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Chemical and Functional Properties of Food Saccharides

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Mass Fraction<br />

© 2004 by CRC Press LLC<br />

1.2<br />

0.9<br />

0.6<br />

0.3<br />

0<br />

0.5 1 1.5 2<br />

lg(dp)<br />

FIGURE 13.4 Degree <strong>of</strong> polymerization distribution (m_dpD_d) for inulin from chicory by<br />

calibrated SEC (for details see Figure 13.3). ææ: Raftilin ® ST (commercial product), mean<br />

values <strong>of</strong> DP from m_dpD_d are DP w = 15, DP n = 7 (including mono- <strong>and</strong> disaccharides);<br />

ææ: Raftilin ® HP (commercial product), mean values <strong>of</strong> DP from m_dpD_d are DP w =<br />

34, DP n = 24 (including mono- <strong>and</strong> disaccharides).<br />

Chicory is used in several applications. Combination <strong>of</strong> bitter compounds <strong>and</strong><br />

fructans from sliced chicory roots with additional ingredients such as malt, barley,<br />

<strong>and</strong> fig in a roasting process provides a “healthy” <strong>and</strong> compliant c<strong>of</strong>fee surrogate.<br />

Hydrolytic depolymerization <strong>of</strong> inulin to fructose even provides basic material for<br />

manufacturing nutrition products for diabetics.<br />

Nondigestibility <strong>of</strong> inulin in the human intestinal tract makes this material a tool<br />

to test renal clearance. In the last decade, the fact <strong>of</strong> indigestibility became increasingly<br />

interesting from the point <strong>of</strong> view <strong>of</strong> soluble dietary fibers. As consumer request<br />

for functional <strong>and</strong> healthy food increases exponentially, tailored fructooligosaccharides<br />

<strong>and</strong> inulin perfectly match the request <strong>of</strong> application pr<strong>of</strong>iles <strong>of</strong> prebiotic<br />

goods in various market segments (Figure 13.4). Domination <strong>of</strong> large-scale fructan<br />

production from chicory is supported by the relatively simple cultivation <strong>of</strong> the crops,<br />

easy harvesting <strong>of</strong> the roots, <strong>and</strong> utilization <strong>of</strong> existing sugar beet processing technology.<br />

The most crucial point in isolation <strong>and</strong> purification <strong>of</strong> inulin is the quantitative<br />

elimination <strong>of</strong> salts <strong>and</strong> bitter compounds. Finally obtained distribution <strong>of</strong><br />

fructan polymers may be controlled by chicory cultivar <strong>and</strong> period <strong>of</strong> harvesting <strong>and</strong><br />

may be determined prior to harvesting by chromatography. 25,26<br />

Isolation <strong>of</strong> inulin-type fructans from chicory by hot-water extraction from sliced<br />

chicory roots runs similar to the processing <strong>of</strong> sugar beets. Their current annual<br />

production is ca. 100,000 t <strong>and</strong> is on the rise. If specific distribution pr<strong>of</strong>iles <strong>of</strong> inulin

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