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Chemical and Functional Properties of Food Saccharides

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© 2004 by CRC Press LLC<br />

wood would be at disposal after a period <strong>of</strong> reforestation. Finally, whole-tree utilization<br />

combined with a reorganization <strong>of</strong> the paper cycle would supply abundant<br />

ethanol from grassl<strong>and</strong>s, restricting, however, their use as pastures for grazing<br />

animals. Entirely new horizons will be opened for lignin, 21 for example, for selfcrimping<br />

fiber 22 or as an extender for biodegradable polylactides. 14<br />

21.11 CONCLUDING REMARKS<br />

The grass-covered global surface with about 23 × 10 8 ha photosynthesizes a gargantuan<br />

amount <strong>of</strong> polysaccharides (PS), proteins, <strong>and</strong> lignins. If extensively cultivated,<br />

probably half <strong>of</strong> this area would be sufficient to produce enough ethanol to serve as<br />

the world’s fuel source, exceeding the efficiency <strong>of</strong> oil by ca. 85% (electric plus<br />

thermal) when feeding fuel cells, almost doubling the output <strong>of</strong> a Carnot cycle. It<br />

is also astonishing that temperate regions yield much higher PS harvests than the<br />

tropics do. For example, sugar harvest in more south located Cuba yields ca. 2 t/ha<br />

whereas that in more north located Bavaria ca. 12 t/ha despite more intense sunshine<br />

in the South. However, maximal rainfall in the North concentrates closer to the<br />

harvest (20 to 30 in. for agriculture <strong>and</strong> beyond 30 in. for forests) <strong>of</strong> grasses <strong>and</strong><br />

energy crops such as Sudan grass.<br />

Another surprising feature is the amount <strong>of</strong> DM in crops <strong>of</strong> forests (3 t/ha ·<br />

annum) <strong>and</strong> grassl<strong>and</strong>s (7 to 20 t/ha · annum) caused by interaction <strong>of</strong> sunlight <strong>and</strong><br />

chlorophyll but governed by water supply at the right time. Hence, green biorefineries<br />

can replace the present oil flow <strong>of</strong> nearly 3.5 bt/annum by ethanol if the explosive<br />

growth <strong>of</strong> population can be controlled.<br />

A beneficial side effect is the supply <strong>of</strong> proteins up to 15% <strong>of</strong> DM. This<br />

indispensable food component is lost if fermentation produces biogas instead <strong>of</strong><br />

ethanol. At any rate, lignin plus ash return to the soil as a humus preserver, increasing<br />

nitrogen assimilation fourfold. The practice to burn lignin appears in hindsight an<br />

<strong>of</strong>fence against nature.<br />

REFERENCES<br />

1. Osterroth, D., From Coal to Biomass, Springer-Verlag, Berlin, 1989, p. 175.<br />

2. Roeper, H., Renewable raw materials in Europe, Starch/Staerke, 54, 89, 2002.<br />

3. Grove, W., in Elektrochemie, Ostwald, W., Ed., Leipzig, 1896, reprint: H. Deutsch<br />

Verlag, Frankfurt/Main.<br />

4. Verne, J., The Isl<strong>and</strong> <strong>of</strong> Secrets, 1869. Reprinted as Die geheimnisvolle Insel, W.<br />

Heuschen-Villaret, Arena Verlag, Würzburg, 1974.<br />

5. Huppmann, G. <strong>and</strong> Kraus, P., Hot module fuel cells, German Patent DE 4425186<br />

1996.<br />

6. Klemm, P., Discrepancy in discovery <strong>and</strong> consumption <strong>of</strong> oil, Energie-Depesche 16<br />

(3), 37, 2002.<br />

7. New Caxton Encyclopedia, Caxton Publishers, London, 1969, 4995 pp.<br />

8. Sahm, H., Anaerobic degratation <strong>of</strong> halogenated aromatic compunds, Microbiol.<br />

Ecol., 12, 147, 1r986.

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