Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

OP-1-11BIOMASS’ PRODUCTS TREATMENT INTO HYDROCARBONS ANDHYDROGEN-CONTAINING GAS OVER NANOSIZED CATALYSTSAND MEMBRANE-CATALYTIC SYSTEMSTsodikov M.V. 1 , Chistyakov A.V. 1 , Gekhman A.E. 2 , Moiseev I.I. 21 A.V. Topchiev Institute of Petrochemical Synthesis, RAS, Moscow,tsodikov@ips.ac.ru2 N.S. Kurnakov Institute of General and Inorganic Chemistry, RAS, MoscowResults of the present paper relate to research of catalytic and membranecatalyticprocesses based on alcohols, methane and carbon dioxide feed that allowobtaining fuel compounds and petrochemical substrates.Nanosized catalysts that possess high activity and selectivity in new reactions ofalkanes and olefins formation from bioalcohols were prepared with using ofheterometallic alkoxide and acetic precursors containing metals of II, VI-VIII groups.It was shown the possibility of selectivity adjustment in one-step process directed onbranched alkanes, olefins and alkane – olefin fractions formation. With use of kineticand structural methods the genesis of applied catalysts was characterized andpossible routes of studied reactions were found.New approaches to high rate dry and vapor-phase reforming of bio-products leadto hydrogen-containing gas formation over membrane-catalytic systems modifiedwith nanosized active components were developed.Principal possibility of high effective cellulose conversion over nanosizedcatalysts impregnated directly on the substrate surface was demonstrated.On the basis of developed approaches principal scheme was proposed thatdemonstrated the possibility to obtain a wide range of industrial important processesbased on renewable raw materials.Acknowledgements:Authors kindly thanks: Prof. Vargaftik M.N., Dr. Kozitsina N.Yu (IGIC RAS) andProf. Drobot D.V. (Lomonosov M.V. MSAFCT), RFBR and RAS for financial support.35