INDIUM75China’s 21 indium producers were allowed to export a combined total of 93 tons of indium in the latter half of 2010,compared with 140 tons during the first half of the year. Most of this material was exported to Japan for consumption.In the downstream market, dem<strong>and</strong> for ITO targets increased during the first half of 2010 from that of the second halfof 2009 owing to a rise in LCD panel production. However, LCD panel inventories began to increase during thesecond half of 2010 owing to lower-than-expected LCD sales in the United States <strong>and</strong> global economic uncertainty.One LCD panel producer initiated a 30% production cut at one of its Japanese plants to control inventory. As a resultof weakening LCD dem<strong>and</strong> that occurred in the latter half of 2010, LCD panel producers lowered prices, resulting inan aggressive price competition among flat-screen LCD TV producers. However, ITO producers were not able tosignificantly lower their prices as higher indium prices in 2010 cut into profits.World Refinery Production <strong>and</strong> Reserves:Refinery production Reserves 62009 2010 eUnited States — — Quantitative estimates of reserves are notBelgium 30 30 available.Brazil 5 5Canada 40 35China 280 300Japan 67 70Korea, Republic of 70 80Peru 25 25Russia 4 4Other countries 2525World total (rounded) 546 574World Resources: Indium’s abundance in the continental crust is estimated to be approximately 0.05 part per million.Trace amounts of indium occur in base metal sulfides—particularly chalcopyrite, sphalerite, <strong>and</strong> stannite—by ionicsubstitution. Indium is most commonly recovered from the zinc-sulfide ore mineral sphalerite. The average indiumcontent of zinc deposits from which it is recovered ranges from less than 1 part per million to 100 parts per million.Although the geochemical properties of indium are such that it occurs with other base metals—copper, lead, <strong>and</strong> tin—<strong>and</strong> to a lesser extent with bismuth, cadmium, <strong>and</strong> silver, most deposits of these metals are subeconomic for indium.Vein stockwork deposits of tin <strong>and</strong> tungsten host the highest known concentrations of indium. However, the indiumfrom this type of deposit is usually difficult to process economically. Other major geologic hosts for indiummineralization include volcanic-hosted massive sulfide deposits, sediment-hosted exhalative massive sulfide deposits,polymetallic vein-type deposits, epithermal deposits, active magmatic systems, porphyry copper deposits, <strong>and</strong> skarndeposits.Substitutes: Indium’s recent price volatility <strong>and</strong> various supply concerns associated with the metal have acceleratedthe development of ITO substitutes. Antimony tin oxide coatings, which are deposited by an ink-jetting process, havebeen developed as an alternative to ITO coatings in LCDs <strong>and</strong> have been successfully annealed to LCD glass.Carbon nanotube coatings, applied by wet-processing techniques, have been developed as an alternative to ITOcoatings in flexible displays, solar cells, <strong>and</strong> touch screens. Poly(3,4-ethylene dioxythiophene) (PEDOT) has alsobeen developed as a substitute for ITO in flexible displays <strong>and</strong> organic light-emitting diodes. PEDOT can be applied ina variety of ways, including spin coating, dip coating, <strong>and</strong> printing techniques. Graphene quantum dots have beendeveloped to replace ITO electrodes in solar cells <strong>and</strong> also have been explored as a replacement for ITO in LCDs.Researchers have recently developed a more adhesive zinc oxide nanopowder to replace ITO in LCDs. Thetechnology was estimated to be commercially available within the next 3 years. Gallium arsenide can substitute forindium phosphide in solar cells <strong>and</strong> in many semiconductor applications. Hafnium can replace indium in nuclearreactor control rod alloys.e Estimated. NA Not available. — Zero.1 Imports for consumption of unwrought indium <strong>and</strong> indium powders (Tariff no. 8112.92.3000).2 Indium Corp.’s price for 99.97% purity metal; 1-kilogram bar in lots of 10,000 troy ounces. Source: Platts Metals Week.3 Price is based on 99.99% minimum purity indium at warehouse (Rotterdam); cost, insurance, <strong>and</strong> freight (in minimum lots of 50 kilograms).Source: Platts Metals Week.4 Price is based on 99.99% purity indium, primary or secondary, shipped to Japan. Source: Platts Metals Week.5 Defined as imports – exports + adjustments for Government <strong>and</strong> industry stock changes; exports were assumed to be no greater than thedifference between imports <strong>and</strong> consumption.6 See Appendix C for resource/reserve definitions <strong>and</strong> information concerning data sources.U.S. Geological Survey, <strong>Mineral</strong> <strong>Commodity</strong> <strong>Summaries</strong>, January <strong>2011</strong>
76IODINE(Data in metric tons elemental iodine unless otherwise noted)Domestic Production <strong>and</strong> Use: Iodine was produced in 2010 by three companies operating in Oklahoma, with afourth company initializing iodine production in Montana in March 2010. Domestic iodine production decreasedslightly in 2009 compared with that of 2008, owing to the economic downturn. Production in 2010 was estimated toincrease from that of 2009. To avoid disclosing company proprietary data, U.S. iodine production in 2010 waswithheld. The operation at Woodward, OK, continued production of iodine from subterranean brines. Anothercompany continued production at Vici, OK. Prices for iodine have increased in recent years owing to high dem<strong>and</strong>,which has led to high capacity utilization. The average c.i.f. value of iodine imports in 2010 was estimated to be$24.18 per kilogram.Domestic <strong>and</strong> imported iodine were used by downstream manufacturers to produce many intermediate iodinecompounds, making it difficult to establish an accurate end-use pattern. Of the consumers that participate in anannual U.S. Geological Survey canvass, 17 plants reported consumption of iodine in 2009. Iodine <strong>and</strong> iodinecompounds reported were unspecified organic compounds, including ethyl <strong>and</strong> methyl iodide, 51%; potassium iodide,11%; crude iodine, 11%; povidine-iodine (iodophors), 7%; ethylenediamine dihydroiodide, 5%; sodium iodide, 4%;<strong>and</strong> other, 11%.Salient Statistics—United States: 2006 2007 2008 2009 2010 eProduction W W W W WImports for consumption, crude content 5,640 6,060 6,300 5,190 5,200Exports 1,580 1,060 950 1,160 1,000Shipments from Government stockpile excesses 467 93 — — —Consumption:Apparent W W W W WReported 4,570 4,470 4,590 4,550 4,800Price, average c.i.f. value, dollars per kilogram,crude 19.34 21.01 21.52 25.55 24Employment, number e 30 30 30 30 30Net import reliance 1 as a percentageof reported consumption 89 100 100 89 88Recycling: Small amounts of iodine were recycled, but no data were reported.Import Sources (2006–09): Chile, 82%; Japan, 17%; <strong>and</strong> other, 1%.Tariff: Item Number Normal Trade Relations12-31-10Iodine, crude 2801.20.0000 Free.Iodide, calcium or copper 2827.60.1000 Free.Iodide, potassium 2827.60.2000 2.8% ad val.Iodides <strong>and</strong> iodide oxides, other 2827.60.5100 4.2% ad val.Depletion Allowance: 14% (Domestic <strong>and</strong> foreign).Government Stockpile: None.Prepared by Marc A. Angulo [(703) 648-7945, mangulo@usgs.gov, fax: (703) 648-7757]
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U.S. Department of the InteriorKEN
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INTRODUCTION3Each chapter of the 20
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5NET EXPORTS OF MINERALRAW MATERIAL
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SIGNIFICANT EVENTS, TRENDS, AND ISS
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mineral materials valued at $1.30 b
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11MAJOR METAL-PRODUCING AREASAuB2P1
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13MAJOR INDUSTRIAL MINERAL-PRODUCIN
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ABRASIVES (MANUFACTURED)15Events, T
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ALUMINUM17The United States continu
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ANTIMONY19Events, Trends, and Issue
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ARSENIC21According to university me
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ASBESTOS23Events, Trends, and Issue
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- Page 46 and 47: CHROMIUM43Stockpile Status—9-30-1
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- Page 52 and 53: COPPER49Events, Trends, and Issues:
- Page 54 and 55: DIAMOND (INDUSTRIAL)51Events, Trend
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- Page 58 and 59: FELDSPAR55Feldspar use in tile and
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PUMICE AND PUMICITE125Events, Trend
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QUARTZ CRYSTAL (INDUSTRIAL)127Event
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RARE EARTHS129Events, Trends, and I
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RHENIUM131Events, Trends, and Issue
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RUBIDIUM133Events, Trends, and Issu
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SALT135Many chefs have advocated us
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SAND AND GRAVEL (CONSTRUCTION)137Ev
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SAND AND GRAVEL (INDUSTRIAL)139The
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SCANDIUM141Scandium’s use in meta
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SELENIUM143Events, Trends, and Issu
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SILICON145Events, Trends, and Issue
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SILVER147Silver was used as a repla
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SODA ASH149A Wyoming soda ash produ
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SODIUM SULFATE151Events, Trends, an
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STONE (CRUSHED)153Events, Trends, a
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STONE (DIMENSION)155Events, Trends,
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STRONTIUM157Events, Trends, and Iss
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SULFUR159World sulfur production in
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TALC AND PYROPHYLLITE161Events, Tre
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TANTALUM163Events, Trends, and Issu
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TELLURIUM165Events, Trends, and Iss
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THALLIUM167Beginning in 2009, there
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170TIN(Data in metric tons of tin c
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172TITANIUM AND TITANIUM DIOXIDE 1(
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174TITANIUM MINERAL CONCENTRATES 1(
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176TUNGSTEN(Data in metric tons of
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178VANADIUM(Data in metric tons of
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180VERMICULITE(Data in thousand met
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182WOLLASTONITE(Data in metric tons
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184YTTRIUM 1(Data in metric tons of
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186ZEOLITES (NATURAL)(Data in metri
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188ZINC(Data in thousand metric ton
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190ZIRCONIUM AND HAFNIUM(Data in me
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192APPENDIX AAbbreviations and Unit
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194Demonstrated.—A term for the s
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196Part B—Sources of Reserves Dat
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198Europe and Central Eurasia—con