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A handbbok on Weed Control in Rice.pdf

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Bensulfur<strong>on</strong> c<strong>on</strong>trols many broadleaf<br />

weeds and sedges. It can be<br />

applied as preemergence or early<br />

postemergence treatment. When used<br />

<strong>in</strong> comb<strong>in</strong>ati<strong>on</strong> with a grass herbicide<br />

such as thiobencarb, mol<strong>in</strong>ate, or<br />

butachlor, bensulfur<strong>on</strong> provides<br />

excellent weed c<strong>on</strong>trol. Applicati<strong>on</strong><br />

can be made up to the 3-leaf stage of<br />

the weeds. Bensulfur<strong>on</strong> provides good<br />

c<strong>on</strong>trol of S. maritimus when applied<br />

6-12 d after emergence of the weed<br />

(Bernasor and De Datta 1986).<br />

Water solubility at 25 °C is<br />

120 mg/liter. LD 50 <strong>in</strong> rats is<br />

75,000 mg/kg. LC 50 (96 h) for ra<strong>in</strong>bow<br />

trout is >150 mg/liter.<br />

Polycyclic alkanoic acids<br />

Polycyclic alkanoic acids c<strong>on</strong>trol grass<br />

weeds. In general, polycyclic alkanoic<br />

acids are lost from the soil through<br />

biodegradati<strong>on</strong>, rather than through<br />

leach<strong>in</strong>g or volatilizati<strong>on</strong>. Ra<strong>in</strong>fall after<br />

foliar applicati<strong>on</strong> can greatly reduce<br />

herbicide absorpti<strong>on</strong> because of a<br />

reduced amount of herbicide <strong>in</strong><br />

c<strong>on</strong>tact with the plant. One example of<br />

the group is fenoxaprop. Herbicides<br />

such as MCPA, 2,4-D, and bentaz<strong>on</strong><br />

antag<strong>on</strong>ize polycyclic alkanoic acids.<br />

Fenoxaprop. Fenoxaprop<br />

(0.03-0.05 kg ai/ha) is a postemergence,<br />

selective herbicide for c<strong>on</strong>trol<br />

of annual and perennial grassy weeds.<br />

It is a c<strong>on</strong>tact herbicide that is partly<br />

systemic. <strong>Rice</strong> is tolerant from the<br />

3-leaf stage to early tiller<strong>in</strong>g.<br />

Fenoxaprop has no soil activity. It<br />

should not be applied with phenoxy<br />

compounds.<br />

Water solubility at 25 °C is<br />

0.8 mg/liter. LD 50 is 2,357 mg/kg.<br />

Miscellaneous herbicides<br />

Several herbicides do not clearly fall<br />

<strong>in</strong>to any of the group<strong>in</strong>gs. These<br />

herbicides differ <strong>in</strong> chemistry, selectivity,<br />

and mode of acti<strong>on</strong>. Bentaz<strong>on</strong>,<br />

chlomethoxynil, c<strong>in</strong>methyl<strong>in</strong>,<br />

oxadiaz<strong>on</strong>, and qu<strong>in</strong>clorac are<br />

examples.<br />

Bentaz<strong>on</strong>. Bentaz<strong>on</strong> (1-2 kg ai/ha)<br />

selectively c<strong>on</strong>trols a number of broadleaf<br />

weeds and sedges, primarily by<br />

c<strong>on</strong>tact acti<strong>on</strong>. Broadleaf weeds at the<br />

2- to 10-leaf stage are c<strong>on</strong>trolled most<br />

readily. Delay <strong>in</strong> applicati<strong>on</strong> will result<br />

<strong>in</strong> <strong>in</strong>adequate c<strong>on</strong>trol. In irrigated rice,<br />

bentaz<strong>on</strong> should be applied <strong>on</strong>ly to<br />

weeds that have emerged above the<br />

water level. Bentaz<strong>on</strong> does not c<strong>on</strong>trol<br />

grasses and has no known preemergence<br />

activity. Available commercial<br />

mixtures <strong>in</strong>clude bentaz<strong>on</strong> + MCPA<br />

and bentaz<strong>on</strong> + propanil.<br />

Water solubility is 500 mg/liter.<br />

LD 50 for rats is about 1,100 mg/kg. It<br />

has low fish toxicity. LC 50 (96 h) for<br />

ra<strong>in</strong>bow trout is 510 mg/liter.<br />

Chlomethoxynil (chlometoxyfen).<br />

Chlomethoxynil is used at<br />

1.5-2.5 kg ai/ha <strong>in</strong> transplanted and<br />

upland rice. It is applied 3-8 d after<br />

transplant<strong>in</strong>g rice.<br />

Water solubility is 0.3 mg/liter at<br />

15 °C. LD 50 for mice is 3,300 mg/kg.<br />

LC 50 (40 h) for carp is 237 mg/liter.<br />

C<strong>in</strong>methyl<strong>in</strong>. C<strong>in</strong>methyl<strong>in</strong> provides<br />

excellent c<strong>on</strong>trol of grasses and<br />

moderate suppressi<strong>on</strong> of broadleaf<br />

weeds and sedges. It has been tested at<br />

100-200 g ai/ha for transplanted rice<br />

4-9 d after transplant<strong>in</strong>g and at<br />

100 g ai/ha for direct seeded rice<br />

7-9 d after seed<strong>in</strong>g.<br />

Water solubility is 61 mg/liter.<br />

LD 50 is 3,900 mg/kg.<br />

Oxadiaz<strong>on</strong>. Oxadiaz<strong>on</strong> is a preemergence<br />

herbicide applied at<br />

0.5-0.75 kg ai/ha. Uptake by weed<br />

seedl<strong>in</strong>g shoots causes plant death<br />

because root uptake is low. Its<br />

postemergence activity aga<strong>in</strong>st grasses<br />

is limited. Because it has low water<br />

solubility and high adsorpti<strong>on</strong>,<br />

oxadiaz<strong>on</strong> is not leached and has good<br />

persistence. It can be used <strong>in</strong> transplanted<br />

and direct seeded rice.<br />

Commercial mixed formulati<strong>on</strong>s<br />

<strong>in</strong>clude oxadiaz<strong>on</strong> + 2,4-D and<br />

oxadiaz<strong>on</strong> + propanil.<br />

Oxadiaz<strong>on</strong> can be specifically<br />

formulated to be applied directly <strong>on</strong>to<br />

the surface of the ricefield floodwater.<br />

A shaker bottle with a calibrated<br />

stopper is used to spread oxadiaz<strong>on</strong><br />

directly <strong>on</strong>to the water without any<br />

diluti<strong>on</strong>. The field should be flooded<br />

3-5 cm at applicati<strong>on</strong> and water should<br />

not be disturbed for 2-5 d after<br />

applicati<strong>on</strong>.<br />

Water solubility is 0.7 mg/liter at<br />

20 °C. LD 50 for rats is more than<br />

8,000 mg/kg. LC 50 (96 h) for ra<strong>in</strong>bow<br />

trout is 1-9 mg/liter; for catfish,<br />

³15.4 mg/liter.<br />

Piperophos. Piperophos is a<br />

piperid<strong>in</strong>e compound used as a<br />

preemergence and postemergence<br />

herbicide. It c<strong>on</strong>trols annual grasses<br />

and sedges. The commercial product<br />

c<strong>on</strong>ta<strong>in</strong><strong>in</strong>g piperophos + dimethame-<br />

tryn <strong>in</strong> the ratio 4:l is used <strong>in</strong> rice to<br />

c<strong>on</strong>trol most annual weeds. It is<br />

applied at 1-2 kg ai/ha at the 2- to<br />

4-leaf stage of weed. It has good selec-<br />

tivity <strong>in</strong> transplanted and upland rice.<br />

Pr<strong>in</strong>cipal herbicides 71

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