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A handbbok on Weed Control in Rice.pdf

A handbbok on Weed Control in Rice.pdf

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Thiocarbamates<br />

Thiocarbamates are active when<br />

applied to the soil. Some are highly<br />

volatile, which makes soil <strong>in</strong>corpora-<br />

ti<strong>on</strong> necessary. Thiocarbamate herbi-<br />

cides c<strong>on</strong>trol germ<strong>in</strong>at<strong>in</strong>g annual<br />

grassy and broadleaf weeds. The<br />

process of lipid biosynthesis appears<br />

to be the most sensitive to thiocar-<br />

bamates. Examples of this group are<br />

thiobencarb and mol<strong>in</strong>ate. Most<br />

thiocarbamate herbicides have a<br />

relatively short soil persistence. Recent<br />

evidence (Roeth 1986) has shown<br />

<strong>in</strong>creased breakdown of some thiocar-<br />

bamate herbicides <strong>in</strong> soils with a<br />

history of thiocarbamates applicati<strong>on</strong>.<br />

Mol<strong>in</strong>ate. Mol<strong>in</strong>ate is a herbicide for<br />

selective weed c<strong>on</strong>trol <strong>in</strong> rice at<br />

2-4 kg ai/ha. It is particularly effective<br />

for c<strong>on</strong>troll<strong>in</strong>g Ech<strong>in</strong>ochloa weed<br />

species. It can be applied as a granular<br />

formulati<strong>on</strong> to the water <strong>in</strong> flooded<br />

rice. Emulsifiable c<strong>on</strong>centrates<br />

applied to the soil surface are<br />

extremely volatile and must be<br />

<strong>in</strong>corporated immediately. Mol<strong>in</strong>ate<br />

can be applied before sow<strong>in</strong>g rice, at<br />

postemergence preflood, at flood<strong>in</strong>g,<br />

or postflood. Moisture is required to<br />

activate mol<strong>in</strong>ate. In pre-flood treat-<br />

ment, the area should be flooded as<br />

so<strong>on</strong> as possible. Once applied, a<br />

c<strong>on</strong>t<strong>in</strong>uous water cover must be ma<strong>in</strong>-<br />

ta<strong>in</strong>ed. <strong>Rice</strong> is extremely tolerant of<br />

this herbicide. Cool temperatures will<br />

cause less than optimal weed c<strong>on</strong>trol.<br />

Commercial mixtures <strong>in</strong>clude<br />

mol<strong>in</strong>ate + propanil.<br />

Water solubility is 880 mg/liter at<br />

20 ºC. LD 50 for male rats is 369 mg/kg.<br />

LC 50 (96 h) for goldfish is 30 mg/liter.<br />

At recommended rates, mol<strong>in</strong>ate had<br />

no detectable effects <strong>on</strong> fish <strong>in</strong> ditches<br />

dra<strong>in</strong><strong>in</strong>g water from treated ricefields<br />

<strong>in</strong> California.<br />

70 <strong>Weed</strong> c<strong>on</strong>trol handbook<br />

Thiobencarb. Thiobencarb is more<br />

effective <strong>on</strong> grasses and sedges than<br />

<strong>on</strong> broadleaf weeds. Thiobencarb<br />

<strong>in</strong>terferes with prote<strong>in</strong> synthesis and<br />

<strong>in</strong>hibits photosynthesis. Prote<strong>in</strong><br />

synthesis and amylase biosynthesis are<br />

<strong>in</strong>hibited more <strong>in</strong> susceptible grass<br />

species than <strong>in</strong> rice.<br />

In transplanted rice, thiobencarb<br />

shows maximum herbicidal selectivity<br />

by tak<strong>in</strong>g advantage of differences <strong>in</strong><br />

growth between rice seedl<strong>in</strong>gs at the<br />

3- to 6-leaf stages and germ<strong>in</strong>at<strong>in</strong>g<br />

weeds. Thiobencarb (2-3 kg ai/ha) is<br />

distributed <strong>in</strong> the top soil after applica-<br />

ti<strong>on</strong> and is readily leached from the<br />

soil. <strong>Rice</strong> plant <strong>in</strong>jury symptoms<br />

<strong>in</strong>clude dwarf malformati<strong>on</strong> and deep<br />

green<strong>in</strong>g. In some cases, leaf scorch<strong>in</strong>g<br />

appears.<br />

Thiobencarb should be applied<br />

between preemergence and the 2-leaf<br />

stage of Ech<strong>in</strong>ochloa spp. because<br />

herbicidal activity decreases after this<br />

stage. For post-emergence applicati<strong>on</strong>,<br />

thiobencarb should be applied after<br />

the 1.5-leaf stage of rice to the 2- to<br />

3-leaf stage of Ech<strong>in</strong>ochloa spp. to<br />

obta<strong>in</strong> the best weed kill without<br />

damag<strong>in</strong>g the rice. Cool temperatures<br />

may delay <strong>on</strong>set of herbicidal activity.<br />

Commercial mixtures available<br />

<strong>in</strong>clude thiobencarb + propanil and<br />

thiobencarb + simetryn.<br />

Water solubility is 30 mg/liter at<br />

20 °C. LD 50 for rats is 1,300 mg/kg.<br />

LC 50 (48 h) is 3.6 mg/liter for carp.<br />

Triaz<strong>in</strong>es<br />

The triaz<strong>in</strong>es are a large group of<br />

herbicides. They are applied preemer-<br />

gence and postemergence to c<strong>on</strong>trol<br />

seedl<strong>in</strong>g grasses and broadleaf weeds.<br />

They c<strong>on</strong>trol broadleaf weeds better<br />

than grasses and do not c<strong>on</strong>trol estab-<br />

lished annual or perennial weeds.<br />

Their mode of acti<strong>on</strong> is through<br />

<strong>in</strong>hibiti<strong>on</strong> of photosynthesis <strong>in</strong> plants.<br />

Simetryn and dimethametryn are<br />

triaz<strong>in</strong>es.<br />

Simetryn. Simetryn is used as a<br />

mixture with thiobencarb to c<strong>on</strong>trol<br />

broadleaf weeds <strong>in</strong> rice. LD 50 for rats is<br />

1,830 mg/kg.<br />

Dimethametryn. Dimethametryn is a<br />

triaz<strong>in</strong>e compound used as a selective,<br />

preemergence, and postemergence<br />

herbicide. It c<strong>on</strong>trols annual broadleaf<br />

weeds and grasses.<br />

Sulf<strong>on</strong>ylureas<br />

Sulf<strong>on</strong>ylureas have very high biolgical<br />

activity, and rates as low as<br />

0.002 kg ai/ha have been used.<br />

Although weed seed germ<strong>in</strong>ati<strong>on</strong> is<br />

not usually affected, subsequent root<br />

and shoot growth are severely <strong>in</strong>hib-<br />

ited <strong>in</strong> sensitive seedl<strong>in</strong>gs. <strong>Weed</strong><br />

growth <strong>in</strong>hibiti<strong>on</strong> is rapid, with visual<br />

symptoms with<strong>in</strong> 1-2 d <strong>in</strong> rapidly<br />

grow<strong>in</strong>g plants. The site of acti<strong>on</strong> of<br />

the sulf<strong>on</strong>ylureas is the enzyme<br />

acetolactate synthase. Inhibiti<strong>on</strong> of this<br />

enzyme, which is needed for the<br />

producti<strong>on</strong> of the essential am<strong>in</strong>o acid<br />

build<strong>in</strong>g blocks val<strong>in</strong>e and isoleuc<strong>in</strong>e,<br />

results <strong>in</strong> rapid cessati<strong>on</strong> of growth<br />

and eventual plant death. All plants<br />

c<strong>on</strong>ta<strong>in</strong> this target enzyme, but the<br />

ability of some plants to rapidly<br />

c<strong>on</strong>vert the herbicide to an <strong>in</strong>active<br />

product is the basis for selectivity<br />

(Beyer et al 1988).<br />

Bensulfur<strong>on</strong>. Bensulfur<strong>on</strong> (0.05 kg<br />

ai/ha) is a sulf<strong>on</strong>ylurea herbicide used<br />

<strong>in</strong> direct seeded and transplanted rice.<br />

It has good crop safety <strong>on</strong> <strong>in</strong>dica rice<br />

varieties, but less crop safety <strong>on</strong><br />

jap<strong>on</strong>ica types. Indica rices metabolize<br />

the herbicide more rapidly than<br />

jap<strong>on</strong>ica rices. Thiocarbamates<br />

herbicides, except mol<strong>in</strong>ate, show an<br />

antidote effect <strong>on</strong> bensulfur<strong>on</strong> through<br />

the accelerati<strong>on</strong> of detoxificati<strong>on</strong> by<br />

rice.

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