF THE SUPPORT
Page 411: PP-II-134АLTERNATIVE APPROACH TO D
Page 415 and 416: CATALYTIC PROPERTIES OF LAYERED OF
Page 417 and 418: PP-II-138EFFECT OF Zr ON THE OXIDAT
Page 419 and 420: PP-II-139THE NATURE OF ACTION OF TH
Page 421 and 422: PP-II-140CYCLOHEXANE OXIDATION OVER
Page 423 and 424: PP-II-141Mo AND W HETEROPOLYACID-CO
Page 425 and 426: HYDROCARBON CONVERSION CATALYSTS BA
Page 427 and 428: PP-II-142selectivity of the hexene-
Page 429 and 430: PP-II-143XPS, XRD and UV-Vis DRS st
Page 431 and 432: PP-II-144from the surface of sample
Page 433 and 434: PP-II-146THE INFLUENCE OF THE ACIDI
Page 435 and 436: PP-II-147CHARACTERISATION OF NEW GO
Page 437 and 438: STUDY ON THE REGULARITIES OF THE FO
Page 439 and 440: PP-II-148Platinum catalysts support
Page 441 and 442: PP-II-149selectivity to LHC, moreov
Page 443 and 444: PP-II-150steamed until a gel format
Page 445 and 446: PP-II-151ELECTRONIC STATE OF Cr n+
Page 447 and 448: PP-II-152METAL SUPPORTED CATALYSTS
Page 449 and 450: PP-II-153FORECASTING CATALYTIC CHAR
Page 451 and 452: RE - CONTENTING HC OXIDATION CATALY
Page 453 and 454: PP-II-155reaction are shown on the
Page 455 and 456: PP-II-156The product of stereoselec
Page 457 and 458: PP-II-157Supporting Pd on ZnO coate
Page 459 and 460: PP-II-158relating to acetone. With
Page 461 and 462: PP-II-159At the same time, catalyst
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PP-II-160The aim of our work is to
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PP-II-161crystallization state of t
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PP-II-162several carbon materials a
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PP-II-1625. J. M. H. Dirkx, H. S. v
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PP-III-1INFLUENCE OF DISSOLVED OXYG
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PP-III-2and microstructure, oxidati
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PP-III-3Aerosol, vapour of toxiccom
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PP-III-4inserted in PAn either in t
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PP-III-5The mechanism of pyrolysis
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ELECTROCATALYSTS WITH LOW PLATINUM
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PP-III-8VERY PURE SILICA FIBROUS AS
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PP-III-9METAL CONTAINING ZEOLITES -
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THE INFLUENCE OF TREATMENT METHOD O
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PARA-HYDROGEN INDUCED POLARIZATION
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PP-III-12NOVEL CHITOSAN-BASED CATAL
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PP-III-13Fig. 1. Dark adsorption (1
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PP-III-14residual pressure of 0.67
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PP-III-15using the same feedstock.
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PP-III-16Fig. 2. SEM-images of surf
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EPOXIDATION OF RAPESEED OIL BY HYDR
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PP-III-19THE PECULIARITIES OF CATAL
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PP-III-20CATALYTIC MEMBRANE CONTACT
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PP-III-21CATALYTIC ACTIVE LAYERS ON
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PP-III-22MODIFICATION OF COMPOUNDED
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EFFECT OF LIQUID POLYKETONE ON THE
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CATALYSTS SEARCH FOR α-METYLBENZYL
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PP-III-25PARTIAL OXIDATION OF PROPA
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PP-III-27BIODIESEL SYNTHESIS BY CAT
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PP-III-28PRODUCTION OF BIO-SYNGAS V
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PP-III-28Fig. 1. Changes in Н 2 an
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PP-III-29Table 1: Texture and adsor
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PP-III-30dimensionless front veloci
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PP-III-31synthesized. Experiments h
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PP-III-32It is established, that cr
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PP-III-33adsorptive catalysts in ad
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PP-III-34turbocompressor and two ca
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PP-III-35The Cu, Ni/ γ -Al 2 O 3 c
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PP-III-36pressure at 800-900 o C. T
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PP-III-370,50Concentration / Vol.-%
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PP-III-38HETEROGENEOUS-CATALYTIC DE
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PP-III-39HYDROISOMERIZATION OF CATA
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METHOD OF CATALYTIC UTILIZATION OF
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PP-III-41Catalytic properties of Fe
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PP-III-42heat in a steam-power unit
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PP-III-43In this way, the content o
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PP-III-45THE ECOLOGIC AND ECONOMIC
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PP-III-46INFLUENCE OF SUPPORT NATUR
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PP-III-47MIGRATION OF SUPPORTED PLA
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Table 2.PP-III-47The [Pt]/[Al] atom
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PP-III-48Under nitrogen atmosphere
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PP-III-49With aim to achieve the ho
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PP-III-50clinoptilolite (Aydag depo
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PP-III-51References1. Balzhinimaev
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PP-III-52Black light UV lamps. The
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USE OF THE NITROGEN-CONTAINING CARB
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PP-III-54CATALYTIC BEHAVIOUR OF VAR
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PP-III-55and sulfur, was spent (fig
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PP-III-56Specific reaction rates of
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PP-III-57special catalyst system wi
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PP-III-59UTILIZATION OF WASTE BIOMA
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MECHANOCHEMISTRY AND MECHANO-CATALY
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PP-III-62CATALYTIC INTENSIFICATION
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PP-III-64ABOUT WHAT MANUFACTURE OF
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PP-III-65OXDATIVE CONVERSION OF HYD
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PP-III-66COMPLEX QUALITY CONTROL SY
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PP-III-67INFLUENCE OF DIFFUSION, SI
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PP-III-68ONE STEP PROCESS FOR HYDRO
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FEATURES OF DRAG FACTOR FOR COMPLEX
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FIXED BED REACTORS WITH GRADIENT CA
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PP-III-70respective variational pro
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PP-III-71Operation at high volumetr
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PP-III-72It was performed the optim
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PP-III-73production stages of refin
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pik⎛N= fi ⎜∑j ∑⎝ j=1Nik,
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PP-III-75three MCP’s. In the seco
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PP-III-76during the reaction. The i
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PP-III-77enthalpy calculated for va
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PP-III-78calculating kinetics of pa
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PP-III-79ventilators 7 and 10, flam
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PP-III-801) C 6 H 5 CH 3 + 2 [YO]
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PP-III-81Δm/m coating, %204060V=0.
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PP-III-82• diameter of its genera
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PP-III-83ΔP,1mm H 2 O/m40023003420
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Concentration, vol.%PP-III-84The ef
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PP-III-85autocatalyst of thermoconv
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PP-III-86The influence of such para
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PP-III-87hydrocarbons increases wit
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AUTOWAVE PROCESSES IN A STATIC CATA
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PP-III-90KINETIC AND THERMODYNAMIC
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PP-III-91which mathematical descrip
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PP-III-93UTILIZATION OF LARGE-SCALE
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CATALYTIC TECHNOLOGY OF UTILIZATION
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PP-III-95PROPERTIES AND ACTIVITY OF
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PREPARATION AND CHARACTERIZATION OF
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PP-III-98The comparison of TPR runs
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ADVERTISEMENT
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PerformancePassionSuccessAutomotive
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Обслуживаемые рынк
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Polyurethanes are an integral part
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− prehydrotreating of gasolines a
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Kovalyov E. 123Kovtunov K. 489Kozlo
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List ofparticipantsABRAMOVA Anna Vs
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BOEVA Olga AnatolievnaD.I. Mendelee
Page 674 and 675:
DJEKIC TanjaEindhoven University of
Page 676 and 677:
GIMUNDINOV Shamil AbzalovichD.V. So
Page 678 and 679:
KACHEVSKY Stanislav AndreevichLomon
Page 680 and 681:
KONEV Vasily NikolayevichBoreskov I
Page 682 and 683:
LEDOUX Marc-JacquesCNRS DPI3 Rue Mi
Page 684 and 685:
MIERCZYŃSKI PawełInstitute of Gen
Page 686 and 687:
OBYSKALOVA Elina AnatolievnaBoresko
Page 688 and 689:
REBROV EvgenyEindhoven University o
Page 690 and 691:
SHALAGINA Anastasia EvgenievnaBores
Page 692 and 693:
SPIRIDONOV Alexey AlexeevichBoresko
Page 694 and 695:
VEDYAGIN Alexei Anatol'evichBoresko
Page 696 and 697:
ZAKHARENKO Valery SemenovitchBoresk
Page 698 and 699:
Volume IVolume IICONTENTPOSTER PRES
Page 700 and 701:
PP-I-25 Hocine S., Cherifi O., Bett
Page 702 and 703:
PP-I-52 Timoshenkov S.P., Artemov E
Page 704 and 705:
PP-I-80 Shinkarev V.V., Kuvshinov G
Page 706 and 707:
PP-II-21 Chistoforova N.V., Yelkina
Page 708 and 709:
PP-II-45 Khachani M., Boucetta C.,
Page 710 and 711:
PP-II-68 Malinskaya M.Ju., Sviridov
Page 712 and 713:
PP-II-90 Nikitin V., Mikenas T., Za
Page 714 and 715:
PP-II-114 Sepúlveda J., Santarosa
Page 716 and 717:
PP-II-139 Tkach V.S., Suslov D.S.,
Page 718 and 719:
Section III. Environmental and indu
Page 720 and 721:
PP-III-28 Yakovlev V.A., Kirillov V
Page 722 and 723:
PP-III-52 Shelimov B., Tolkachev N.
Page 724 and 725:
PP-III-77 Mel’gunov M., Kovalev M
Page 726:
III International Conference“Cata
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III International Conference

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