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Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

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PP-62which were taken in preset quantities for obtaining oxides <strong>of</strong> the preset compositionwith introduction <strong>of</strong> the agents stabilizing the mother liquor.Pipe-like microporous membranes <strong>of</strong> 15 mm in diameter and 130 mm in lengthwere used as initial membranes.The mother liquors <strong>of</strong> metal-complex precursors were pumped through themembrane in order to modify the internal surface <strong>of</strong> the channels. Then themembrane was blown through with the moistened heated air, dried in vacuum (1Torr), and heated at various modes.A membrane-catalytic module with gas consumption <strong>of</strong> up to 25 m 3 /h was made.The membrane-catalytic system containing palladium particles as an activecomponent was used to study the process <strong>of</strong> vapor conversion <strong>of</strong> ethanol and aceticacid as the main products <strong>of</strong> biomass fermentation. The initial mixture compositioncorresponded to that <strong>of</strong> the fermentation products (a substrate/H 2 O – 10-12). Thespecific activity in hydrogen formation was 600 l/dm 3 membrh and 400 l/dm 3 membrh foracetic acid and ethanol, respectively.154

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