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Chemical and Functional Properties of Food Saccharides

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© 2004 by CRC Press LLC<br />

FIGURE 14.4 Titration curves <strong>of</strong> chitosans monitored by 1 H NMR. The chemical shifts<br />

differences between H-2 <strong>of</strong> D-units <strong>and</strong> the internal reference sodium-(trimethylsilyl)-propionate-d<br />

4 (TSP) as a function <strong>of</strong> pH for chitosan. : F A = 0.01, _: F A = 0.13, <strong>and</strong> : F A = 0.49.<br />

Solid lines indicate logistic regression. (From Str<strong>and</strong>, S.P. et al., Biomacromolecules, 2, 1310,<br />

2001. With permission.)<br />

FIGURE 14.5 Degradation rate constants (k) as a function <strong>of</strong> F A <strong>of</strong> chitosans, determined by<br />

the viscosity assay at a chitosan concentration <strong>of</strong> 1.5 mg/ml in 0.4 M HCl at 60∞C. (From<br />

Vårum, K.M., Ottøy, M.H., <strong>and</strong> Smidsrød, O., Acid hydrolysis <strong>of</strong> chitosans, Carbohydr.<br />

Polym., 46, 89, 2001. With permission).

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