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Chemical and Functional Properties of Food Saccharides

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10<br />

CONTENTS<br />

© 2004 by CRC Press LLC<br />

Enzymatic Conversions<br />

<strong>of</strong> Carbohydrates<br />

Stanislaw Bielecki<br />

10.1 Introduction<br />

10.2 Enzymes Involved in Conversions <strong>of</strong> Carbohydrates<br />

10.2.1 Glycoside Hydrolases<br />

10.2.2 Glycosyltransferases<br />

10.2.3 Glycansucrases<br />

10.2.4 Mechanisms <strong>of</strong> Glycosidic Bond Hydrolysis<br />

<strong>and</strong> Transglycosylation<br />

10.2.5 Glycosynthases<br />

10.2.6 Other Sugar-Converting Enzymes<br />

10.2.6.1 Synthesis <strong>of</strong> Monosaccharides<br />

10.2.6.2 Selected Conversions Catalyzed by Oxidoreductases<br />

10.3 Oligosaccharides<br />

10.3.1 Fructooligosaccharides<br />

10.3.2 Isomaltooligosaccharides<br />

10.3.3 Galactooligosachharides<br />

10.4 Polysaccharides<br />

10.4.1 Starch<br />

10.4.1.1 Common <strong>Properties</strong> <strong>of</strong> the a-Amylase Family<br />

<strong>of</strong> Enzymes<br />

10.4.1.2 a-Amylases<br />

10.4.1.3 Exo-Acting Enzymes<br />

10.4.1.4 Debranching Enzymes<br />

10.4.1.5 Cyclodextrins <strong>and</strong> Cycloamyloses<br />

10.4.1.6 Trehalose<br />

10.4.1.7 Other Starch Conversions<br />

10.4.2 Cellulose, Chitin, <strong>and</strong> Chitosan<br />

10.4.3 Pectin<br />

10.4.4 Xylan<br />

10.4.5 Fructans<br />

References

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