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Chemical and Functional Properties of Food Saccharides

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© 2004 by CRC Press LLC<br />

cane quality, <strong>and</strong> the type <strong>of</strong> clarifier. The scum from clarifiers (precipitate) is mixed<br />

with the final bagasse, filtered, <strong>and</strong> desweetened on a rotary vacuum filter.<br />

Either sulfitation (addition <strong>of</strong> SO 2) <strong>of</strong> cane juice prior to the liming or liming<br />

prior to the sulfitation is commonly used to achieve mill white sugar. Better sedimentation<br />

<strong>of</strong> slurry is achieved when the sulfitation precedes liming. Calcium sulfite<br />

is precipitated in the process <strong>and</strong> the clarified juice with 12−16% solids is passed<br />

through a multiple-effect evaporator, producing a thick juice containing 60−70% <strong>of</strong><br />

dry substance.<br />

Cane juice, after concentration in evaporators, is <strong>of</strong> lower purity than that <strong>of</strong> the<br />

thick beet juice. It contains more reducing sugars (5−13%) <strong>and</strong> high-molecular<br />

components (0.4−3%). Commercial cane sugar is crystallized in three stages. The<br />

C massecuite is centrifuged in continuous centrifuges to yield C sugar <strong>and</strong> final<br />

molasses. The C sugar <strong>of</strong> about 85% purity is mixed into a magma, which is used<br />

as a seed for the A <strong>and</strong> B crystallization stages.<br />

4.3.1 BY-PRODUCTS AND WASTE<br />

Bagasse is the major by-product in cane sugar production. It is used, first <strong>of</strong> all, as<br />

the source <strong>of</strong> energy available from combustion. Methane can also be produced from<br />

bagasse. Other uses <strong>of</strong> bagasse are composting for fertilizer for cane plantation,<br />

paper <strong>and</strong> board manufacture, <strong>and</strong> cattle fodder. Methods <strong>of</strong> utilization <strong>of</strong> molasses<br />

<strong>and</strong> lime mud are common for both technologies <strong>of</strong> sucrose production.<br />

4.4 PRODUCTION OF OTHER SACCHARIDES<br />

ESSENTIAL IN FOOD TECHNOLOGY<br />

Apart from sucrose, D-fructose, D-glucose, <strong>and</strong> lactose have found wide application<br />

in food technology. Importance <strong>of</strong> D-fructose arises, most importantly, from its<br />

insulin-independent metabolism, nonpromoting formation <strong>of</strong> cavities, <strong>and</strong> hygroscopicity,<br />

the latter frequently employed to preserve moisture in foodstuffs. Its<br />

sweetness, higher than that <strong>of</strong> sucrose (Chapter 5), is an additional advantage <strong>of</strong> that<br />

saccharide. D-Glucose is most commonly used as the source <strong>of</strong> the “fast” energy in<br />

the recovery stage after various medical treatments or strenuous activity. Lactose is<br />

frequently used as a carrier <strong>of</strong> other sweeteners <strong>and</strong> as an additive to improve the<br />

taste <strong>of</strong> dairy products <strong>and</strong> the appearance <strong>of</strong> microwave-heated foodstuffs.<br />

D-Fructose <strong>and</strong> D-glucose are currently produced in biotechnological processes,<br />

preferably from enzymatically saccharified starch (Chapter 10). In the first part <strong>of</strong><br />

the last century, considerable attention was paid to saccharification <strong>of</strong> wood in the<br />

acid-catalyzed processes as the source <strong>of</strong> D-glucose.<br />

Lactose is moderately soluble in water (ca. 20 wt% at 20°C). It is most readily<br />

available from whey (almost the 5% content) by careful evaporation in order to<br />

achieve crystals in the preferred β form. Fast evaporation results in the crystalline<br />

α form <strong>of</strong> lactose which, when present in food, produces s<strong>and</strong>iness.

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