My PhD dissertation - Institut Fresnel

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VII Literature References 115 Compounds Index 125 Curriculum Vitae 129
Page 1: Various Facets of Organophosphorus
Page 5: III Remerciements Je tiens à remer
Page 9: 3.3.6 Relevance of the Data Assesse
Page 15: VIII Abstract Organophosphorus comp
Page 19: General Part
Page 22 and 23: 2 However, this statement clearly p
Page 24 and 25: 4 However, the mechanism proposed a
Page 26 and 27: 6 The second part of this work sets
Page 29 and 30: 2 Preparation of Tertiary Phosphine
Page 31 and 32: 11 Table 1. Preparation of variousl
Page 33 and 34: 13 variously substituted furans in
Page 35 and 36: 15 unfortunately revealed the prese
Page 37: 17 and gave only the mono-chlorinat
Page 40 and 41: 20 organic molecules have been dete
Page 42 and 43: 3.3 Assessment of the Relative Ease
Page 44 and 45: 24 on the leaving alkyl group durin
Page 46 and 47: 26 the reacting phosphonium salt (R
Page 48 and 49: 28 Furthermore, the intensities of
Page 50 and 51: R P N R 24a - 24d 30 HCl / DEE 4.8
Page 52 and 53: 32 Table 5. Trialkylphosphine oxide
Page 54 and 55: 34 Primary alkyl substituents were
Page 56 and 57: 3.3.6 Relevance of the Data Assesse
Page 58 and 59: 38 Only one study on alkaline decom
Page 60 and 61: 4.1 Preparation of Enantiomerically
Page 62 and 63:
42 trace of organic byproducts, as
Page 64 and 65:
44 bulk of the O-substituents. Thus
Page 66 and 67:
4.2.2 Racemate Resolution of 6,6’
Page 68 and 69:
48 Another advantage of the synthet
Page 70 and 71:
50 At first, bis(phenol ether) 7 wa
Page 72 and 73:
52 A single-crystal X-ray analysis
Page 74 and 75:
4.4.1 The Use of Variable-Temperatu
Page 76 and 77:
T > Tc T = Tc T < Tc T
Page 78 and 79:
58 ≠ -1 torsional barrier at that
Page 80 and 81:
60 each in the coplanar transition
Page 82 and 83:
62 48. This experimental result cou
Page 85 and 86:
65 5 Conclusions and Outlook Severa
Page 87:
67 If the ratio of the products for
Page 91 and 92:
1 Generalities 69 Commercial starti
Page 93 and 94:
2 The Preparation of Phosphines fro
Page 95 and 96:
73 MS: 412 (5%, M + ), 301 (44%), 1
Page 97 and 98:
75 allowed to reach ambient tempera
Page 99 and 100:
31 P NMR (acetone-d6) : δ = - 73.1
Page 101 and 102:
79 (-)-N-{1-[(1S)-Phenylethyl]pyrro
Page 103 and 104:
3 The Alkaline Decomposition of Qua
Page 105 and 106:
83 13 C NMR: δ = 43.8 (d, J = 14 H
Page 107 and 108:
85 1 H NMR: δ = 0.97 (d, J = 6.1 H
Page 109 and 110:
87 Dibutyl-tert-butylphosphine (26e
Page 111 and 112:
89 C16H31P (254.39) calcd. C 75.54%
Page 113 and 114:
91 1 H NMR: δ = 1.7 (m, 6 H), 1.5
Page 115 and 116:
93 1 H NMR: δ = 1.7 (m, 4 H), 1.6
Page 117 and 118:
95 hexanes (15 mL) and the reaction
Page 119 and 120:
97 Theoretical ratio: (50.3:49.7) E
Page 121:
99 To illustrate the experimental m
Page 124 and 125:
102 was added and the phases were s
Page 126 and 127:
104 (+)-(M)-2,2’-Dibromo-6,6’-b
Page 128 and 129:
106 13 C NMR (DMSO-d6): δ = 167.2,
Page 130 and 131:
108 (R)-(-)-MTPA ester from (-)-(P)
Page 132 and 133:
110 1 H NMR (acetone-d6): δ = 7.3
Page 134 and 135:
112 13 C NMR (acetone-d6): δ = 133
Page 136 and 137:
114 4.5 Seclected Crystallographic
Page 139 and 140:
Literature References 115 [ 1] G.H.
Page 141 and 142:
117 [ 44] R.S. Berry, J. Chem. Phys
Page 143 and 144:
119 [ 93] A. Köllhofer, H. Plenio,
Page 145 and 146:
121 [143] R. Hulst, R.W.J. Zijlstra
Page 147 and 148:
123 [192] W.R. Moser, C.J. Papile,
Page 150:
PCl 25d: p.26, 27, 72 C 2H 6ClP PCl
Page 154:
Br COOH Br COOH 37: p. 35, 39, 40 4
Page 158:
Curriculum Vitae
Page 162:
130 Publication F. Leroux, M. Mauri
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