LIME93The lime industry is facing possible future regulation of carbon dioxide emissions after the U.S. <strong>Environmental</strong> Agency(EPA) published findings that greenhouse gas emissions (GHG), including carbon dioxide, threaten the public health<strong>and</strong> welfare of current <strong>and</strong> future generations. These “endangerment” findings allow the EPA to require that anymodification to a stationary source that increases GHG emissions above the significance threshold would need to gothrough “prevention of significant deterioration” (PSD) review <strong>and</strong> install the “best available control technology.” In2010, the EPA published its “PSD <strong>and</strong> title V greenhouse gas tailoring rule” to establish the applicability criteria thatdetermine which stationary sources <strong>and</strong> modification projects become subject to permitting requirements for GHGemissions. The tailoring rule is designed to phase in regulation of GHG emissions from stationary sources bytemporarily increasing the amount of GHG emissions that would trigger PSD, so that tens of thous<strong>and</strong>s of sources arenot immediately swept into the PSD program.World Lime Production <strong>and</strong> Limestone Reserves:Production Reserves 42009 2010 eUnited States 15,800 18,000 Adequate for allAustralia 2,000 2,200 countries listed.Belgium 2,000 2,000Brazil 7,450 7,700Canada 1,600 1,800China 185,000 190,000France 3,500 3,700Germany 6,000 6,800India 13,000 14,000Iran 2,700 2,800Italy 5 6,000 6,400Japan (quicklime only) 8,400 9,400Korea, Republic of 3,600 4,000Mexico 5,500 5,700Pol<strong>and</strong> 1,950 2,000Romania 2,000 2,200Russia 7,000 7,400South Africa (sales) 1,380 1,400Spain 2,000 2,200Turkey (sales) 3,800 4,000United Kingdom 1,500 1,600Vietnam 1,700 1,800Other countries 15,500 16,000World total (rounded) 299,000 310,000World Resources: Domestic <strong>and</strong> world resources of limestone <strong>and</strong> dolomite suitable for lime manufacture areadequate.Substitutes: Limestone is a substitute for lime in many applications, such as agriculture, fluxing, <strong>and</strong> sulfur removal.Limestone, which contains less reactive material, is slower to react <strong>and</strong> may have other disadvantages compared withlime, depending on the application; however, limestone is considerably less expensive than lime. Calcined gypsum isan alternative material in industrial plasters <strong>and</strong> mortars. Cement, cement kiln dust, fly ash, <strong>and</strong> lime kiln dust arepotential substitutes for some construction uses of lime. Magnesium hydroxide is a substitute for lime in pH control,<strong>and</strong> magnesium oxide is a substitute for dolomitic lime as a flux in steelmaking.e Estimated. NA Not available.1 Data are for quicklime, hydrated lime, <strong>and</strong> refractory dead-burned dolomite. Includes Puerto Rico.2 Sold or used by producers.3 Defined as imports – exports + adjustments for Government <strong>and</strong> industry stock changes; stock changes are assumed to be zero for apparentconsumption <strong>and</strong> net import reliance calculations.4 See Appendix C for resource/reserve definitions <strong>and</strong> information concerning data sources.5 Includes hydraulic lime.U.S. Geological Survey, <strong>Mineral</strong> <strong>Commodity</strong> <strong>Summaries</strong>, January <strong>2011</strong>
94LITHIUM(Data in metric tons of lithium content unless otherwise noted)Domestic Production <strong>and</strong> Use: Chile was the leading lithium chemical producer in the world; Argentina, China, <strong>and</strong>the United States also were major producers. Australia <strong>and</strong> Zimbabwe were major producers of lithium oreconcentrates. The United States remained the leading importer of lithium minerals <strong>and</strong> compounds <strong>and</strong> the leadingproducer of value-added lithium materials. Because only one company produced lithium compounds from domesticresources, reported production <strong>and</strong> value of production were withheld from publication to avoid disclosing companyproprietary data. Estimation of value for the lithium mineral compounds produced in the United States is extremelydifficult because of the large number of compounds used in a wide variety of end uses <strong>and</strong> the great variability of theprices for the different compounds. Two companies produced a large array of downstream lithium compounds in theUnited States from domestic or South American lithium carbonate. A U.S. recycling company produced a smallquantity of lithium carbonate from solutions recovered during the recycling of lithium-ion batteries.Although lithium markets vary by location, global end-use markets are estimated as follows: ceramics <strong>and</strong> glass, 31%;batteries, 23%; lubricating greases, 9%; air treatment, 6%; primary aluminum production, 6%; continuous casting, 4%;rubber <strong>and</strong> thermoplastics, 4%; pharmaceuticals, 2%; <strong>and</strong> other uses, 15%. Lithium use in batteries exp<strong>and</strong>edsignificantly in recent years because rechargeable lithium batteries were being used increasingly in portableelectronic devices <strong>and</strong> electrical tools.Salient Statistics—United States: 2006 2007 2008 2009 2010 eProduction W W W W WImports for consumption 3,260 3,140 3,160 1,890 2,000Exports 1,500 1,440 1,450 920 1,600Consumption:Apparent W W W W WEstimated 2,500 2,400 2,300 1,300 1,000Employment, mine <strong>and</strong> mill, number 61 68 68 68 68Net import reliance 1 as a percentage ofapparent consumption >50% >50% >50% >50% 43%Recycling: Recycled lithium content has been historically insignificant, but has increased steadily owing to the growthin consumption of lithium batteries. One U.S. company has recycled lithium metal <strong>and</strong> lithium-ion batteries since 1992at its Canadian facility in British Columbia. In 2009, the U.S. Department of <strong>Energy</strong> awarded the company $9.5 millionto construct the first U.S. recycling facility for lithium-ion batteries.Import Sources (2006–09): Chile, 59%; Argentina, 38%; China, 1%; <strong>and</strong> other, 2%.Tariff: Item Number Normal Trade Relations12-31-10Other alkali metals 2805.19.9000 5.5% ad val.Lithium oxide <strong>and</strong> hydroxide 2825.20.0000 3.7% ad val.Lithium carbonate:U.S.P. grade 2836.91.0010 3.7% ad val.Other 2836.91.0050 3.7% ad val.Depletion Allowance: 22% (Domestic), 14% (Foreign).Government Stockpile: None.Events, Trends, <strong>and</strong> Issues: Market conditions improved for lithium-based products in 2010. Sales volumes for themajor lithium producers were reported to be up more than 30% by mid-2010. Consumption by lithium end-usemarkets for batteries, ceramics <strong>and</strong> glass, grease, <strong>and</strong> other industrial applications all increased. The leading lithiumproducer in Chile lowered its lithium prices by 20% in 2010. Many new companies continued exploring for lithium onclaims worldwide. Numerous claims in Nevada, as well as Argentina, Australia, Bolivia, <strong>and</strong> Canada, have beenleased or staked.The only active lithium carbonate plant in the United States was a brine operation in Nevada. Subsurface brines havebecome the dominant raw material for lithium carbonate production worldwide because of lower production costscompared with the mining <strong>and</strong> processing costs for hard-rock ores. Two brine operations in Chile dominate the worldPrepared by Brian W. Jaskula [(703) 648-4908, bjaskula@usgs.gov, fax: (703) 648-7757]
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U.S. Department of the InteriorKEN
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INTRODUCTION3Each chapter of the 20
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5NET EXPORTS OF MINERALRAW MATERIAL
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SIGNIFICANT EVENTS, TRENDS, AND ISS
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mineral materials valued at $1.30 b
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11MAJOR METAL-PRODUCING AREASAuB2P1
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13MAJOR INDUSTRIAL MINERAL-PRODUCIN
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ABRASIVES (MANUFACTURED)15Events, T
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ALUMINUM17The United States continu
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ANTIMONY19Events, Trends, and Issue
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ARSENIC21According to university me
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ASBESTOS23Events, Trends, and Issue
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BARITE25Nationally, the rig count o
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BAUXITE AND ALUMINA27Events, Trends
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BERYLLIUM29Events, Trends, and Issu
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BISMUTH31Events, Trends, and Issues
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BORON33Events, Trends, and Issues:
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BROMINE35Events, Trends, and Issues
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CADMIUM37NiCd battery use in consum
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CEMENT39The manufacture of clinker
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CESIUM41Events, Trends, and Issues:
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SELENIUM143Events, Trends, and Issu
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SILICON145Events, Trends, and Issue
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SILVER147Silver was used as a repla
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SODA ASH149A Wyoming soda ash produ
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SODIUM SULFATE151Events, Trends, an
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STONE (CRUSHED)153Events, Trends, a
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STONE (DIMENSION)155Events, Trends,
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STRONTIUM157Events, Trends, and Iss
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SULFUR159World sulfur production in
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TALC AND PYROPHYLLITE161Events, Tre
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TANTALUM163Events, Trends, and Issu
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TELLURIUM165Events, Trends, and Iss
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THALLIUM167Beginning in 2009, there
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170TIN(Data in metric tons of tin c
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172TITANIUM AND TITANIUM DIOXIDE 1(
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174TITANIUM MINERAL CONCENTRATES 1(
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176TUNGSTEN(Data in metric tons of
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178VANADIUM(Data in metric tons of
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180VERMICULITE(Data in thousand met
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182WOLLASTONITE(Data in metric tons
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184YTTRIUM 1(Data in metric tons of
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186ZEOLITES (NATURAL)(Data in metri
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188ZINC(Data in thousand metric ton
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190ZIRCONIUM AND HAFNIUM(Data in me
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192APPENDIX AAbbreviations and Unit
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194Demonstrated.—A term for the s
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196Part B—Sources of Reserves Dat
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198Europe and Central Eurasia—con