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XXVI ANNUAL REPORT GOA UNIVERSITY

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Major Thrust Areas of Research and Achievements<br />

JAED – Structural, optical and transport properties of various oxide glasses, hydrogels,<br />

polymer solutions and porous materials have been examined by X-Ray and Neutron<br />

Diffraction, Ultra- and Small Angle Neutron Scattering, UV-visible and FTIR spectroscopy,<br />

rheology, porosimetry, DSC, DTA and other methods.<br />

US – Preparation of wide band gap materials including nano materials and their<br />

characterization using XRD, SEM, TEM, XPS are done. Luminescence, optical<br />

absorption,dielectric and electrical conductivity properties are studied.<br />

RBT- Extensive work is being carried out in nanomaterials. The work includes:<br />

(i) Preparation of various types of nanomagnetic materials like Mn-Zn , Ni-Zn, Co-Zn<br />

spinel ferrites, more complex materials like hexa-ferrites using innovative chemical<br />

techniques.<br />

(ii) Preparation of metallic nanoparticles using microbes.<br />

(iii) Structure, grain size and magnetic Characterization, using modern techniques via<br />

XRD, EDS, TEM, SPM, SEM, Mossbauer, VSM, SQUID, Neutron Diffraction etc.<br />

(iv) Study of electrical transport properties in nanoparticles and bulk material made<br />

from nanoparticles.<br />

(v) Studies on Genotoxicity of Magentic nanoparticles (mnps) in Mammalian Cells.<br />

In the process of this investigations the department could successfully develop<br />

magnetic nanoparticles exhibiting superparamagnetism at room temperature.<br />

RVP – Analysis of various quantum phases of ultracold bosonic atoms in a periodic onedimensional<br />

optical superlattice. Studies have been performed using the finite-size<br />

density-matrix renormalization group method in the framework of the Bose-Hubbard<br />

model. Calculations have been carried out for a wide range of densities and the energy<br />

shifts due to the superlattice potential. At commensurate fillings, we find the Mott<br />

insulator and the superfluid phases as well as Mott insulators induced by the superlattice.<br />

At a particular incommensurate density, the system is found to be in the superfluid phase<br />

coexisting with density oscillations for a certain range of parameters of the system.<br />

KRP - Efforts have been made to understand (a) magneto-structural coupling in Shape<br />

memory alloys (b) the complex magnetic ordering observed in Double Perovskites (c)<br />

Catalytic and ionic conductivity in ceria based compounds and (d) mechanism of long<br />

lasting luminescence in biomarkers. EXAFS, XAS and XMCD are being deployed as main<br />

techniques. Experience gained on understanding Shape memory alloys will be extended<br />

to other materials like Antiperovskites and Fe based Superconductors.<br />

Visiting Scholars<br />

• A. V. Rao, Shivaji University, Kolhapur, Aerogels and Applications, 31 st March,<br />

2011.<br />

• K. Narasimha Rao, I.I.Sc., Bangalore, Thin Films Preparation and Characterization,<br />

31 st March, 2011.<br />

• Alok Banerjee, UGC-DAE Consortium for Scientific Research, Indore, Phase<br />

Coexistence and Functionality in Materials of Current Interest, 31 st March, 2011.<br />

• V. M. Kenkre, Distinguished Professor of Physics, University of New Mexico, USA,<br />

Theory of Abrupt Transitions in Biological/Ecological Systems: Interplay of<br />

Nonlinearity and Inhomogeneity, 22 nd December, 2010.<br />

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