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A handbbok on Weed Control in Rice.pdf

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Table 4.1. Mean<strong>in</strong>gs of signal words found <strong>on</strong> herbicide formulati<strong>on</strong> labels, to state danger to<br />

humans.<br />

Lethal oral dose<br />

Approximate lethal (LD 50 ) for rats<br />

Signal word Acute toxicity oral dose for an (mg/kg body<br />

adult human weight) (See p. 62<br />

for discussi<strong>on</strong> <strong>on</strong><br />

Danger/Pois<strong>on</strong><br />

Warn<strong>in</strong>g<br />

Cauti<strong>on</strong><br />

No signal word<br />

Highly toxic<br />

Moderately toxic<br />

Low to relatively<br />

n<strong>on</strong>toxic<br />

Relatively n<strong>on</strong>toxic<br />

(ISO). A herbicide may be produced or<br />

formulated by more than <strong>on</strong>e company<br />

and thus be sold under several brand<br />

names, but the comm<strong>on</strong> name or<br />

chemical name should always be the<br />

same <strong>on</strong> all products. For example:<br />

Trade or brand names: Machete,<br />

Butanex, Lambast<br />

Chemical name: N-(buthoxymethyl)-2-<br />

chloro-N-(2,6diethylphenyl)<br />

acetamide<br />

Comm<strong>on</strong> name: butachlor<br />

Active <strong>in</strong>gredient. Each label specifi-<br />

cally names the active <strong>in</strong>gredient<br />

present <strong>in</strong> the herbicide. The amount of<br />

active <strong>in</strong>gredient may be given <strong>in</strong><br />

percentage by weight or <strong>in</strong> grams per<br />

liter, and may be listed by its comm<strong>on</strong><br />

name or by its chemical name. The<br />

<strong>in</strong>ert <strong>in</strong>gredients need not be named,<br />

but the label should specify their per-<br />

centage of c<strong>on</strong>tent.<br />

Formulati<strong>on</strong>. Some labels spell out<br />

the formulati<strong>on</strong>, others use abbrevia-<br />

ti<strong>on</strong>s, such as EC or E for emulsifiable<br />

c<strong>on</strong>centrates; WP or W for wettable<br />

powder; FW, F, or L for flowables; G<br />

for granules; and S for solubles.<br />

C<strong>on</strong>tent. Each label gives the total<br />

amount of herbicide <strong>in</strong> the c<strong>on</strong>ta<strong>in</strong>er<br />

(eg, <strong>in</strong> liters [L] or kilograms [kg]).<br />

A taste to <strong>on</strong>e<br />

teaspo<strong>on</strong>ful (5 ml)<br />

One teaspo<strong>on</strong>ful to 2<br />

tablespo<strong>on</strong>fuls (30 ml)<br />

30-450 ml<br />

LD 50 )<br />

5-50<br />

50-500<br />

500-5,000<br />

Signal words and symbols. Herbicide<br />

labels state how pois<strong>on</strong>ous the<br />

product is, us<strong>in</strong>g specific signal words<br />

and symbols. Examples are shown <strong>in</strong><br />

Table 4.1.<br />

Labels of all highly toxic products<br />

have, <strong>in</strong> additi<strong>on</strong> to the word pois<strong>on</strong>,<br />

the skull and cross-b<strong>on</strong>es symbol.<br />

Pictograms-graphically def<strong>in</strong>itive<br />

symbols-are also recommended for<br />

<strong>in</strong>clusi<strong>on</strong> <strong>on</strong> agrochemical labels (Info<br />

Letter 1988). Examples of pictograms<br />

are draw<strong>in</strong>gs of a pair of pants <strong>in</strong> boots<br />

and a pair of hands <strong>in</strong> gloves, to c<strong>on</strong>vey<br />

the need to wear footwear and gloves<br />

for safe handl<strong>in</strong>g of chemicals. These<br />

labels also <strong>in</strong>clude the statement Keep<br />

out of reach of children.<br />

Directi<strong>on</strong>s for use. Directi<strong>on</strong>s for use<br />

provide <strong>in</strong>structi<strong>on</strong>s <strong>on</strong> how to use the<br />

herbicide. This <strong>in</strong>cludes <strong>in</strong>formati<strong>on</strong> <strong>on</strong><br />

weeds that the herbicide c<strong>on</strong>trols,<br />

crops <strong>on</strong> which applicati<strong>on</strong> of the<br />

herbicide is safe, applicati<strong>on</strong> rates,<br />

applicati<strong>on</strong> time, and applicati<strong>on</strong><br />

method. All directi<strong>on</strong>s for use must be<br />

followed.<br />

Name of manufacturer. The name and<br />

address of the manufacturer or<br />

distributor of the product often is<br />

required by law to be <strong>on</strong> the label.<br />

Hazards to humans and domestic<br />

animals. The hazards porti<strong>on</strong> of a label<br />

<strong>in</strong>dicates how the herbicide may be<br />

harmful to man and domestic animals.<br />

It gives <strong>in</strong>formati<strong>on</strong> <strong>on</strong> how to avoid<br />

pois<strong>on</strong><strong>in</strong>g or c<strong>on</strong>tam<strong>in</strong>ati<strong>on</strong>, such as<br />

the type of protective cloth<strong>in</strong>g re-<br />

quired.<br />

Envir<strong>on</strong>mental hazards. To help<br />

reduce undesirable effects <strong>on</strong> the<br />

envir<strong>on</strong>ment, the label also provides<br />

envir<strong>on</strong>mental precauti<strong>on</strong>s. It may<br />

<strong>in</strong>clude warn<strong>in</strong>gs that it is harmful to<br />

birds, fish, and wildlife, and advice <strong>on</strong><br />

how to avoid c<strong>on</strong>tam<strong>in</strong>at<strong>in</strong>g water<br />

bodies.<br />

Harvest<strong>in</strong>g statement. A harvest<strong>in</strong>g<br />

statement is pr<strong>in</strong>ted <strong>on</strong> labels when<br />

there is a chance that the treated crop<br />

may be fed to animals or handled by<br />

humans. Because residues of a herbi-<br />

cide require a m<strong>in</strong>imum number of<br />

days to degrade, a harvest<strong>in</strong>g state-<br />

ment specifies the number of days<br />

between the last herbicide applicati<strong>on</strong><br />

and the time when the crop can be<br />

safely cut, threshed, or eaten.<br />

Herbicide applicators<br />

A herbicide applicator is any device<br />

used to apply herbicides <strong>on</strong> plant and<br />

soil surfaces. Applicators distribute an<br />

exact quantity of a herbicide uniformly<br />

over a given area. They can be classi-<br />

fied as n<strong>on</strong>pressurized or pressurized.<br />

N<strong>on</strong>pressurized applicators <strong>in</strong>clude<br />

the water can, granular applicator,<br />

c<strong>on</strong>trolled-droplet applicator, and<br />

direct-c<strong>on</strong>tact applicators such as rope<br />

wicks and wipers.<br />

Hydraulic (pressurized) applicators<br />

usually need water to work. A pressur-<br />

ized applicator may be manually<br />

operated (such as the lever-operated<br />

knapsack sprayer), motorized, or<br />

ground-driven (Fig 4.2).<br />

Herbicide use 55

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