III International Conference

PP-II-108CHLORINATED SULFOCATIONITES – EFFECTIVE CATALYSTS OF INDUCEDOXIDATION OF UNSATURATED HYDROCARBONSSadygov O.A., Alimardanov H.M.Y.H. Mamedaliyev Institute of Petrochemical Processes of NAS of Azerbaijan, Baky, AzerbaijanE-mail: hafizalimardanov@yahoo.comIntroduction.Modified forms of ionites, possessing a number of advantages against homogeneouscatalysts, are recently widely applied in reactions of liquid phase oxidation of unsaturatedhydrocarbons [1].In the present work we present results of study of activity of modified forms of KU-2type cationite in reactions of induced oxidation of unsaturated hydrocarbons - octene-1,decene-1, bicyclo heptene and dicyclopentadiene in the presence of carboxylic acids andhydrogen peroxide by the circuit:RCOOH+H 2 O 2KU-2RCOOOH+H 2 O+>C=C< >C-C< +H 2 O , RCOOH>C-CC-C