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Chemical and Functional Properties of Food Saccharides

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The ultimate pH <strong>of</strong> meat after rigor mortis may range between 7.0 <strong>and</strong> 4.8.<br />

Usually, pH <strong>of</strong> meat <strong>of</strong> st<strong>and</strong>ard quality ranges between 5.3 <strong>and</strong> 5.8 for pork, veal,<br />

beef, <strong>and</strong> lamb, <strong>and</strong> between 5.8 <strong>and</strong> 6.0 for poultry. 5<br />

The rate <strong>of</strong> postmortem glycolysis in skeletal muscles depends on the temperature<br />

at which the carcass is cooled. Also, composition <strong>of</strong> muscle fiber type; species,<br />

breed, <strong>and</strong> sex <strong>of</strong> animals; resistance to stress; <strong>and</strong> processing <strong>of</strong> the carcass after<br />

slaughter, as, for instance, electrical stimulation, storage temperature, prerigor cutting<br />

<strong>and</strong> curing, influence glycolysis.<br />

The rate <strong>of</strong> glycolysis is higher in white muscle fibers than in the red, because<br />

the activity <strong>of</strong> muscle ATPases in white muscle fibers is higher than it is in red<br />

muscle fibers.<br />

Muscle stimulation associated with the activity <strong>of</strong> the animal prior to its slaughter,<br />

electrical stunning at the time <strong>of</strong> slaughter, <strong>and</strong> electrical stimulation <strong>of</strong> freshly<br />

slaughtered carcass result in intensified release <strong>of</strong> calcium ions from the sarcoplasmic<br />

reticulum <strong>and</strong> mitochondria <strong>and</strong> increase the rate <strong>of</strong> postmortem glycolysis.<br />

The rate <strong>of</strong> postmortem glycolysis in anatomically the same muscles but from<br />

another specimen can be entirely different. It is important in determining the ultimate<br />

properties <strong>and</strong> quality <strong>of</strong> meat (Figure 16.3).<br />

A normal pH decline pattern in porcine muscle is represented by a gradual<br />

decrease from approximately pH 7.4 in living muscle to a pH <strong>of</strong> about 5.6 to 5.7<br />

within 6 to 8 h postmortem, <strong>and</strong> then to ultimate pH (reached at approximately 24<br />

h postmortem) in range <strong>of</strong> 5.3 to 5.7. In some animals, the pH drops only slightly<br />

during the first hour after slaughter <strong>and</strong> remains stable at a relatively high level,<br />

giving an ultimate pH in the range <strong>of</strong> 6.5 to 6.8. In other animals, muscle pH drops<br />

rapidly to around 5.4 to 5.5 during the first hour after exsanguination. Meat from<br />

these animals ultimately develops a pH in the range <strong>of</strong> 5.3 to 5.6.<br />

pH<br />

© 2004 by CRC Press LLC<br />

7.0<br />

6.5<br />

6.0<br />

5.5<br />

5.0<br />

1 2 3 4 5 6 24<br />

Hours Post-Mortem<br />

Meat Quality<br />

Dark, firm, <strong>and</strong> dry<br />

Normal<br />

Pale, s<strong>of</strong>t, <strong>and</strong> exudative<br />

FIGURE 16.3 Effect <strong>of</strong> postmortem pH decline on the meat quality. (Modified from Briskey,<br />

E.J. et al., J. Agric. <strong>Food</strong> Chem., 14, 201, 1966.)

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