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Chemical and Functional Properties of Food Saccharides

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A<br />

B<br />

PAD signal<br />

PAD signal<br />

© 2004 by CRC Press LLC<br />

0 50 100 150 200<br />

Retention time (min)<br />

0 50 100 150 200<br />

Retention time (min)<br />

FIGURE 7.2 Anion-exchange chromatograms <strong>of</strong> Naegeli dextrins prepared from an A-type<br />

crystalline starch, waxy maize (A), <strong>and</strong> a B-type crystalline starch ae-waxy maize (B). The<br />

Naegeli dextrins are prepared <strong>and</strong> analyzed according to the methods reported in Jane, J.,<br />

Wong, K.-S., <strong>and</strong> McPherson, A.E., Carbohydr. Res., 300, 219, 1997.<br />

structures reflect that many branch linkages, carrying short chains, are present within<br />

the crystalline region <strong>of</strong> amylopectin clusters in A-type starch. In contrast, there are<br />

few branch linkages carrying short branch chains present in B-type starches. 44 These<br />

observed branch structures <strong>of</strong> amylopectin molecules are in good agreement with<br />

the fact that A-type starches consist <strong>of</strong> more short chains than do B-type starches.

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