CESIUM41Events, Trends, <strong>and</strong> Issues: Domestic cesium occurrences will remain uneconomic unless market conditionschange, such as the discovery of new end uses or increased consumption for existing end uses. Commercially usefulquantities of inexpensive cesium are available as a byproduct of the production of lithium. Increases in lithiumexploration are expected to yield discoveries of additional cesium resources, which may lead to exp<strong>and</strong>ed commercialapplications. There are no known human health issues associated with cesium, <strong>and</strong> its use has minimalenvironmental impact.Cesium’s cost <strong>and</strong> reactivity limit its viability in many applications; however, its use in cesium formate brines <strong>and</strong>nuclear medicine is showing steady growth. Cesium formate drilling operations are being undertaken in the TharDesert in Pakistan, in the North Sea off the coast of Norway, <strong>and</strong> in Argentina. In addition to its use in drilling fluid,cesium formate brine is used as a fast-acting liquid pill for releasing drill pipes differentially stuck in oil-based mud(OBM) filter cakes. The pill of formate brine rapidly destroys the OBM filter cake <strong>and</strong> allows the pipe to be jarred free.The International Atomic <strong>Energy</strong> Agency has indicated that cesium-137 is one of several radioactive materials thatmay be used in radiological dispersion devices or “dirty bombs.” Cesium-137 is now regulated in the United States bythe U.S. Nuclear Regulatory Commission (NRC) <strong>and</strong> the <strong>Environmental</strong> Protection Agency (EPA). The NRC monitorsdevices containing cesium-137, requiring material holders to obtain specific licenses for these devices. The EPAplaces a maximum allowance of cesium-137 that can be released into the air by nuclear facilities <strong>and</strong> requires thecleanup of contaminated soil <strong>and</strong> groundwater. The NRC agreed to encourage research into finding <strong>and</strong>implementing alternatives, but deemed that a near-term replacement was not practical <strong>and</strong> would be detrimental tocurrent emergency medical capabilities.World Mine Production <strong>and</strong> Reserves: Pollucite, mainly formed in association with lithium-rich, lepidolite-bearing orpetalite-bearing zoned granite pegmatites, is the principal cesium ore mineral. Cesium reserves are thereforeestimated based on the occurrence of pollucite, which is mined as a byproduct of the lithium mineral lepidolite. Mostpollucite contains 5% to 32% Cs 2 O. Data on cesium resources <strong>and</strong> mine production are either limited or not available.The main pollucite zone at Bernic Lake in Canada contains approximately 400,000 metric tons of pollucite with anaverage Cs 2 O content of 24%, <strong>and</strong> a secondary zone of approximately 100,000 metric tons of pollucite contains anaverage of 5% Cs 2 O. The next largest occurrence that may become economic is in Zimbabwe.Reserves 1Canada 70,000,000Other countriesNAWorld total (rounded) 70,000,000World Resources: World resources of cesium have not been estimated. Cesium is associated with lithium-bearingpegmatites worldwide, <strong>and</strong> cesium resources have been identified in Namibia <strong>and</strong> Zimbabwe. Smaller concentrationsare also known in brines in Chile <strong>and</strong> China <strong>and</strong> in geothermal systems in Germany, India, <strong>and</strong> Tibet.Substitutes: Cesium <strong>and</strong> rubidium can be used interchangeably in many applications because they have similarphysical properties <strong>and</strong> atomic radii. Cesium, however, is more electropositive than rubidium, making it a preferredmaterial in many applications.NA Not available.1 See Appendix C for resource/reserve definitions <strong>and</strong> information concerning data sources.U.S. Geological Survey, <strong>Mineral</strong> <strong>Commodity</strong> <strong>Summaries</strong>, January <strong>2011</strong>
42CHROMIUM(Data in thous<strong>and</strong> metric tons gross weight unless otherwise noted)Domestic Production <strong>and</strong> Use: In 2010, the United States was expected to consume about 2% of world chromiteore production in various forms of imported materials, such as chromite ore, chromium chemicals, chromiumferroalloys, chromium metal, <strong>and</strong> stainless steel. One U.S. company mined chromite ore in Oregon. Importedchromite was consumed by one chemical firm to produce chromium chemicals. One company produced chromiummetal. Stainless- <strong>and</strong> heat-resisting-steel producers were the leading consumers of ferrochromium. Superalloysrequire chromium. The value of chromium material consumption in 2009 was $358 million as measured by the valueof net imports, excluding stainless steel, <strong>and</strong> was expected to be about $420 million in 2010.Salient Statistics—United States: 1 2006 2007 2008 2009 2010 eProduction:Mine — — — — —Recycling 2 179 162 146 141 160Imports for consumption 520 485 559 273 400Exports 212 291 287 280 200Government stockpile releases 103 137 11 25 1Consumption:Reported (includes recycling) 437 442 401 376 400Apparent 3 (includes recycling) 589 493 432 159 360Unit value, average annual import (dollars per metric ton):Chromite ore (gross mass) 141 156 227 227 230Ferrochromium (chromium content) 1,290 1,951 3,728 2,085 2,400Chromium metal (gross mass) 8,181 8,331 11,078 9,896 10,000Stocks, yearend, held by U.S consumers 10 10 7 7 5Net import reliance 4 as a percentage of apparentconsumption 70 67 66 12 56Recycling: In 2010, recycled chromium (contained in reported stainless steel scrap receipts) accounted for 44% ofapparent consumption.Import Sources (2006–09): Chromium contained in chromite ore, chromium ferroalloys <strong>and</strong> metal, <strong>and</strong> stainlesssteel mill products <strong>and</strong> scrap: South Africa, 33%; Kazakhstan, 16%; Russia, 9%; China, 6%; <strong>and</strong> other, 36%.Tariff: 5 Item Number Normal Trade Relations12-31-10Ore <strong>and</strong> concentrate 2610.00.0000 Free.Ferrochromium:Carbon more than 4% 7202.41.0000 1.9% ad val.Carbon more than 3% 7202.49.1000 1.9% ad val.Other:Carbon more than 0.5% 7202.49.5010 3.1% ad val.Other 7202.49.5090 3.1% ad val.Ferrochromium silicon 7202.50.0000 10% ad val.Chromium metal:Unwrought, powder 8112.21.0000 3% ad val.Waste <strong>and</strong> scrap 8112.22.0000 Free.Other 8112.29.0000 3% ad val.Depletion Allowance: 6 22% (Domestic), 14% (Foreign).Government Stockpile: In fiscal year (FY) 2010, which ended on September 30, 2010, the Defense LogisticsAgency, DLA Strategic Materials (formerly the Defense National Stockpile Center), reported disposals of 25,819 tonsof high-carbon ferrochromium, 9,405 tons of low-carbon ferrochromium, <strong>and</strong> 151 tons of chromium metal. Disposalsin the following table are estimated as the change in DLA Strategic Materials’ reported current year minus previousyear physical inventory, with adjustments for accounting changes when appropriate. Metallurgical-grade chromite ore<strong>and</strong> ferrochromium silicon stocks were exhausted in FY 2002; chemical- <strong>and</strong> refractory-grade chromite ore stockswere exhausted in FY 2004. The DLA Strategic Materials announced that maximum disposal limits for FY <strong>2011</strong> hadnot been approved.Prepared by John F. Papp [(703) 648-4963, jpapp@usgs.gov, fax: (703) 648-7757]
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LEAD91caused by underground fires a
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LIME93The lime industry is facing p
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LITHIUM95market, and a facility at
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MAGNESIUM COMPOUNDS97In Australia,
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MAGNESIUM METAL99U.S. magnesium con
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MANGANESE101Government Stockpile:St
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MERCURY103Events, Trends, and Issue
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MICA (NATURAL)105Depletion Allowanc
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MOLYBDENUM107Events, Trends, and Is
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NICKEL109Nickel prices were adverse
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NIOBIUM (COLUMBIUM)111Events, Trend
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NITROGEN (FIXED)—AMMONIA113Accord
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PEAT115Events, Trends, and Issues:
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PERLITE117Events, Trends, and Issue
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PHOSPHATE ROCK119Events, Trends, an
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PLATINUM-GROUP METALS121Events, Tre
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POTASH123Events, Trends, and Issues
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PUMICE AND PUMICITE125Events, Trend
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RARE EARTHS129Events, Trends, and I
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RHENIUM131Events, Trends, and Issue
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RUBIDIUM133Events, Trends, and Issu
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SALT135Many chefs have advocated us
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SAND AND GRAVEL (CONSTRUCTION)137Ev
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SAND AND GRAVEL (INDUSTRIAL)139The
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SCANDIUM141Scandium’s use in meta
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SELENIUM143Events, Trends, and Issu
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SILICON145Events, Trends, and Issue
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SODA ASH149A Wyoming soda ash produ
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SODIUM SULFATE151Events, Trends, an
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STONE (CRUSHED)153Events, Trends, a
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STONE (DIMENSION)155Events, Trends,
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STRONTIUM157Events, Trends, and Iss
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SULFUR159World sulfur production in
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TALC AND PYROPHYLLITE161Events, Tre
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TANTALUM163Events, Trends, and Issu
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TELLURIUM165Events, Trends, and Iss
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THALLIUM167Beginning in 2009, there
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170TIN(Data in metric tons of tin c
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172TITANIUM AND TITANIUM DIOXIDE 1(
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174TITANIUM MINERAL CONCENTRATES 1(
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176TUNGSTEN(Data in metric tons of
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178VANADIUM(Data in metric tons of
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180VERMICULITE(Data in thousand met
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182WOLLASTONITE(Data in metric tons
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184YTTRIUM 1(Data in metric tons of
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186ZEOLITES (NATURAL)(Data in metri
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188ZINC(Data in thousand metric ton
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190ZIRCONIUM AND HAFNIUM(Data in me
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192APPENDIX AAbbreviations and Unit
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194Demonstrated.—A term for the s
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196Part B—Sources of Reserves Dat
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198Europe and Central Eurasia—con