|References| [53] J. Barber, Phil. Trans. R. Soc. A, (2007), 365(1853), 1007–1023. [54] J. T. Muckerman, D. E. Polyansky, T. Wada, K. Tanaka, E. Fujita, Inorg. Chem., (2008), 47(6), 1787–1802. [55] F. Liu, J. J. Concepcion, J. W. Jurss, T. Cardolaccia, J. L. Templeton, T. J. Meyer, Inorg Chem., (2008), 47(6), 1727–1752. [56] G. Zhang, R. Zong, H.-W. Tseng, R. P. Thummel, Inorg. Chem., (2008), 47(3), 990–998. [57] L. Li, L. Duan, Y. Xu, M. Gorlov, A. Hagfeldt, L. Sun, Chem. Commun., (2010), 46(39), 7307–7309. [58] L. Duan, Y. Xu, P. Zhang, M. Wang , L. Sun, Inorg. Chem., (2010), 49(1), 209–215. [59] X. Chen, S. Shen, L. Guo, S. S. Mao, Chem. Rev., (2010), 110(11), 6503–6570. [60] J. C. Gordon, G. J. Kubas, Organometallics, (2010), 29(21), 4682–4701. [61] J. R. Bolton, Solar Energy, (1996), 57(1), 37– 50. [62] W. J. Youngblood, S.-H. A. Lee, K. Maeda, T. E. Mallouk, Acc. Chem. Res., (2009), 42(12), 1966–1973. [63] L.-C. Song, X. Luo, Y.-Z. Wang, B. Gai, Q.- M. Hu, Journal of Organometallic Chemistry, (2009), 694(1), 103–112. [64] R. K. Thauer, A.-K. Kaster, M. Goenrich, M. Schick, T. Hiromoto, S. Shima, Annu. Rev. Biochem., (2010), 79, 507–536. [65] C. M. Thomas, T. Liu, M. B. Hall, M. Y. Darensbourg, Inorg. Chem., (2008), 47(15), 7009–7024. [66] P. Zhang, M. Wang, Y. Na, X. Li, Y. Jiang, L. Sun, Dalton Trans., (2010), 39(5), 1204–1206. [67] J. W. Peters, Science, (1998), 282(5395), 1853– 1858. [68] C.-Y. Liu, P. Knochel, The Journal of organic chemistry, (2007), 72(19), 7106–15. [69] A. F. Heyduk, D. G. Nocera, Science, (2001), 293(5535), 1639–1641. [70] L. Duan, M. Wang, P. Li, Y. Na, N. Wang, L. Sun, Dalton Trans., (2007), (13), 1277–1283. [71] S. Hansen, (2009). Ph.D. thesis. [72] J.-m. Lehn, Angew. Chem. Int. Ed., (1988), 27(1), 89–112. [73] D. J. Cram, Angew. Chem. Int. Ed., (1988), 27(8), 1009–1020. [74] C. J. Pedersen, Angew. Chem. Int. Ed., (1988), 27(8), 1021–1027. [75] G. Accorsi, N. Armaroli, V. Balzani, G. Bergamini, S. Campagna, F. Cardinali, C. Chiorboli, M. Indelli, N. A. P. Kane-Maguire, A. Listorti, F. Nastasi, F. Puntoriero, F. Scandola, Topics in Current Chemistry: Photochemistry, Photophysics of Coordination Compounds I, Vol. 280 of Topics in Current Chemistry, V. Balzani, S. Campagna, (Eds.), (2007), Springer Berlin Heidelberg, Berlin, Heidelberg, p. 265. [76] M. R. Wasielewski, Chemical Reviews, (1992), 92(3), 435–461. [77] J. P. Sauvage, J. P. Collin, J. C. Chambron, S. Guillerez, C. Coudret, V. Balzani, F. Barigelletti, L. De Cola , L. Flamigni, Chem. Rev., (1994), 94(4), 993–1019. [78] S. Campagna, S. Serroni, S. Bodige, F. M. MacDonnell, Inorg. Chem., (1999), 38(4), 692–701. [79] C. Chiorboli, M. a. J. Rodgers, F. Scandola, Journal of the American Chemical Society, (2003), 125(2), 483–91. [80] S. Rau, B. Schäfer, D. Gleich, E., ers, M. Rudolph, M. Friedrich, H. Görls, W. Henry, J. G. Vos, Angew. Chem. Int. Ed., (2006), 45(37), 6215–6218. |243|
|References| [81] S. Tschierlei, M. Presselt, C. Kuhnt, A. Yartsev, T. Pascher, V. Sundström, M. Karnahl, M. Schwalbe, B. Schäfer, S. Rau, M. Schmitt, B. Dietzek, J. Popp, Chem. Eur. J., (2009), 15(31), 7678–7688. [82] H. Ozawa, M.-a. Haga, K. Sakai, J. Am. Chem. Soc., (2006), 128(15), 4926–4927. [83] S. Rau, D. Walther, J. G. Vos, Dalton Trans., (2007), (9), 915–919. [84] M. Elvington, J. Brown, S. M. Arachchige, K. J. Brewer, J. Am. Chem. Soc., (2007), 129(35), 10644–10645. [85] A. Fihri, V. Artero, A. Pereira, M. Fontecave, Dalton Trans., (2008), (41), 5567–5569. [86] A. Fihri, V. Artero, M. Razavet, C. Baffert, W. Leibl, M. Fontecave, Angew. Chem. Int. Ed., (2008), 47(3), 564–567. [87] C. Li, M. Wang, J. Pan, P. Zhang, R. Zhang, L. Sun, J. Organomet. Chem., (2009), 694(17), 2814–2819. [88] S. Tschierlei, M. Karnahl, M. Presselt, B. Dietzek, J. Guthmuller, L. González, M. Schmitt, S. Rau , J. Popp, Angew. Chem., (2010), 122(23), 4073–4076. [89] B. Schäfer, <strong>Dissertation</strong>, (2006), Friedrich- Schiller-Universität Jena, p. 218. [90] M. Schwalbe, <strong>Dissertation</strong>, (2007), Friedrich- Schiller-Universität Jena, p. 194. [91] S. M. Arachchige, J. R. Brown, E. Chang, A. Jain, D. F. Zigler, K. Rangan, K. J. Brewer, Inorg. Chem., (2009), 48(5), 1989–2000. [92] S. Jasimuddin, T. Yamada, K. Fukuju, J. Otsuki, K. Sakai, Chem. Commun., (2010). [93] H. Ozawa, Y. Yokoyama, M.-a. Haga, K. Sakai, Dalton Trans., (2007), (12), 1197–206. [94] P. Lei, M. Hedlund, R. Lomoth, H. Rensmo, O. Johansson, L. Hammarström, J. Am. Chem. Soc., (2008), 130(1), 26–27. [95] T. D. Pilz, N. Rockstroh , S. Rau, J. Coord. Chem., (2010), 63(14), 2727–2742. [96] A. Bencini, V. Lippolis, Coord. Chem. Rev., (2010), 254(17-18), 2096–2180. [97] M. Yamada, Y. Nakamura, S. Kuroda, I. Shimao, Bull. Chem. Soc. Jpn., (1990), 63(9), 2710–2712. [98] M. Schmittel, A. Ganz, D. Fenske, Org. Lett., (2002), 4(14), 2289–2292. [99] R. Zong, R. P. Thummel, J. Am. Chem. Soc., (2004), 126(35), 10800–10801. [100] R. Zong, R. P. Thummel, Inorg. Chem., (2005), 44(17), 5984–5986. [101] G. Ambrosi, M. Formica, V. Fusi, L. Giorgi, A. Guerri, M. Micheloni, P. Paoli, R. Pontellini, P. Rossi, Inorg. Chem., (2007), 46(11), 4737– 4748. [102] C. Bazzicalupi, A. Bencini, S. Ciattini, C. Giorgi, A. Masotti, P. Paoletti, B. Valtancoli, N. Navon, D. Meyerstein, Dalton Trans., (2000), (14), 2383–2391. [103] D. L. Melton, D. G. Vanderveer, R. D. Hancock, Inorg. Chem., (2006), 45(23), 9306– 9314. [104] M. Schmittel, A. Ganz, D. Fenske, M. Herderich, Dalton Trans., (2000), (3), 353– 359. [105] J.-p. Sauvage, Acc. Chem. Res., (1998), 31(10), 611–619. [106] D. Tzalis, Y. Tor, S. Failla, J. S. Siegel, Tetrahedron Lett., (1995), 36(20), 3489–3490. [107] D. Tzalis, Y. Tor, Chem. Commun., (1996), (9), 1043–1044. [108] B. Schäfer, H. Görls, S. Meyer, W. Henry, J. G. Vos, S. Rau, Eur. J. Inorg. Chem., (2007), 2007(25), 4056–4063. [109] M. Schmittel, A. Ganz, Synlett, (1997), 1997(6), 710–712. |244|
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Development of Novel Catalysts for
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Diese Arbeit entstand auf Anregung
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Den Arbeisgruppen von Prof. Dr. U.
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Contents 1 Introduction 1 1.1 Fossi
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|Contents| 6 Experimental Section 1
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|1 Introduction| 1 Introduction The
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|1.1 Fossil Fuels and Nuclear Power
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|1.2 Renewable Fuels| of natural ga
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|1.3 Energy Transformation and Stor
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|1.4 Solar Energy Conversion| A fra
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|1.5 Photosynthesis| Figure 9: Mole
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|1.6 Photocatalyzed Reactions| 2 NA
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|1.6 Photocatalyzed Reactions| (1)
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|1.7 Mimicking Photosynthesis| So t
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|1.8 Formalisms of Photocatalytic S
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|1.9 Multicomponent Systems from Fu
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|1.9 Multicomponent Systems from Fu
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|1.9 Multicomponent Systems from Fu
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|1.9 Multicomponent Systems from Fu
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|1.9 Multicomponent Systems from Fu
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|1.9 Multicomponent Systems from Fu
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|1.10 Intramolecular Photoredoxcata
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|1.10 Intramolecular Photoredoxcata
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|1.10 Intramolecular Photoredoxcata
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|1.10 Intramolecular Photoredoxcata
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|1.10 Intramolecular Photoredoxcata
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|1.10 Intramolecular Photoredoxcata
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|2 Scope of the Thesis| motifs with
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|3.1 Brominated Phenanthrolines - A
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|3.1 Brominated Phenanthrolines - A
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|3.1 Brominated Phenanthrolines - A
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|3.2 Bisphenanthroline: A Suitable
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|3.2 Bisphenanthroline: A Suitable
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|3.2 Bisphenanthroline: A Suitable
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|3.2 Bisphenanthroline: A Suitable
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f f f f f f |3.2 Bisphenanthroline:
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|3.2 Bisphenanthroline: A Suitable
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|3.2 Bisphenanthroline: A Suitable
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|3.2 Bisphenanthroline: A Suitable
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|3.2 Bisphenanthroline: A Suitable
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|3.2 Bisphenanthroline: A Suitable
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|3.3 NN-NHC-Ligand bbip: Toward Sec
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|3.3 NN-NHC-Ligand bbip: Toward Sec
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|3.3 NN-NHC-Ligand bbip: Toward Sec
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|3.3 NN-NHC-Ligand bbip: Toward Sec
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|3.4 Outlook, Exploratory Investiga
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|3.4 Outlook, Exploratory Investiga
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|3.4 Outlook, Exploratory Investiga
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|3.4 Outlook, Exploratory Investiga
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|3.4 Outlook, Exploratory Investiga
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|3.4 Outlook, Exploratory Investiga
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|3.4 Outlook, Exploratory Investiga
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|4 Summary| 4 Summary Against the b
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|4 Summary| The resulting complexes
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|4 Summary| 10 [TEA] + TEA visible
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|4 Summary| absorption between 430
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|4 Summary| additional NN- and NHC-
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|5 Zusammenfassung| Die Herstellung
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|5 Zusammenfassung| phenphen und Ru
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|5 Zusammenfassung| Fragment tragen
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|5 Zusammenfassung| [TEA] + TEA vis
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