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A handbbok on Weed Control in Rice.pdf

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area less than 1 ha or for a tankful. The<br />

amount of water needed to spray a<br />

given area can be calculated as<br />

If the area to be sprayed is 1,000 m 2 and<br />

the sprayer output is 200 liters/ha<br />

(from the calibrati<strong>on</strong> described earlier),<br />

then the amount of water required to<br />

spray this area is :<br />

When the area to be sprayed is de-<br />

term<strong>in</strong>ed <strong>on</strong> the basis of sprayer<br />

capacity, area can be calculated as<br />

If a knapsack sprayer has a capacity<br />

of 15 liters and the sprayer output is<br />

200 liters/ha, then the area covered by<br />

<strong>on</strong>e full tank (15 liters) is<br />

The total amount of formulated<br />

product to be used <strong>in</strong> the examples<br />

above can be calculated as<br />

60 <strong>Weed</strong> c<strong>on</strong>trol handbook<br />

To summarize, the steps required to<br />

arrive at the amount of herbicide and<br />

water to be sprayed <strong>on</strong> a given area are<br />

1. Determ<strong>in</strong>e sprayer output per<br />

hectare (calibrate the sprayer).<br />

2. Determ<strong>in</strong>e the quantity of formu-<br />

lated product required per hectare<br />

(from label or other recommendati<strong>on</strong>s).<br />

3. Use the size of the area to be<br />

sprayed or the sprayer capacity<br />

(whichever is smaller) to determ<strong>in</strong>e the<br />

amount of water needed.<br />

4. Calculate the formulated product<br />

needed for the quantity of water.<br />

Appendix B gives calculated dosage<br />

rates per hectare for different formula-<br />

ti<strong>on</strong>s, so that you can cross check your<br />

own calculati<strong>on</strong>s.<br />

Calculati<strong>on</strong> of dosage <strong>in</strong> acid<br />

equivalents of salts and esters<br />

Herbicide dosage recommendati<strong>on</strong>s<br />

computed <strong>in</strong> kilograms of active<br />

<strong>in</strong>gredient per hectare refer to the<br />

unaltered chemical molecule. But <strong>in</strong><br />

herbicide molecules that are acids, the<br />

acidic porti<strong>on</strong> is normally transformed<br />

to a salt or ester, to improve such<br />

characteristics as solubility <strong>in</strong> water or<br />

oil and foliar penetrati<strong>on</strong>. In general,<br />

the parent acid porti<strong>on</strong> of the herbicide<br />

molecule rema<strong>in</strong>s as the herbicidally<br />

active porti<strong>on</strong>, while the ester or salt<br />

attached to the parent acid satisfies the<br />

functi<strong>on</strong>s for <strong>in</strong>creased solubility or<br />

<strong>in</strong>creased penetrati<strong>on</strong>. The acid equiva-<br />

lent of a salt or ester form of a herbi-<br />

cide, therefore, is that porti<strong>on</strong> of the<br />

molecule represent<strong>in</strong>g the orig<strong>in</strong>al acid<br />

form of the molecule. The dosage rec-<br />

ommendati<strong>on</strong> for such herbicides is<br />

given as kilograms of acid equivalent<br />

of the active <strong>in</strong>gredient per hectare.<br />

The recommended dosage of herbi-<br />

cides applied as salts or esters is often<br />

based <strong>on</strong> the herbicidal porti<strong>on</strong> of the<br />

salt or ester molecule, and excludes the<br />

herbicidally <strong>in</strong>active porti<strong>on</strong><br />

(Anders<strong>on</strong> 1983).<br />

The product labels of most commercial<br />

herbicide formulati<strong>on</strong>s c<strong>on</strong>ta<strong>in</strong><strong>in</strong>g<br />

salts and esters specify the amount of<br />

acid equivalent present <strong>in</strong> the formulati<strong>on</strong>.<br />

The acid equivalent is equal to the<br />

difference <strong>in</strong> weight, expressed as percent,<br />

between the parent acid molecule<br />

(m<strong>in</strong>us a value of 1, represent<strong>in</strong>g the<br />

loss of the H + ) and that of the salt or<br />

ester molecule. It is always less than<br />

l00%, and is calculated by the<br />

follow<strong>in</strong>g formula:<br />

Molecular weight (mol/wt) of<br />

acid<br />

Example: The molecular weight of<br />

2,4-D is 221. The molecular weight of<br />

its isopropyl ester is 263. The acid<br />

equivalent of the isopropyl ester of<br />

2,4-D is determ<strong>in</strong>ed as<br />

Field techniques for<br />

us<strong>in</strong>g herbicides<br />

Proper field techniques are important<br />

to get good weed c<strong>on</strong>trol from herbi-<br />

cides. Read all labels before us<strong>in</strong>g a<br />

herbicide, and follow the directi<strong>on</strong>s. To<br />

kill the weeds and not the rice, us<strong>in</strong>g<br />

the correct dosage is essential. C<strong>on</strong>tact<br />

herbicides work best when they are<br />

applied <strong>in</strong> a high volume of water.

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