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90 CHAPTER 2. ATMOSPHERE AND REMOTE SENSING<br />

2.5.19 Comparison of GOME NO2 retrievals analysed by different scientific<br />

groups<br />

Participating scientists: Walburga Wilms-Grabe, Steffen Beirle, Randall Martin, Andreas Richter,<br />

Michel van Roozendael, and Thomas Wagner<br />

Abstract In order to improve nonuniform GOME NO2 products of differing analysis tools applied<br />

at several institutes, NO2 SCDs have been compared for selected GOME orbits. The results show<br />

principal agreement between retrievals of IASB in Brussels, IUP Bremen and IUP Heidelberg, but in<br />

some extent clear discrepancies to retrievals of Dalhousie University in Halifax.<br />

Figure 2.53: NO2 SCDs of one GOME orbit crossing north-east of the United States and the Pacific,<br />

analysed for 03 February 1996 (left) and 06 February 2000 (right) by Heidelberg (blue), Bremen<br />

(black), Brussels (green) and Halifax (red)<br />

Background Several scientific groups are occupied<br />

with the analysis of GOME trace gas measurements.<br />

In dependence of the used retrieval<br />

tools, the resulting trace gas distributions differ<br />

from each other, though they were analyzed for<br />

the same location and time. Therefore, a comparison<br />

study is performed in order to assess the<br />

discrepancies and to evaluate the reliability of<br />

GOME products. The study is concentrated on<br />

NO2, an important trace gas for both the troposphere<br />

and stratosphere. The assessment of NO2<br />

retrievals can help all GOME data users to choose<br />

the most appropriate data set and particularly<br />

helps the provider of evaluated GOME data to<br />

unify the different existing analyzing algorithms.<br />

Funding See satellite group overview.<br />

Methods and results For the whole GOME<br />

measurement period, two GOME orbits per year<br />

have been selected as case studies: one orbit in<br />

the winter time (February) and one in the summer<br />

time (July). The chosen orbits are all located<br />

above nearly the same region, including high polluted<br />

areas in north-east of the United States and<br />

clean areas above the Pacific. This choice allows<br />

to compare NO2 retrievals for the complete orbit,<br />

but also to consider separately polluted and<br />

non-polluted parts of the orbit. In order to obtain<br />

really basic information about reasons for the<br />

variability of GOME NO2 products, in a first step<br />

pure SCDs were compared.<br />

The figure shows two examples of several NO2 retrievals.<br />

The principal agreement of all participating<br />

groups is existing. However, all selected<br />

orbits indicate better agreement between the NO2<br />

distributions of Bremen, Brussels and Heidelberg<br />

and more obvious deviations in the NO2 results<br />

of Halifax. The deviations of Halifax are related<br />

as well to the absolute SCD values (positive offset)<br />

as to the scattering of the data. In the figure,<br />

the differing scatter patterns of Halifax can<br />

be seen clearly in the region between −50 ◦ and<br />

−10 ◦ latitude. Correlations between NO2 results<br />

of Bremen, Brussels and Heidelberg lie around<br />

0.97 and 0.99 in both polluted and unpolluted regions.<br />

Correlations between data of one of these<br />

groups and data of Halifax are around 0.97 in<br />

polluted areas and about 0.55 in the less NO2enriched<br />

region between −50 ◦ and −10 ◦ latitude.<br />

Outlook/Future work Level 2 data of the<br />

DLR have to be included in the comparison study.<br />

Also VCDs and air mass factors have to be considered,<br />

the number of selected orbits has to be<br />

extended.<br />

Main publication Publication is planned later<br />

on in an advanced stage of the comparison study.

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