My PhD dissertation - Institut Fresnel

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"Penserions nous beaucoup et penserions nous bien si nous ne pensions pas en commun avec d'autres qui nous font part de leurs pensées et auxquels nous communiquons les nôtres ?" E. Kant
Page 1: Various Facets of Organophosphorus
Page 7: IV TABLE OF CONTENTS Abstract VIII
Page 11: Experimental Part VI 1 Generalities
Page 15: VIII Abstract Organophosphorus comp
Page 19: General Part
Page 22 and 23: 2 However, this statement clearly p
Page 24 and 25: 4 However, the mechanism proposed a
Page 26 and 27: 6 The second part of this work sets
Page 29 and 30: 2 Preparation of Tertiary Phosphine
Page 31 and 32: 11 Table 1. Preparation of variousl
Page 33 and 34: 13 variously substituted furans in
Page 35 and 36: 15 unfortunately revealed the prese
Page 37: 17 and gave only the mono-chlorinat
Page 40 and 41: 20 organic molecules have been dete
Page 42 and 43: 3.3 Assessment of the Relative Ease
Page 44 and 45: 24 on the leaving alkyl group durin
Page 46 and 47: 26 the reacting phosphonium salt (R
Page 48 and 49: 28 Furthermore, the intensities of
Page 50 and 51: R P N R 24a - 24d 30 HCl / DEE 4.8
Page 52 and 53:
32 Table 5. Trialkylphosphine oxide
Page 54 and 55:
34 Primary alkyl substituents were
Page 56 and 57:
3.3.6 Relevance of the Data Assesse
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38 Only one study on alkaline decom
Page 60 and 61:
4.1 Preparation of Enantiomerically
Page 62 and 63:
42 trace of organic byproducts, as
Page 64 and 65:
44 bulk of the O-substituents. Thus
Page 66 and 67:
4.2.2 Racemate Resolution of 6,6’
Page 68 and 69:
48 Another advantage of the synthet
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50 At first, bis(phenol ether) 7 wa
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52 A single-crystal X-ray analysis
Page 74 and 75:
4.4.1 The Use of Variable-Temperatu
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T > Tc T = Tc T < Tc T
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58 ≠ -1 torsional barrier at that
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60 each in the coplanar transition
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62 48. This experimental result cou
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65 5 Conclusions and Outlook Severa
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67 If the ratio of the products for
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1 Generalities 69 Commercial starti
Page 93 and 94:
2 The Preparation of Phosphines fro
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73 MS: 412 (5%, M + ), 301 (44%), 1
Page 97 and 98:
75 allowed to reach ambient tempera
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31 P NMR (acetone-d6) : δ = - 73.1
Page 101 and 102:
79 (-)-N-{1-[(1S)-Phenylethyl]pyrro
Page 103 and 104:
3 The Alkaline Decomposition of Qua
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83 13 C NMR: δ = 43.8 (d, J = 14 H
Page 107 and 108:
85 1 H NMR: δ = 0.97 (d, J = 6.1 H
Page 109 and 110:
87 Dibutyl-tert-butylphosphine (26e
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89 C16H31P (254.39) calcd. C 75.54%
Page 113 and 114:
91 1 H NMR: δ = 1.7 (m, 6 H), 1.5
Page 115 and 116:
93 1 H NMR: δ = 1.7 (m, 4 H), 1.6
Page 117 and 118:
95 hexanes (15 mL) and the reaction
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97 Theoretical ratio: (50.3:49.7) E
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99 To illustrate the experimental m
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102 was added and the phases were s
Page 126 and 127:
104 (+)-(M)-2,2’-Dibromo-6,6’-b
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106 13 C NMR (DMSO-d6): δ = 167.2,
Page 130 and 131:
108 (R)-(-)-MTPA ester from (-)-(P)
Page 132 and 133:
110 1 H NMR (acetone-d6): δ = 7.3
Page 134 and 135:
112 13 C NMR (acetone-d6): δ = 133
Page 136 and 137:
114 4.5 Seclected Crystallographic
Page 139 and 140:
Literature References 115 [ 1] G.H.
Page 141 and 142:
117 [ 44] R.S. Berry, J. Chem. Phys
Page 143 and 144:
119 [ 93] A. Köllhofer, H. Plenio,
Page 145 and 146:
121 [143] R. Hulst, R.W.J. Zijlstra
Page 147 and 148:
123 [192] W.R. Moser, C.J. Papile,
Page 150:
PCl 25d: p.26, 27, 72 C 2H 6ClP PCl
Page 154:
Br COOH Br COOH 37: p. 35, 39, 40 4
Page 158:
Curriculum Vitae
Page 162:
130 Publication F. Leroux, M. Mauri
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