Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

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OP-1-8conditions (300-340°C and 2.0 MPa H 2 ) and possibility of green diesel productionwith different cetane number via hydroisomerization catalysts application.Thus, developed transetherification and mild hydrocracking processes allow toobtain high-clean biodiesel and green diesel with high cetane number, which can beused as improving additive to traditional fossil diesels. Developed new effectivecatalysts can be used in processing of non-food lipidic renewables.32
CATALYTIC HYDROTREATING OF FAST PYROLYSISOIL WITH NiCu/δ-Al 2 O 3 CATALYSTSArdiyanti A.R. 1 , Khromova S.A. 2 , Yakovlev V.A. 2 , Venderbosch R.H. 3 ,Heeres H.J. 1OP-1-91 Chemical Engineering Department, University of Groningen, Nijenborgh 4,Groningen, The Netherlands, e-mail: A.R.Ardiyanti@rug.nl2 Boreskov Institute of Catalysis, Pr. Akad. Lavrentieva, 5, Novosibirsk, Russia3 Biomass Technology Group B.V., Josink Esweg 34, Enschede, The NetherlandsLignocellulosic biomass can be converted efficiently via fast-pyrolysis intopyrolysis oil, an attractive liquid energy carrier [1]. However, the application ofpyrolysis oil (e.g. as feedstock for existing refinery units) is limited due to its limitedthermal stability, high acidity, and high viscosity. To enhance the application range ofpyrolysis oil, catalytic hydrotreating of the pyrolysis oil has been proposed [2]. Themajor objectives of catalytic hydrotreating are a reduction of the oxygen content, andto achieve a product with improved stability and lower viscosity. Here we report ourstudies on catalytic hydrotreatment of pyrolysis oil using NiCu/δ-Al 2 O 3 catalysts with arange of Ni/Cu ratios in a batch set-up. Good deoxygenation levels were observed,though distinct differences in the perfomance were present (Figure 1).This study clearlyindicates that NiCu/δ-Al 2 O 3catalysts have high potentialfor the catalytic upgrading ofpyrolysis oils. Further studiesin dedicated continuous setupsare in progressatomic O/CReferences[1]. McKendry, P. Bioresour. Technol. 2002, 83, 37-46.[2]. Elliott, D. C. Energy Fuels 2007, 21, 1792-1815.AcknowledgementsBiocoup (EU-FP6) is acknowledged for financial support.0.60.50.40.30.20.1Pyrolysis oilNi/Cu 13.3/11.8Ni 20.8Ni/Cu 16.2/2Ni/Cu 13.8/6.83Cu 24.5Ni/Cu 5.92/18.20.00.8 1.0 1.2 1.4 1.6atomic H/CFigure 1. Van Krevelen plot of hydrotreated oils.33
Page 1 and 2: Boreskov Institute of Catalysis SB
Page 3 and 4: International Scientific CommitteeV
Page 5 and 6: PL-1DESIGN OF CATALYSTS AND CATALYT
Page 7 and 8: PL-3CATALYTIC TRANSFORMATIONS FOR P
Page 9 and 10: PL-4In this contribution the princi
Page 11 and 12: PL-5THEORETICAL AND EXPERIMENTAL AN
Page 13 and 14: PL-6heat exchanging internals; dyna
Page 15 and 16: CATALYTIC CRACKING OF SUNFLOWER SEE
Page 17 and 18: KN-3CONVERSIONS OF WOOD AND CELLULO
Page 19 and 20: CATALYTIC FUEL-GAS CLEANING IN A ST
Page 21 and 22: BIO4ENERGY - THE SWEDISH QUESTFOR S
Page 23 and 24: ORAL PRESENTATIONSSection 1.CATALYS
Page 25 and 26: OP-1-2METHANOLYSIS OF VEGETABLE OIL
Page 27 and 28: OP-1-4SYNTHESIS, CHARACTERIZATION A
Page 29 and 30: OP-1-6THE PRODUCTION OF MOTOR FUEL
Page 31: HYDROTREATMENT CATALYSTS DESIGN FOR
Page 35: OP-1-11BIOMASS’ PRODUCTS TREATMEN
Page 38 and 39: OP-1-14BIO-ETHANOL - PETROCHEMICAL
Page 40 and 41: OP-1-15USING BIOMASS-BASED FUELS FO
Page 42 and 43: OP-2-1COMBINATION OF METAL AND ACID
Page 44 and 45: OP-2-3CELLULOSE HYDROTHERMAL CONVER
Page 46 and 47: OP-2-4CATALYTIC CONVERSION OF CONCE
Page 48 and 49: OP-2-6KINETICS OF SELECTIVE OXIDATI
Page 50 and 51: OP-2-8PROCESS FOR THE PRODUCTION OF
Page 52 and 53: OP-2-10BIODERIVED LACTIC ACID AND L
Page 54 and 55: OP-2-11CATALYTIC CONVERSION OF HEMI
Page 56 and 57: OP-2-13Cu CATALYSTS FOR HYDROGENOLY
Page 58 and 59: OP-2-15Cu-CONTAINING CATALYSTS FOR
Page 60 and 61: OP-2-16MICROWAVE-ASSISTED EPOXIDATI
Page 62 and 63: OP-2-18ULTRASOUND-INDUCED FORMATION
Page 64 and 65: OP-2-20EFFECT OF Ag DOPING IN La-Mn
Page 66 and 67: OP-2-22INSIGHTS IN GLYCEROL REFORMI
Page 68 and 69: OP-3-1APPLICATION OF NOVEL CATALYST
Page 70 and 71: OP-3-2REDUCING CONVERSIONS OF GLYCE
Page 72 and 73: OP-3-4LOW-TEMPERATURE CONVERSION OF
Page 74 and 75: OP-3-6H 2 PRODUCTION BY STEAM REFOR
Page 76 and 77: OP-3-8CATALYTIC STEAM REFORMING OF
Page 78 and 79: OP-3-10CATALYTIC GAS PHASE CONVERSI
Page 80 and 81: ORAL PRESENTATIONSSection 4.BIOCATA
Page 82 and 83:
OP-4-2THE EFFECT OF OXYGEN MASS TRA
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OP-4-4VALORIFICATION OF FERMENTATIO
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OP-4-5MECHANISM OF ULTRASOUND-ASSIS
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PP-1THE ORTHO - PARA CONVERSION OF
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PP-3THREE-STAGE WASTE-FREE PROCESS
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PP-4Н 2 О with formation superflu
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PP-6HYDROGEN FROM FORMIC ACID DECOM
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PP-8VALORIZATION OF GLYCEROL BY CON
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PP-10BIODIESEL PRODUCTION FROM WAST
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PP-11Figure 1. CHEMPAK architecture
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PP-13HYDROCONVERSION OF VEGETABLE O
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PP-15CaO AND Al 2 O 3 SUPPORT SOLID
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PP-17CATALYTIC CRACKING OF GLUCOSE
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PP-19[DBU][Ac]: A TASK-SPECIFIC ION
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PP-21SELECTIVE CONVERSION OF CARBON
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PP-23HYDROGEN PRODUCTION BY ETHANOL
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PP-25SUB- AND SUPERCRITICAL WATER A
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PP-27THE BLENDING OF SECOND - GENER
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PP-29STUDY ON THE PRETREATMENTS OF
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PP-31THERMAL CONVERSIONS OF WOOD SA
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PP-33PHYSICOCHEMICAL PROPERTIES OF
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PP-35LOW-TEMPERATURE OXIDATION OF O
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PP-37LABORATORY EQUIPMENT FOR THE S
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PP-39FERMENTATION PROCESSES OF FREE
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PP-41THERMOCATALYTIC HYDROLYSIS AND
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PP-43OBTAINING OF SYNTHETIC FUEL FR
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PP-44hydrogen. The highest values o
Page 136 and 137:
PP-46PROBLEM OF RECEPTION OF ANTIMA
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PP-48INVESTIGATION OF NEW WAYS OF B
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PP-50DEVELOPMENT OF AN EFFICIENT ME
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PP-52ZEOLITE COATINGS ON SUGAR CANE
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PP-54PREPARATION OF ADVANCED ADSORB
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PP-56HYDROGENATION OF CIS-METHYL OL
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PP-57CAVITATION ASSISTED DESIGH OF
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PP-59KINETICS OF CATALYTIC GASIFICA
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PP-61ORGANOSOLV LIGNIN AS CHEMICALS
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PP-62which were taken in preset qua
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PP-64EXTRACTION OF HUMIC ACIDS FROM
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PP-66THE INVESTIGATION OF ASPECTS O
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LIST OF PARTICIPANTSNeisiani ABDOLL
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Andrey CHISTYAKOVA.V. Topchiev Inst
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Yusuf ISA MAKARFIM.V. Lomonosov Mos
Page 166 and 167:
Nikolaj LAPINInstitute of Microelec
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Vitaly ORDOMSKYDepartment of Chemis
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Irina SIMAKOVABoreskov Institute of
Page 172 and 173:
Elena VIALICHPerm State UniversityB
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ORAL PRESENTATIONS.................
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OP-2-18 Andreeva D., Schäferhans J
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PP-15 Dias A.P., Puna J.F., Gomes J
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PP-50Rustamov M.I., Abad-zade Kh.I.
Page 182:
INTERNATIONAL CONFERENCECATALYSIS F
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Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

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