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Chemical and Functional Properties of Food Saccharides

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1<br />

CONTENTS<br />

© 2004 by CRC Press LLC<br />

<strong>Saccharides</strong> <strong>and</strong><br />

Polysaccharides:<br />

An Introduction<br />

Piotr Tomasik<br />

1.1 Occurrence <strong>and</strong> Significance<br />

1.2 Carbohydrates as a Class <strong>of</strong> Compounds<br />

1.3 Further Remarks on the Structure<br />

1.4 <strong>Food</strong> Carbohydrates<br />

References<br />

1.1 OCCURRENCE AND SIGNIFICANCE<br />

Carbohydrates, one <strong>of</strong> the most common groups <strong>of</strong> natural products, are construction<br />

materials for plant (cellulose, hemicelluloses, pectins) <strong>and</strong> animal tissues.<br />

They are the sources <strong>of</strong> energy <strong>and</strong> storage material in flora (starch, inulin) <strong>and</strong><br />

fauna (glycogen).<br />

Several specific carbohydrates are utilized in nature, for instance, as watermaintaining<br />

hydrocolloids, sex attractants (pheromones), <strong>and</strong> others formed by photosynthesis<br />

<strong>and</strong> associated processes. Some <strong>of</strong> them are subsequently utilized by<br />

plants, which transform them into other products; for instance, some plants may turn<br />

D-galactose into ascorbic acid, or some carbohydrates reside in plants as final<br />

products <strong>of</strong> photosynthesis <strong>and</strong> metabolism. Several <strong>of</strong> them are interesting for their<br />

pharmacological properties.<br />

The list <strong>of</strong> known natural carbohydrates is continuously growing, owing to new<br />

discoveries in animal <strong>and</strong>, particularly, plant material. Recently, two novel polysaccharides<br />

have been isolated from deep-sea hydrothermal microorganisms. 1,2 Their<br />

unique thickening <strong>and</strong> gelling properties make them suitable for future commercialization.<br />

The number <strong>of</strong> synthetic <strong>and</strong> semisynthetic carbohydrates is also growing. Several<br />

interesting features <strong>of</strong> the biological activity <strong>and</strong> functional properties <strong>of</strong> natural<br />

carbohydrates are the driving force for designing products <strong>of</strong> novel structure with<br />

improved properties. For example, syntheses <strong>of</strong> carbohydrate derivatives with heparin-like<br />

properties are being continuously developed. There are also a number <strong>of</strong>

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