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Nitrification inhibitor dicyandiamide (DCD) 31<br />

A methodology to incorporate the N 2 O mitigation technology, the nitrification<br />

inhibitor dicyandiamide (DCD) into the Agriculture sector of the Inventory has been<br />

developed. A detailed description of the methodology can be found in Clough et al<br />

(2008). The N 2 O emissions reported in the Agricultural soils category take into account<br />

the use of nitrification inhibitors on dairy farms using the methodology described in<br />

Clough et al (2008).<br />

Dicyandiamide has been well researched and the research to date has shown that it<br />

reduces N 2 O emissions and nitrate leaching in pastoral grassland systems grazed by<br />

ruminant animals. There have been over 28 peer-reviewed and published New Zealand<br />

studies on its use and effects.<br />

The method to incorporate inhibitor mitigation of N 2 O emissions into New Zealand’s<br />

Agriculture Inventory is by an amendment to the existing IPCC methodology. Activity<br />

data on livestock numbers is drawn from Statistics New Zealand’s Agricultural<br />

Production survey. This survey has recently included questions on the area that DCD was<br />

applied on grazed pastures.<br />

The inhibitor is applied to pastures based on research that has identified good<br />

management practice to maximise N 2 O emission reductions. This is at a rate of<br />

10 kilograms per hectare, applied twice per year in autumn and early spring within seven<br />

days of the application of animal excreta. ‘Good practice’ application methods of DCD<br />

can be by slurry or DCD-coated granule.<br />

Changes to the emission factors EF 3PR&P and parameter Frac LEACH were established<br />

through research (table 5.5.4). These emission factors and parameters were modified<br />

based on comprehensive field-based research that showed significant reductions in direct<br />

and indirect N 2 O emissions and nitrate leaching where the DCD was applied. The peerreviewed<br />

literature on inhibitor use in grazed pasture systems was reviewed and it was<br />

determined that, on a national basis, reductions in EF 3PR&P and Frac LEACH of, 67 per cent<br />

and 53 per cent could be made respectively (Clough et al, 2008). There has been some<br />

research into the effect of the inhibitor on EF 3(PR&P DUNG) , however, these data are limited<br />

and further work needs to be carried out before incorporating this research into the<br />

New Zealand Inventory.<br />

The reductions in the emission factors and parameters are used along with the fraction of<br />

dairy land treated with the inhibitor to calculate DCD weighting factors.<br />

1 % <br />

100<br />

<br />

∙<br />

<br />

The appropriate weighting factor is then used as an additional multiplier in the current<br />

methodology for calculating indirect and direct emissions of N 2 O from grazed pastures.<br />

The calculations use a modified EF 3(PR&P) of 0.0099 and Frac LEACH of 0.0696 for dairy<br />

grazing area in the months that the inhibitor is applied (May to September). The modified<br />

emission factors (table 5.5.7) are based on information from the Agricultural Production<br />

census that 2.9 per cent of the effective dairying area in New Zealand received inhibitor<br />

in 2012.<br />

Mitigation estimates for calendar years 2007 to 2012 are shown in table 5.5.7.<br />

Application of this inhibitor was found to have no effect on ammonia volatilisation during<br />

May to September when it is applied. This is supported by the results of field studies<br />

(Clough et al, 2008; Sherlock et al, 2008).<br />

31<br />

After 2012, there was a voluntary suspension of DCD sales in New Zealand, so no mitigation<br />

estimates are reported for <strong>2013</strong>.<br />

174 New Zealand’s Greenhouse Gas Inventory <strong>1990</strong>–<strong>2013</strong>

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