Chemical and Functional Properties of Food Saccharides
Chemical and Functional Properties of Food Saccharides
Chemical and Functional Properties of Food Saccharides
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© 2004 by CRC Press LLC<br />
orographic (mountains cause windward rains), or cyclonic rains. The last type<br />
prevails in temperate latitudes, yielding water steadily pouring out <strong>of</strong> dull, overcast<br />
skies, <strong>and</strong> in winter as snow, sleet, or hail. Cyclonics reach their main precipitation<br />
between latitudes <strong>of</strong> 45 <strong>and</strong> 55°North, primarily in the Northern Hemisphere, with<br />
a preponderance <strong>of</strong> summer rainfall. 7<br />
Forests <strong>and</strong> grassl<strong>and</strong>s represent the two major vegetations. The former stabilize<br />
the climate, including moisture or dust content <strong>of</strong> air <strong>and</strong> the water table. The role<br />
<strong>of</strong> grassl<strong>and</strong>s is less appreciated. For example, most authors credit 90% <strong>of</strong> the<br />
planetary biomass to forests — allegedly 50 × 10 9 t 1 — <strong>of</strong> which only 2.3 × 10 6 t<br />
(4.5%) is consumed by humans 2 , primarily as fuel in the Third World besides timber<br />
<strong>and</strong> pulp for paper in the First World.<br />
Regarding wood as a possible energy source, one has to consider that only 14<br />
to 18% <strong>of</strong> forests are accessible. About 1 to 2 × 10 5 km 2 <strong>of</strong> tropical forests are<br />
eradicated yearly. The annual yield per hectare declines from the tropical 20 t<br />
wood/ha to merely 3 t/ha in Central Europe (timber quality) <strong>and</strong> still less in Northern<br />
Europe (1 to 2 t/ha). However, improved forest management <strong>and</strong> reforestation could<br />
possibly double the timber harvest. Complementing such endeavors could be the<br />
perfection <strong>of</strong> the burgeoning technique to utilize whole trees, rendering their lignin<br />
<strong>and</strong> carbohydrates into saleable products to boost the revenues per hectare to be<br />
reinvested in forestry.<br />
As regards grassl<strong>and</strong>s, one has to discern drier (steppe) <strong>and</strong> moister (prairies)<br />
areas allowing trees to grow turning to a savannah, whereas vanishing precipitation<br />
diverts the steppe to desert. The total grass-bearing surface is estimated to cover a<br />
fifth <strong>of</strong> all continents close to 30 × 10 6 km 2 , including the mentioned 23 × 10 6 km 2<br />
attended by farmers or stock-breeders for animals, etc. For extensively cultivated<br />
grassl<strong>and</strong>s, a biomass <strong>of</strong> 4 t/ha <strong>of</strong> dry matter (DM) can be interpreted as modest.<br />
Nevertheless, even by such an assumption, nearly 12 × 10 9 t <strong>of</strong> DM/ha would contain<br />
at least 50% <strong>of</strong> cellulosics capable <strong>of</strong> yeilding 3 × 10 9 t <strong>of</strong> ethanol, energetically<br />
virtually equivalent to oil if upgraded by burning in fuel cells, furnishing electric<br />
<strong>and</strong> thermal power approaching almost the 7.3 billion OE spent in 2001. 2 The<br />
supervised, <strong>and</strong>, if intensively cultivated, grassl<strong>and</strong>s in temperate zones would be<br />
capable <strong>of</strong> producing between 7 <strong>and</strong> 12 t <strong>of</strong> DM/ha, possibly amounting to a global<br />
23 × 10 6 km 2 , bearing ca. 23 × 10 6 km 2 × 10 2 ha × 10 t/ha = 20–23 × 10 9 t <strong>of</strong><br />
DM/ha made up <strong>of</strong> approximately 60% polysaccharides, 15% lignin, 10–15% ashes,<br />
<strong>and</strong> 10% protein. Such polysaccharides include a soluble fraction <strong>and</strong> solid fibers,<br />
both convertible to ethanol, whereas proteins are suitable for forage <strong>and</strong> human food<br />
(especially the rubisco-fraction rich in magnesium). Lignin <strong>and</strong> ash are returned to<br />
the soil, furthering humus <strong>of</strong> enhanced nitrogen assimilation.<br />
The actual share <strong>of</strong> grass-bearing l<strong>and</strong>s is closer to 25% (37 × 10 6 km 2 ) <strong>of</strong> the<br />
terrestrial surface because large sections <strong>of</strong> arable l<strong>and</strong> bear grasses such as cereals,<br />
corn, sugarcane, or bamboo. Cereals in temperate zones yield 3 to 4 t/ha <strong>of</strong> starch<br />
crops compared to sugar from cane <strong>of</strong> 1 to almost 9 t/ha (in Hawaii), depending on<br />
soil, age <strong>of</strong> crop, sunshine, <strong>and</strong> rain. Carbohydrates stored below the surface <strong>of</strong> soil<br />
furnish even more starch, for example, potatoes about 6 to 7 t/ha starch or sugar<br />
beets up to 12 t/ha pure sugar. Obviously, intensive agriculture yields impressively<br />
more carbohydrates than extensive forest management in northern latitudes. Wood