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Chemical and Functional Properties of Food Saccharides

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3<br />

CONTENTS<br />

© 2004 by CRC Press LLC<br />

<strong>Saccharides</strong>: Modifications<br />

<strong>and</strong> Applications<br />

Ya-Jane Wang<br />

3.1 Introduction<br />

3.2 Sugar Alcohols <strong>and</strong> Polydextrose<br />

3.3 Caramels<br />

3.4 Saccharide Ethers<br />

3.5 Fatty Acid Esters<br />

3.6 Fatty Acid Polyesters<br />

3.7 Physicochemical <strong>Properties</strong> <strong>and</strong> Applications<br />

3.7.1 Sugar Alcohols<br />

3.7.2 Polydextrose<br />

3.7.3 Saccharide Ethers<br />

3.7.4 Fatty Acid Esters<br />

3.7.4.1 Emulsifying <strong>Properties</strong><br />

3.7.4.2 Complex Formation <strong>of</strong> Sucrose Esters with Starch<br />

<strong>and</strong> Proteins<br />

3.7.4.3 Antimicrobial <strong>Properties</strong> <strong>of</strong> Sucrose Fatty Acid Esters<br />

3.7.5 Fatty Acid Polyesters<br />

References<br />

3.1 INTRODUCTION<br />

The massive availability <strong>of</strong> saccharides, mainly sucrose <strong>and</strong> D-glucose, has made<br />

them attractive sources for many products. Natural biodegradability <strong>and</strong> versatility<br />

<strong>of</strong> saccharides <strong>and</strong> health awareness were principal factors stimulating consumer<br />

attempts to reduce uptake <strong>of</strong> the calorie food. Response from industry resulted in<br />

reduction <strong>of</strong> energy in processed food products. Several technologies were developed,<br />

which were based on the processing <strong>of</strong> sucrose <strong>and</strong> D-glucose into sugar<br />

substitutes (e.g., sugar alcohols), food flavoring ingredients <strong>and</strong> colorants (e.g.,<br />

caramels), surfactants, emulsifiers, <strong>and</strong> fat replacers (saccharide ethers with longchain<br />

alkyl groups, fatty acid esters, <strong>and</strong> polyesters <strong>of</strong> saccharides). The processing<br />

involves either biochemical (see Chapter 10) or chemical methods.

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