Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

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PP-48INVESTIGATION OF NEW WAYS OF BIODIESEL PRODUCTIONRomanova Anastasiya 1 , Khanikyan Vago 2 , Kustov Andrey 3 , Sapunov Valentin 41 D.I. Mendeleyev University of Chemical Technology of Russia, Moscow,liceistka2003@mail.ru, +7(499)77969732 A.N. Nesmeyanov Institute of Organoelement Compounds RAS, Moscow,vagokhan@rambler.ru, +7(499)77969733 "VEGA-CHEM" Ltd., Moscow, koustov@muctr.edu.ru, +7(499)97895544 "VEGA-CHEM" Ltd., Moscow, sapunovvals@gmail.com, +7(499)9789554Biodiesel is a renewable diesel fuel that is also known as FAME (fatty-acid methylester) in the European Community. Biodiesel has the advantage that it works just aswell as normal diesel fuel, but the combustion process expels lower concentrations oftoxic emissions. It is made from animal fats, vegetable oils or recycled restaurantgreases. As is known, the traditional technologies for Biodiesel manufacture haveseveral disadvantages. For example, there are very stringent requirements onavailability of water and free fatty acids (FFA) in raw vegetable oil in case ofhomogeneous alkaline catalysis using. The large ratio of Methanol/ Oil, hightemperature and pressure and also a relatively short lifetime of the catalyst are themain disadvantages of technology of heterogeneous catalysis. For decision of theabove enumerated questions, we have carried out various studies usingheterogeneous and homogeneous catalysis as well. The most interesting results wehave obtain by using FA salts of lead (II) as a homogeneous catalysis. This variant ofprocess design allows carrying out the transesterification of vegetable oil in relativelymild conditions and in presence of any quantity of FFA in the feedstock. In addition,using of lead (II) salts in contrast to the alkali catalysts excludes, practically, theproblems, which associated with the stages of phase separation of the final productsin case of transesterification of vegetable oils by other lower alcohols. Analysis ofdistribution of lead compounds in the reaction products and their comparison with theobtained kinetic regularities of the process, allowed us to offer a variant of reuse ofthe catalyst, which makes this technology attractive also.138
PROCESS FOR THE PREPARATION OF BIOFUEL BYDECARBOXYLATION OF NATURAL CARBOXYLIC ACIDSRomanova Anastasiya, Shvets Valeriy, Suchkov Yury, Korneev IgorD.I. Mendeleev University of Chemical Technology of Russia, Mosсow,Miusskaya sq., 9, liceistka2003@mail.ruPP-49The world’s fossil fuel resources – including crude oil, natural gas and coal – arehuge, however they will be exhausted sooner or later. There is already fossil fueldeficit leading to a rise of motor fuel prices. As a result use of renewable energysources expands steadily. Thus, the most significance acquires a biofuel producedfrom vegetable oils, animal fats, or its derivatives, particularly, fatty acids.In literature there are a lot of works devoted to the process of producing thebiofuel engine (biodiesel, ethanol, methanol etc.) In the current report we presentresults of investigation of process for production of biofuel by decarboxylation of fattyacids, which in perspective should be a key stage in obtaining hydrocarbonscontaining 15-21 carbon atoms. This type of fuel can be termed as biofuel IIgeneration.The influence of reaction conditions (such as temperature, pressure, catalyst typeand feed rate of stock) on conversion and selectivity of process decarboxylation offatty acids was investigated and optimal ranges of these parameters weredetermined.As a catalyst the series of compounds from a number of industrial catalysts ofhydrorefining, individual and supported zeolites and many others, were tested. It wasfound that the most efficient catalysts are γ-alumina and supported zeolites, whichcan be recycled.139
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Boreskov Institute of Catalysis SB
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International Scientific CommitteeV
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PL-1DESIGN OF CATALYSTS AND CATALYT
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PL-3CATALYTIC TRANSFORMATIONS FOR P
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PL-4In this contribution the princi
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PL-5THEORETICAL AND EXPERIMENTAL AN
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PL-6heat exchanging internals; dyna
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CATALYTIC CRACKING OF SUNFLOWER SEE
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KN-3CONVERSIONS OF WOOD AND CELLULO
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CATALYTIC FUEL-GAS CLEANING IN A ST
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BIO4ENERGY - THE SWEDISH QUESTFOR S
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ORAL PRESENTATIONSSection 1.CATALYS
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OP-1-2METHANOLYSIS OF VEGETABLE OIL
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OP-1-4SYNTHESIS, CHARACTERIZATION A
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OP-1-6THE PRODUCTION OF MOTOR FUEL
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HYDROTREATMENT CATALYSTS DESIGN FOR
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CATALYTIC HYDROTREATING OF FAST PYR
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OP-1-11BIOMASS’ PRODUCTS TREATMEN
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OP-1-14BIO-ETHANOL - PETROCHEMICAL
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OP-1-15USING BIOMASS-BASED FUELS FO
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OP-2-1COMBINATION OF METAL AND ACID
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OP-2-3CELLULOSE HYDROTHERMAL CONVER
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OP-2-4CATALYTIC CONVERSION OF CONCE
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OP-2-6KINETICS OF SELECTIVE OXIDATI
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OP-2-8PROCESS FOR THE PRODUCTION OF
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OP-2-10BIODERIVED LACTIC ACID AND L
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OP-2-11CATALYTIC CONVERSION OF HEMI
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OP-2-13Cu CATALYSTS FOR HYDROGENOLY
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OP-2-15Cu-CONTAINING CATALYSTS FOR
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OP-2-16MICROWAVE-ASSISTED EPOXIDATI
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OP-2-18ULTRASOUND-INDUCED FORMATION
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OP-2-20EFFECT OF Ag DOPING IN La-Mn
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OP-2-22INSIGHTS IN GLYCEROL REFORMI
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OP-3-1APPLICATION OF NOVEL CATALYST
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OP-3-2REDUCING CONVERSIONS OF GLYCE
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OP-3-4LOW-TEMPERATURE CONVERSION OF
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OP-3-6H 2 PRODUCTION BY STEAM REFOR
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OP-3-8CATALYTIC STEAM REFORMING OF
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OP-3-10CATALYTIC GAS PHASE CONVERSI
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ORAL PRESENTATIONSSection 4.BIOCATA
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OP-4-2THE EFFECT OF OXYGEN MASS TRA
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OP-4-4VALORIFICATION OF FERMENTATIO
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OP-4-5MECHANISM OF ULTRASOUND-ASSIS
Page 88 and 89: PP-1THE ORTHO - PARA CONVERSION OF
Page 90 and 91: PP-3THREE-STAGE WASTE-FREE PROCESS
Page 92 and 93: PP-4Н 2 О with formation superflu
Page 94 and 95: PP-6HYDROGEN FROM FORMIC ACID DECOM
Page 96 and 97: PP-8VALORIZATION OF GLYCEROL BY CON
Page 98 and 99: PP-10BIODIESEL PRODUCTION FROM WAST
Page 100 and 101: PP-11Figure 1. CHEMPAK architecture
Page 102 and 103: PP-13HYDROCONVERSION OF VEGETABLE O
Page 104 and 105: PP-15CaO AND Al 2 O 3 SUPPORT SOLID
Page 106 and 107: PP-17CATALYTIC CRACKING OF GLUCOSE
Page 108 and 109: PP-19[DBU][Ac]: A TASK-SPECIFIC ION
Page 110 and 111: PP-21SELECTIVE CONVERSION OF CARBON
Page 112 and 113: PP-23HYDROGEN PRODUCTION BY ETHANOL
Page 114 and 115: PP-25SUB- AND SUPERCRITICAL WATER A
Page 116 and 117: PP-27THE BLENDING OF SECOND - GENER
Page 118 and 119: PP-29STUDY ON THE PRETREATMENTS OF
Page 120 and 121: PP-31THERMAL CONVERSIONS OF WOOD SA
Page 122 and 123: PP-33PHYSICOCHEMICAL PROPERTIES OF
Page 124 and 125: PP-35LOW-TEMPERATURE OXIDATION OF O
Page 126 and 127: PP-37LABORATORY EQUIPMENT FOR THE S
Page 128 and 129: PP-39FERMENTATION PROCESSES OF FREE
Page 130 and 131: PP-41THERMOCATALYTIC HYDROLYSIS AND
Page 132 and 133: PP-43OBTAINING OF SYNTHETIC FUEL FR
Page 134 and 135: PP-44hydrogen. The highest values o
Page 136 and 137: PP-46PROBLEM OF RECEPTION OF ANTIMA
Page 140 and 141: PP-50DEVELOPMENT OF AN EFFICIENT ME
Page 142 and 143: PP-52ZEOLITE COATINGS ON SUGAR CANE
Page 144 and 145: PP-54PREPARATION OF ADVANCED ADSORB
Page 146 and 147: PP-56HYDROGENATION OF CIS-METHYL OL
Page 148 and 149: PP-57CAVITATION ASSISTED DESIGH OF
Page 150 and 151: PP-59KINETICS OF CATALYTIC GASIFICA
Page 152 and 153: PP-61ORGANOSOLV LIGNIN AS CHEMICALS
Page 154 and 155: PP-62which were taken in preset qua
Page 156 and 157: PP-64EXTRACTION OF HUMIC ACIDS FROM
Page 158 and 159: PP-66THE INVESTIGATION OF ASPECTS O
Page 160 and 161: LIST OF PARTICIPANTSNeisiani ABDOLL
Page 162 and 163: Andrey CHISTYAKOVA.V. Topchiev Inst
Page 164 and 165: Yusuf ISA MAKARFIM.V. Lomonosov Mos
Page 166 and 167: Nikolaj LAPINInstitute of Microelec
Page 168 and 169: Vitaly ORDOMSKYDepartment of Chemis
Page 170 and 171: Irina SIMAKOVABoreskov Institute of
Page 172 and 173: Elena VIALICHPerm State UniversityB
Page 174 and 175: ORAL PRESENTATIONS.................
Page 176 and 177: OP-2-18 Andreeva D., Schäferhans J
Page 178 and 179: PP-15 Dias A.P., Puna J.F., Gomes J
Page 180 and 181: PP-50Rustamov M.I., Abad-zade Kh.I.
Page 182: INTERNATIONAL CONFERENCECATALYSIS F
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Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

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