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|7 Appendix|<br />

Ru(tpphz)Os [Ru(bpy) 2 (µ-tpphz)Os(bpy) 2 ] 4+<br />

Ru(bbip)Ag [Ru(tbbpy) 2 (µ-bbip)AgCl] 2+<br />

Ru(tpphz) [Ru(phen) 2 (tpphz)] 2+ vs. versus<br />

Ru(bbip)Pd [Ru(tbbpy) 2 (µ-bbip)PdCl 2 ] 2+<br />

Ru(bbip)Rh [Ru(tbbpy) 2 (µ-bbip)Rh(cod)Cl] 2+<br />

Ru(bip) [Ru(tbbpy) 2 (bip)] 2+<br />

Ru(tpphz)Pd [Ru(tbbpy) 2 (µ-tpphz)PdCl 2 ] 2+<br />

Ru(tpphz)Pt [Ru(tbbpy) 2 (µ-tpphz)PtCl 2 ] 2+<br />

Ru(tpphz)Ru [{Ru(phen) 2 } 2 (µ-tpphz)] 4+<br />

Ru(Br 2 bip) [Ru(tbbpy) 2 (Br 2 bip)] 2+<br />

S, s singulett<br />

Ru(Br 2 bbip) [Ru(tbbpy) 2 (Br 2 bbip)] 2+<br />

S (sacrificial) substrate<br />

Ru(Br 2 phen) [Ru(tbbpy) 2 (Br 2 phen)] 2+<br />

SCE saturated calomel electrode<br />

Ru(phen) [Ru(tbbpy) 2 (phen)] 2+<br />

sh shoulder<br />

Ru(phenCl) [Ru(tbbpy) 2 (5-chloro-1,10-<br />

T, t triplett<br />

phenanthroline)] 2+<br />

tbbpy 4,4’-di-tertbutyl-2,2’-bipyridine<br />

Ru(phenBr) [Ru(tbbpy) 2 (phenBr)] 2+<br />

TCD thermal conductivity detector<br />

Ru(phenBr 2 ) [Ru(tbbpy) 2 (phenBr 2 )] 2+<br />

Ru(phenBr 4 ) [Ru(tbbpy) 2 (phenBr 4 )] 2+<br />

THF tetrahydrofuran<br />

Ru(phenBr 2 ) 2 [Ru(tbbpy)(phenBr 2 ) 2 ] 2+<br />

TLC thin layer chromatography<br />

Ru(phenBr 2 ) 2 Cl 2 [Ru(phenBr 2 ) 2 Cl 2 ]<br />

TOF turnover frequency<br />

Ru(phenBr 2 ) 3 [Ru(phenBr 2 ) 3 ]<br />

TON turnover number<br />

Ru(phenphen) [Ru(tbbpy) 2 (phenphen)] 2+<br />

Ru(phenphen)Pt<br />

tpphz tetrapyrido[3,2-a:2’,3’-c:3”,2”-h:2”’,3”’-<br />

j]phenazine<br />

[Ru(tbbpy) 2 (µ-phenphen)PtCl 2 ] 2+ tpy the 2,2’;6’,2”-terpyridine<br />

Ru(phenphen)Ru<br />

UV ultraviolet<br />

[{Ru(tbbpy) 2 } 2 (µ-phenphen)] 4+ v volume<br />

Ru’(phenphen)Ru’ [{Ru(bpy) 2 } 2 (µ-phenphen)] 4+ Vis, VIS visible<br />

|240|

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