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Chemical and Functional Properties of Food Saccharides

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© 2004 by CRC Press LLC<br />

8.2.3.1 Steeping <strong>and</strong> Grinding<br />

Steeping is the key operation in preparing kernels for effective separation <strong>and</strong><br />

splitting <strong>of</strong> their components. 3 As previously addressed, water diffusion, chemical<br />

reactions, <strong>and</strong> removal <strong>of</strong> solved compounds together with fermentative processes<br />

(in particular, a lactic acid fermentation) produce tissue structures adequately s<strong>of</strong>tened<br />

for mechanical separation operations. 4 Understeeping results in high-protein<br />

starch <strong>and</strong> starch losses with by-products, whereas oversteeping damages starch<br />

quality <strong>and</strong> gluten losses by excessive solubilization.<br />

Cleaned corn/maize is soaked in process water from starch refining to which<br />

0.1 to 0.2% SO 2 is added to produce steep acid. The steeping battery is managed in<br />

a complex system <strong>of</strong> countercurrent flow where steep acid enters the battery section<br />

with oldest corn (approximately 45% moisture) <strong>and</strong> leaves the section with fresh<br />

corn as light steep water. The temperature applied during steeping is set by tolerance<br />

<strong>of</strong> lactic acid bacteria <strong>and</strong> ranges from 49 to 53°C. Steeping time may vary from<br />

30 to 50 h; however, effective steeping times are 40 to 42 h. After reaching the<br />

correct point <strong>of</strong> treatment, steeped corn is drained (about 50% moisture) <strong>and</strong> fed to<br />

degerminating mills (attrition mills) to tear open kernels <strong>and</strong> leave the intact germ<br />

free for the following separation. In general, degermination takes place in two stages<br />

<strong>of</strong> a first <strong>and</strong> second grind, with intermediate removal <strong>of</strong> germs via hydrocyclones<br />

152 mm in diameter. Ground germ-free material passes 50-µm screen bends (120°,<br />

grit screens) to separate finely split starch <strong>and</strong> gluten (40 to 50% <strong>of</strong> the stream) from<br />

coarse material, which is fed to the third grind by refiner or impact mills for<br />

completed disintegration. Separated starch-free germs are dried. They have a lipid<br />

content <strong>of</strong> 50 to 58% <strong>and</strong> are high-grade material for vegetable oil production.<br />

8.2.3.2 Fiber Separation<br />

Fibers made flexible by steeping become resistant to further fragmentation by milling<br />

<strong>and</strong> are removed by screening from the slurry consisting mainly <strong>of</strong> starch <strong>and</strong> gluten.<br />

The material leaving the grit screens for the third grinding passes the fiber-washing<br />

station, a system <strong>of</strong> five or six stages <strong>of</strong> screen bends in series. Screen bends used<br />

in the fiber-washing station resemble the 120° screens used as grit screens. The<br />

aperture <strong>of</strong> the screens is also 50 µm. While starch <strong>and</strong> gluten are transported to the<br />

first wash screen, fibers leave the last screen for dewatering <strong>and</strong> drying. Coarse fiber<br />

is discharged after optimum washing with maximum 15% bound <strong>and</strong> 5% free starch<br />

(dry substance basis).<br />

8.2.3.3 Starch–Gluten Separation<br />

The stream coming from grit screens <strong>and</strong> the first section <strong>of</strong> the fiber-washing<br />

screens is designated as mill starch <strong>and</strong> contains separated starch, insoluble proteins<br />

(zein, glutelins), <strong>and</strong> soluble impurities, mainly proteins <strong>and</strong> minerals. Mill starch<br />

produced with a density <strong>of</strong> 6 to 8° Bé first passes degritting hydrocyclones to remove<br />

s<strong>and</strong> <strong>and</strong> fine debris that potentially may damage separators <strong>and</strong> hydrocyclone<br />

stations used for starch–gluten separation <strong>and</strong> starch refinement. Debris formed by<br />

the action <strong>of</strong> centrifugal forces <strong>and</strong> high-speed movement applied there can cause

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