10.04.2013 Views

Geologic Studies in Alaska by the U.S. Geological Survey, 1992

Geologic Studies in Alaska by the U.S. Geological Survey, 1992

Geologic Studies in Alaska by the U.S. Geological Survey, 1992

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

196 GEOLOGIC STUDIES IN ALASKA BY THE U.S. GEOLOGICAL SURVEY, <strong>1992</strong><br />

There is also <strong>the</strong> question of <strong>the</strong> potassic metasoma-<br />

tism that has affected both HM and CM rock samples and<br />

which is characteristic of molybdenite deposits <strong>in</strong> general.<br />

The fact that potassic fluids can carry considerable molyb-<br />

denum is likely a part of <strong>the</strong> explanation. Additional fac-<br />

tors seem to be required to expla<strong>in</strong> <strong>the</strong> general co-location<br />

of <strong>the</strong> metasomatism and <strong>the</strong> molybdenite. These factors<br />

may relate to <strong>the</strong> total volume available of enriched fluid<br />

or to rapid crystallization ow<strong>in</strong>g to <strong>the</strong> steepness of gradi-<br />

ents <strong>in</strong> <strong>in</strong>tensive or extensive variables with<strong>in</strong> a con-<br />

stra<strong>in</strong>ed structural sett<strong>in</strong>g. Crystallization of any extensive<br />

portion of a fluid as molybdenite or as o<strong>the</strong>r m<strong>in</strong>erals<br />

might itself be a factor ow<strong>in</strong>g to a consequent <strong>in</strong>crease <strong>in</strong><br />

volatile content <strong>in</strong> <strong>the</strong> rema<strong>in</strong><strong>in</strong>g fluid. The SEM results<br />

that were reported above for <strong>the</strong> potassic phase occurr<strong>in</strong>g<br />

on <strong>the</strong> natural fracture surface permit <strong>the</strong> additional specu-<br />

lation that molybdenum might be transported as a potassic<br />

complex (for example, a K-Fe-Mo complex). If this were<br />

<strong>the</strong> case, <strong>the</strong>n deposition of molybdenite would also free<br />

potassium; such released potassium might be responsible<br />

for <strong>the</strong> potassic metasomatism <strong>in</strong> <strong>the</strong> immediate deposi-<br />

tional environment of <strong>the</strong> molybdenite.<br />

Acknowledgments.-Jim Barker (Interior Develop-<br />

ment, Fairbanks) provided field guidance <strong>in</strong> 1991 to rare-<br />

earth localities <strong>in</strong> <strong>the</strong> Dora Bay area. Dave Taylor<br />

provided field assistance <strong>in</strong> <strong>1992</strong> as a U.S. <strong>Geologic</strong>al Sur-<br />

vey volunteer. Gary McWilliams capta<strong>in</strong>ed <strong>the</strong> research<br />

vessel HYAK and also made m<strong>in</strong>eralogic contributions to<br />

<strong>the</strong> <strong>in</strong>vestigation. The X-ray diffraction confirmation of<br />

scapolite was made <strong>by</strong> Daniel Webster. Short order<br />

chemical analyses were provided <strong>by</strong> M.W. Doughten, P.H.<br />

Briggs, D.L. Fey, J.S. Mee, and D.F. Siems.<br />

REFERENCES CITED<br />

Barker, J.C., and Mardock, Cheryl, 1990, Rare-earth element-<br />

and yttrium-bear<strong>in</strong>g pegmatite dikes near Dora Bay, south-<br />

em Pr<strong>in</strong>ce of Wales Island: U.S. Bureau of M<strong>in</strong>es Open-<br />

File Report 19-90, 41 p.<br />

Brew, D.A., Drew, L.J., Schmidt, J.M., Root, D.H., and Huber,<br />

D.F., 1991, Undiscovered locatable m<strong>in</strong>eral resources of <strong>the</strong><br />

Tongass National Forest and adjacent lands, sou<strong>the</strong>astern<br />

<strong>Alaska</strong>: U.S. <strong>Geologic</strong>al <strong>Survey</strong> Open-File Report 91-10,<br />

370 p., 26 maps.<br />

Candella, P.A., and Holland, H.D., 1986, A mass transfer model<br />

for copper and molybdenum <strong>in</strong> magmatic hydro<strong>the</strong>rmal sys-<br />

tems: <strong>the</strong> orig<strong>in</strong> of porphyry-type ore deposits: Economic<br />

Geology, v. 81, p. 1-18.<br />

Cox, D.P., and S<strong>in</strong>ger, D.A., 1986, M<strong>in</strong>eral deposit models: U.S.<br />

<strong>Geologic</strong>al <strong>Survey</strong> Bullet<strong>in</strong> 1693, 379 p.<br />

Eberle<strong>in</strong>, G.D., Churk<strong>in</strong>, Michael, Jr., Carter, Claire, Berg, H.C.,<br />

and Ovensh<strong>in</strong>e, A.T., 1983, Geology of <strong>the</strong> Craig quad-<br />

rangle, <strong>Alaska</strong>: U.S. <strong>Geologic</strong>al <strong>Survey</strong> Open-File Report<br />

83-91, 30 p., scale 1 :250,000.<br />

Gehrels, G.E., and Berg, H.C., 1984, <strong>Geologic</strong> map of sou<strong>the</strong>ast-<br />

em <strong>Alaska</strong>: U.S. <strong>Geologic</strong>al <strong>Survey</strong> Open-File Report 84-<br />

886, 28 p., scale 1:600,000.<br />

Herreid, Gordon, Bundtzen, T.K., and Turner, D.L., 1978, Geol-<br />

ogy and geochemistry of <strong>the</strong> Craig A-2 quadrangle and vi-<br />

c<strong>in</strong>ity, Pr<strong>in</strong>ce of Wales Island, sou<strong>the</strong>astern <strong>Alaska</strong>: <strong>Alaska</strong><br />

Department of Natural Resources, Division of <strong>Geologic</strong>al<br />

and Geophysical <strong>Survey</strong>s, <strong>Geologic</strong> Report 48, 49 p., 2<br />

maps, scale 1:40,000.<br />

Isuk, E.E., 1976, Solubility of molybdenite <strong>in</strong> <strong>the</strong> system Na20-<br />

K20-Si02-MoS2-H20-C02 with geologic application:<br />

Ames, University of Iowa, Ph.D. <strong>the</strong>sis, 101 p.<br />

Smith, J.V., 1983, Some chemical properties of feldspars, <strong>in</strong><br />

Ribbe, P.H., ed., Feldspar m<strong>in</strong>eralogy: M<strong>in</strong>eralogical Soci-<br />

ety of America, p. 281-296.<br />

U.S. Department of Agriculture, Forest Service, 1991, Tongass<br />

National Forest Land Management Plan Map, scale<br />

1 :760,320.<br />

White, W.H., Bookstrom, A.A., Kamilli, R.J., Ganster, M.W.,<br />

Smith, R.P., Ranta, D.E., and Ste<strong>in</strong><strong>in</strong>ger, R.C., 1981, Char-<br />

acter and orig<strong>in</strong> of Climax-type molybdenum deposits: Eco-<br />

nomic Geology, 75th Anniversary Volume, p. 270-316.<br />

Reviewers: Bruce R. Doe, Karen D. Kelley, and Holly J. Ste<strong>in</strong>.

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!