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PP-III-34DESIGN OF THE CATALYST’ FOR THE CLEANING OF THE EXHAUST GASESOF THE MOTOR TRANSPORT WORKING WITH METHANEGilmundinov Sh.A., Sassykova L.R., Nalibaeva A.M.D.V. Sokolsky Institute of Organic Catalysis and Electrochemisrty MS&HE RK,Almaty, Republic of KazakhstanE-mail: aray77@mail.ruThe Ag-Mn catalysts promoted by 0,1% Pt at the block metal carriers with thehoneycomb channels structure were elaborated and they were tested at the “poor” mixtures.For the efficient wastes lowering at the “poor” mixtures ordinary two catalysts (with the sizes45x50 mm every sample) were used in front of the turbocompressor and two catalysts (withthe sizes 110x90 mm) on the spot of the regular silencer were placed. The cleaning efficacywas by NO x -59%, CH x -76%, CO-99%. Thus as its followed from the tests results the Ag-Mncatalysts using in both complete set led to the improvement was equal to European standardsby the wastes.Every year the transport development and increase of its using in the different loadtransportation is growing. This in its turn lead to a marked atmosphere pollution by the toxicgases which fatal influence on flora and fauna. The engine current characteristicsimprovement and transition to another alternative fuels reduce the total volume of the wastesbut even the transport transfer to the “blue” fuel doesn’t solve the ecological problem. At thesame time with the toxic gases also the hydrocarbons, nitric oxides, carbon oxide are presentand their concentrations lowering is possible to reach by only catalytic method.We carried out the comparative researchings by using catalytic neutralizers of the wastegases at KamAZ (model 820.52-260) with the turbo-inflatable gas engine which was workingat methane with the foil injection distribution and the electronic management. It was revealedthat the catalyst led to considerable lowering of the CO wastes, insignificant decrease of CH 4and it didn’t influence to NO x wastes. The catalytic neutralizers had the low efficacy bymethane neutralization at the rotations of the idle motions and also at the work with the smallloading at the waste gases temperature at the entrance of neutralizer didn’t exceed to 250 0 C.At the engine work with the stoichiometric mixture composite the effect of neutralization ofNO x , CO, CH x to standard Euro III as a result of the oxidation-reduction was observed. Butthe engine economical characteristics got worse. By this reason we carried out the tests of theelaborating Ag-Mn catalysts promoted by 0,1% Pt at the block metal carriers with thehoneycomb channels structure at the “poor” mixtures. For the efficient wastes lowering at the“poor” mixtures work two catalysts (with the sizes 45x50 mm every sample) in front of the532
PP-III-34turbocompressor and two catalysts (with the sizes 110x90 mm) on the spot of the regularsilencer were placed. As a result of the KamAz (model 820.520-260) gas engine tests at theminimum idle motion regime with the complete set primary and secondary neutralizers of thewastes the cleaning efficacy was by NO x -59%, CH x -76%, CO-99%.Thus as it follows from the tests results the Ag-Mn catalysts using in both complete setled to the improvement was equal to European standards by the wastes.533
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"Catalysis is not a branch of chemi
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Siberian Branch of Russian Academy
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INTERNATIONAL ADVISORY COMMITTEE:A.
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POSTER PRESENTATIONSSECTION IMECHAN
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PP-I-1more time in the oxidised sta
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PP-I-2Study of chemical reactions p
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PP-I-3It is suggested that during p
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PP-I-4reaction conditions, 100% con
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PP-I-5Catalytic properties of synth
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PP-I-6iii) The magnitude of above m
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PP-I-8ONE-DIMENSIONAL AND THREE-DIM
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PP-I-8This work was carried out at
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PP-I-9formed on their place. The PI
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PP-I-10CatalystЕа 1 ,kJ/mol(77÷1
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PP-I-11to increase of selectivity t
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PP-I-12The nanostructure of CS (clu
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PP-I-13The exchange in high-tempera
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PP-I-15ROLE OF CARBON DIOXIDE IN TH
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PP-I-16DIRECT OXIDATION OF BENZENE
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PP-I-17DFT STUDY OF REDUCTION REACT
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PP-I-18ORIGINAL MONTE CARLO METHOD
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PP-I-19STUDY ON THE MECHANISM OF TH
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PP-I-20NANOSIZED METAL OXIDES AS ST
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PP-I-21THE STUDYING OF THE NATURE O
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PP-I-22SYNTHESIS OF ETHYLENE-BUTADI
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PP-I-24REACTION OF PHENYLACETYLENE
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PP-I-25EFFECT OF THE PRESSURE ON TH
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PP-I-26INTERPRETATION OF THE ETHYLE
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PP-I-27STUDY OF ONE-POT REDUCTIVE D
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PP-I-28TUNING SURFACE MORPHOLOGY OF
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PP-I-29HIGHLY POROUS BLOCK CELLULAR
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PP-I-30STRUCTURE OF PHOTOCATALYTIC
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PP-I-31According to the 13 C MAS NM
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PP-I-32Conversion and selectivity a
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PP-I-34STUDY OF THE MECHANISM OF CA
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PP-I-35COMPARISON CATALYTIC ACTIVIT
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PP-I-36CRITICAL PHENOMENA FOR LANGM
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PP-I-37ISOTHERMS FOR STEPPED SURFAC
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PP-I-38RESOLUTION OF CHIRAL SULFOXI
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PP-I-39INVESTIGATION OF AMINO-CONTA
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PP-I-40APPLICATION OF POSITRON ANNI
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PP-I-41large pores (15-100 μm) of
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PP-I-42 Pd(1x2) Pd(1x1) Pd(1x2)-c
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PP-I-43the Al/Zr molar ratio has an
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PP-I-44transferred on nickel throug
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PP-I-45S BET , XRD, TPR, SEM, TEM a
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PP-I-46normal and branched alkanes
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PP-I-47growth stages (2) and (3) -
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PP-I-48system operated at frequenci
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PP-I-49The reactivity of these mate
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PP-I-51RECONSTRUCTION OF THE Pd(pol
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PP-I-53INTERMEDIATE PRODUCTS IN PAR
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PP-I-55MOLECULAR MECHANISM OF LOW T
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PP-I-56size of metals encapsulated
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PP-I-57activity of synthetic cataly
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PP-I-58us to suggest that oxidation
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PP-I-59characteristics are as follo
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PP-I-60surfaces changes at 50% cove
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PP-I-611) using the parameter conti
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PP-I-62atoms to PhePA molecule. In
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PP-I-63interaction of CO molecule b
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PP-I-64cases method of Coats-Redfer
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PP-I-65adsorbates and metal atoms.
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PP-I-66were extrapolated then to th
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PP-I-67account an influence of oxyg
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PP-I-68been considered. With this a
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PP-I-70MODIFICATION OF ELECTRONIC S
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PP-I-71most of described methods ch
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PP-I-72Table 1Polymeric active carb
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PP-I-73lower than 450 °C with prac
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PP-I-74Fig. 1. Optimized structure
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PP-I-75(Zn Z d ). The catalytic cyc
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PP-I-76Photocatalytic reaction was
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PP-I-78FRAGMENT COMPOSITION OF DIES
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PP-I-79QUANTUM-CHEMICAL STUDIES OF
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PP-I-80INFUENCE OF CHEMICAL TREATME
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PP-I-81ADSORPTION OF SMALL SILVER S
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PP-I-82EXPLOSION SAFETY IN GAS TRAN
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PP-I-83(ONNO) ad → N 2 O ad + O a
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CATALYTIC ACTIVATION OF UNFAVOURABL
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PP-II-1Therefore, the observed incr
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PP-II-2The samples of uranium oxide
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PP-II-3catalysts prepared by hydrot
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PP-II-4[(C 6 H 5 ) 2 (CH 2 =CHSi] 2
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PP-II-6THE NEW Ni, Zr, Ti-CONTAININ
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PP-II-7SPATIALLY RESOLVED UV-VIS MI
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PP-II-8POLYOL MEDIATED SYNTHESIS OF
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PP-II-8CuO phase were detected, sug
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PP-II-9SHS-INTERMETALLIDES ON THE B
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PP-II-10CO OXIDATION IN HYDROGEN ST
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PP-II-11CATALYTIC PERFORMANCE OF CO
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PP-II-12FORMATION OF RADICAL CATION
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CATALYSTS MOLECULAR DESIGN BY SURFA
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PP-II-14THE CATALYTIC ACTIVITY OF F
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OXIDATION TRIMETHYLHYDROHYNONE IN T
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PP-II-16TECHNOLOGY CONCEPTS ON DEVE
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ACTIVATION OF POST-TITANOCENE OLEFI
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STRUCTURE FEATURES OF NANOCRYSTALLI
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THE H 2 ROLE IN SELECTIVE NO X REDU
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PP-II-20THE IN SITU FTIR STUDY OF T
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PP-II-21LUMINESCENT DIAGNOSTICS OF
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PP-II-22MODIFICATION OF PROPERTIES
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PP-II-23FTIR STUDY OF THE REACTION
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PP-II-24pores (the average diameter
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PP-II-25and the amount of the disso
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PP-II-27ACTIVITY OF PALLADIUM CATAL
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MODIFIED POLYOXIDE CATALYSTS FOR SY
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PP-II-29PRODUCTION OF HYDROGENCONTA
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INFLUENCE OF COMPOSITION AND STRUCT
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PP-II-311NEW COMPOSITE OF A POLYACE
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SOME ASPECTS OF THE SELECTION OF ST
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PP-II-33HYDROTREATING CATALYSTS MOD
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PP-II-34NORBORNADIENE IN NEW SHAPE-
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PP-II-36CATALYTIC SYSTEMS BASED ON
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PP-II-37EFFECT OF PHYSIOCHEMICAL PR
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PP-II-38INVESTIGATION OF STRUCTURE
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PP-II-38As a result of the combined
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PP-II-39synthesized by deposition-p
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PP-II-40halogen in NiX 2 (PPh 3 ) 2
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PP-II-41fell cell - with the requir
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PP-II-42SYNTHESIS OF CATALYSTS ON T
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PP-II-43-crucial role play peroxide
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PP-II-44According to the obtained d
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PP-II-46CYCLOALUMINATION OF α,ω-D
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PP-II-47ETHYLENE OLIGOMERIZATION TO
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PP-II-48aluminas are in the range o
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PP-II-49synthesis methods such as s
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PP-II-50Here, we report the first s
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PP-II-51hydrogenation. This peculia
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PP-II-524% and higher. Apparently t
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PP-II-53The secondary methods are b
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PP-II-55NOVEL CHIRAL NITROGEN CONTA
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PP-II-56NON-OXIDATIVE METHANE CONVE
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PP-II-57THE CATALYTIC ACTIVITY OF P
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PP-II-58The analysis of the raw mat
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PP-II-59analysis. Specific surface
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PP-II-60Ni-U catalysts were shown t
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PP-II-61Deep oxidation of CB vapors
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PP-II-62precipitate at 100 o C favo
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PP-II-63Х X n-С н-C 6 , %1008060
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PP-II-64mixture by microwave radiat
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PP-II-65and 99.995 % mass.) were sa
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PP-II-66CATALYTIC SYSTEMS BASED ON
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PHASE ANALYSIS OF MULTIELEMENT CATA
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PP-II-68EFFECT OF THE LIGAND SUBSTI
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PP-II-69Results and discussion: The
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PP-II-70tests in POM reaction and T
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PP-II-71The acidity, measured by tw
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PP-II-72The effect of nature and ac
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PP-II-74STUDY OF METHANE DEHYDROARO
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PP-II-75CATALYTIC OXIDATION OF ORGA
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Knowledge of the surface VO x speci
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PP-II-77propylene polymerization on
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THE EFFECT OF THE SUPPORT ON THE PE
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THE ACIDIC CATALYSIS IN REACTION OF
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HYDROGEN-RICH GAS PURIFICATION FROM
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PP-II-82During the stage of combine
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PP-II-83higher H 2 /propane ratios
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NANOSTRUCTURED MATERIALS BASED ON Z
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ELECTROCATALYTIC REDUCTION OF NITRO
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PP-II-87with CuKα radiation (λ ~
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PP-II-88The properties of the catal
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PP-II-89The stereospecificity of po
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PP-II-91SYNTHESIS AND CHARACTERIZAT
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PP-II-92INFLUENCE OF NATURE OF HETE
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PP-II-93OPTICALLY ACTIVE AMMONIUM S
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PP-II-94THE INFLUENCE OF FORMING CO
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PP-II-95NEW CATALYST OF LOW-TEMPERA
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PP-II-96DRIFTS AND UV-VIS STUDY OF
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PP-II-97NANOSTRUCTURED COMPLEX OXID
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PLATINUM CATALYSTS AND THEIR ACTIVI
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PP-II-99DESIGN OF STRUCTURED CATALY
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PP-II-100THE INFLUENCE OF CARBON ON
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PP-II-100sp 2 -carbon samples (Sibu
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PP-II-101Undoped LaMnO 3 has a stru
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PP-II-102The redox mechanisms of ca
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PP-II-103weak surface complexes of
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PP-II-104Ellipsometric, LA-XRD, TEM
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357PP-II-105It follows that MAO (or
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PP-II-106For the description of met
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361PP-II-1070.75, 1) were prepared
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PP-II-108(K⋅10 6 l/mole⋅mg⋅eq
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PP-II-110EFFECTS OF THE PROPERTIES
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PP-II-111CATALYTIC ACTIVITY OF POLY
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SYNTHESIS OF OXIRANES FROM RENEWABL
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PP-II-113SELECTIVE OXIDATION OF FOR
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BIODIESEL PRODUCTION FROM OLEIC ACI
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PP-II-115THE MECHANISM OF PHENOL OX
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PP-II-116THERMOSTABILITY OF Pd-ZEOL
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PP-II-117CO OXIDATION ON CuO-CeO 2
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PP-II-118THE ROLE OF I-CONTAINING P
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PP-II-119THE BULK POROUS ELECTRODE
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PP-II-120Methanol was suggested to
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PP-II-121Synthesis of catalysts on
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Yield, %PP-II-122Dynamics of variat
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PP-II-123The analysis of the hydroc
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PP-II-125THE MECHANISM OF COPPER CO
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PP-II-126The problem of the low act
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PP-II-127size of hydrocatalytic pro
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PP-II-128enhanced stability against
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PP-II-130HYDROGEN PRODUCTION BY MET
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CATALYTIC HYDROALKOXYCARBONYLATION
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NANOSTRUCTURED METAL-POLYMERIC CATA
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PP-II-133THE EFFECT OF THE SUPPORT
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PP-II-134АLTERNATIVE APPROACH TO D
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PP-II-135THE LOW-TEMPERATURE CATALY
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CATALYTIC PROPERTIES OF LAYERED OF
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PP-II-138EFFECT OF Zr ON THE OXIDAT
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PP-II-139THE NATURE OF ACTION OF TH
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PP-II-140CYCLOHEXANE OXIDATION OVER
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PP-II-141Mo AND W HETEROPOLYACID-CO
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HYDROCARBON CONVERSION CATALYSTS BA
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PP-II-142selectivity of the hexene-
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PP-II-143XPS, XRD and UV-Vis DRS st
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PP-II-144from the surface of sample
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PP-II-146THE INFLUENCE OF THE ACIDI
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PP-II-147CHARACTERISATION OF NEW GO
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STUDY ON THE REGULARITIES OF THE FO
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PP-II-148Platinum catalysts support
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PP-II-149selectivity to LHC, moreov
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PP-II-150steamed until a gel format
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PP-II-151ELECTRONIC STATE OF Cr n+
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PP-II-152METAL SUPPORTED CATALYSTS
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PP-II-153FORECASTING CATALYTIC CHAR
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RE - CONTENTING HC OXIDATION CATALY
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PP-II-155reaction are shown on the
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PP-II-156The product of stereoselec
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PP-II-157Supporting Pd on ZnO coate
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PP-II-158relating to acetone. With
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PP-II-159At the same time, catalyst
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PP-II-160The aim of our work is to
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PP-II-161crystallization state of t
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PP-II-162several carbon materials a
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PP-II-1625. J. M. H. Dirkx, H. S. v
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PP-III-1INFLUENCE OF DISSOLVED OXYG
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PP-III-2and microstructure, oxidati
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PP-III-3Aerosol, vapour of toxiccom
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PP-III-4inserted in PAn either in t
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PP-III-5The mechanism of pyrolysis
Page 483 and 484: ELECTROCATALYSTS WITH LOW PLATINUM
Page 485 and 486: PP-III-8VERY PURE SILICA FIBROUS AS
Page 487 and 488: PP-III-9METAL CONTAINING ZEOLITES -
Page 489 and 490: THE INFLUENCE OF TREATMENT METHOD O
Page 491 and 492: PARA-HYDROGEN INDUCED POLARIZATION
Page 493 and 494: PP-III-12NOVEL CHITOSAN-BASED CATAL
Page 495 and 496: PP-III-13Fig. 1. Dark adsorption (1
Page 497 and 498: PP-III-14residual pressure of 0.67
Page 499 and 500: PP-III-15using the same feedstock.
Page 501 and 502: PP-III-16Fig. 2. SEM-images of surf
Page 503 and 504: EPOXIDATION OF RAPESEED OIL BY HYDR
Page 505 and 506: PP-III-19THE PECULIARITIES OF CATAL
Page 507 and 508: PP-III-20CATALYTIC MEMBRANE CONTACT
Page 509 and 510: PP-III-21CATALYTIC ACTIVE LAYERS ON
Page 511 and 512: PP-III-22MODIFICATION OF COMPOUNDED
Page 513 and 514: EFFECT OF LIQUID POLYKETONE ON THE
Page 515 and 516: CATALYSTS SEARCH FOR α-METYLBENZYL
Page 517 and 518: PP-III-25PARTIAL OXIDATION OF PROPA
Page 519 and 520: PP-III-27BIODIESEL SYNTHESIS BY CAT
Page 521 and 522: PP-III-28PRODUCTION OF BIO-SYNGAS V
Page 523 and 524: PP-III-28Fig. 1. Changes in Н 2 an
Page 525 and 526: PP-III-29Table 1: Texture and adsor
Page 527 and 528: PP-III-30dimensionless front veloci
Page 529 and 530: PP-III-31synthesized. Experiments h
Page 531 and 532: PP-III-32It is established, that cr
Page 533: PP-III-33adsorptive catalysts in ad
Page 537 and 538: PP-III-35The Cu, Ni/ γ -Al 2 O 3 c
Page 539 and 540: PP-III-36pressure at 800-900 o C. T
Page 541 and 542: PP-III-370,50Concentration / Vol.-%
Page 543 and 544: PP-III-38HETEROGENEOUS-CATALYTIC DE
Page 545 and 546: PP-III-39HYDROISOMERIZATION OF CATA
Page 547 and 548: METHOD OF CATALYTIC UTILIZATION OF
Page 549 and 550: PP-III-41Catalytic properties of Fe
Page 551 and 552: PP-III-42heat in a steam-power unit
Page 553 and 554: PP-III-43In this way, the content o
Page 555 and 556: PP-III-45THE ECOLOGIC AND ECONOMIC
Page 557 and 558: PP-III-46INFLUENCE OF SUPPORT NATUR
Page 559 and 560: PP-III-47MIGRATION OF SUPPORTED PLA
Page 561 and 562: Table 2.PP-III-47The [Pt]/[Al] atom
Page 563 and 564: PP-III-48Under nitrogen atmosphere
Page 565 and 566: PP-III-49With aim to achieve the ho
Page 567 and 568: PP-III-50clinoptilolite (Aydag depo
Page 569 and 570: PP-III-51References1. Balzhinimaev
Page 571 and 572: PP-III-52Black light UV lamps. The
Page 573 and 574: USE OF THE NITROGEN-CONTAINING CARB
Page 575 and 576: PP-III-54CATALYTIC BEHAVIOUR OF VAR
Page 577 and 578: PP-III-55and sulfur, was spent (fig
Page 579 and 580: PP-III-56Specific reaction rates of
Page 581 and 582: PP-III-57special catalyst system wi
Page 583 and 584: PP-III-59UTILIZATION OF WASTE BIOMA
Page 585 and 586:
MECHANOCHEMISTRY AND MECHANO-CATALY
Page 587 and 588:
PP-III-62CATALYTIC INTENSIFICATION
Page 589 and 590:
PP-III-64ABOUT WHAT MANUFACTURE OF
Page 591 and 592:
PP-III-65OXDATIVE CONVERSION OF HYD
Page 593 and 594:
PP-III-66COMPLEX QUALITY CONTROL SY
Page 595 and 596:
PP-III-67INFLUENCE OF DIFFUSION, SI
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PP-III-68ONE STEP PROCESS FOR HYDRO
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FEATURES OF DRAG FACTOR FOR COMPLEX
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FIXED BED REACTORS WITH GRADIENT CA
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PP-III-70respective variational pro
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PP-III-71Operation at high volumetr
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PP-III-72It was performed the optim
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PP-III-73production stages of refin
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pik⎛N= fi ⎜∑j ∑⎝ j=1Nik,
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PP-III-75three MCP’s. In the seco
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PP-III-76during the reaction. The i
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PP-III-77enthalpy calculated for va
Page 619 and 620:
PP-III-78calculating kinetics of pa
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PP-III-79ventilators 7 and 10, flam
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PP-III-801) C 6 H 5 CH 3 + 2 [YO]
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PP-III-81Δm/m coating, %204060V=0.
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PP-III-82• diameter of its genera
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PP-III-83ΔP,1mm H 2 O/m40023003420
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Concentration, vol.%PP-III-84The ef
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PP-III-85autocatalyst of thermoconv
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PP-III-86The influence of such para
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PP-III-87hydrocarbons increases wit
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AUTOWAVE PROCESSES IN A STATIC CATA
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PP-III-90KINETIC AND THERMODYNAMIC
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PP-III-91which mathematical descrip
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PP-III-93UTILIZATION OF LARGE-SCALE
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CATALYTIC TECHNOLOGY OF UTILIZATION
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PP-III-95PROPERTIES AND ACTIVITY OF
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PREPARATION AND CHARACTERIZATION OF
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PP-III-98The comparison of TPR runs
Page 655:
ADVERTISEMENT
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PerformancePassionSuccessAutomotive
Page 660 and 661:
Обслуживаемые рынк
Page 662:
Polyurethanes are an integral part
Page 666 and 667:
− prehydrotreating of gasolines a
Page 668 and 669:
Kovalyov E. 123Kovtunov K. 489Kozlo
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List ofparticipantsABRAMOVA Anna Vs
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BOEVA Olga AnatolievnaD.I. Mendelee
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DJEKIC TanjaEindhoven University of
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GIMUNDINOV Shamil AbzalovichD.V. So
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KACHEVSKY Stanislav AndreevichLomon
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KONEV Vasily NikolayevichBoreskov I
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LEDOUX Marc-JacquesCNRS DPI3 Rue Mi
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MIERCZYŃSKI PawełInstitute of Gen
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OBYSKALOVA Elina AnatolievnaBoresko
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REBROV EvgenyEindhoven University o
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SHALAGINA Anastasia EvgenievnaBores
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SPIRIDONOV Alexey AlexeevichBoresko
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VEDYAGIN Alexei Anatol'evichBoresko
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ZAKHARENKO Valery SemenovitchBoresk
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Volume IVolume IICONTENTPOSTER PRES
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PP-I-25 Hocine S., Cherifi O., Bett
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PP-I-52 Timoshenkov S.P., Artemov E
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PP-I-80 Shinkarev V.V., Kuvshinov G
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PP-II-21 Chistoforova N.V., Yelkina
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PP-II-45 Khachani M., Boucetta C.,
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PP-II-68 Malinskaya M.Ju., Sviridov
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PP-II-90 Nikitin V., Mikenas T., Za
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PP-II-114 Sepúlveda J., Santarosa
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PP-II-139 Tkach V.S., Suslov D.S.,
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Section III. Environmental and indu
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PP-III-28 Yakovlev V.A., Kirillov V
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PP-III-52 Shelimov B., Tolkachev N.
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PP-III-77 Mel’gunov M., Kovalev M
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III International Conference“Cata
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III International Conference

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