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BIOENERGY FOR EUROPE: WHICH ONES FIT BEST?

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42 3 Life cycle assessment of biofuels: methods and tools<br />

The values for the human toxicity category tend to be rather uncertain. The reason for this is that it<br />

is extremely difficult to obtain reliable input data (emission and characterisation factors) for all toxicity<br />

parameters of relevance. Furthermore, within the scientific community the methodology on the assessment<br />

of toxicity is still being discussed.<br />

3.4.3 Parameters and coefficients used<br />

The different emitted substances can be aggregated by the use of an equivalence factor system according<br />

to the efficiency of the substances with regard to the environmental impact categories. In Table 3-2<br />

the characterisation factors used for the calculations are shown. For the characterisation factors regarding<br />

human toxicological impact potentials see Annex 7.5.<br />

Table 3-2 Characterisation factors for non-toxicological impact potential categories (see text for references).<br />

Substance name Formula<br />

Global warming<br />

potential<br />

(g CO2-eq./g)<br />

100-year 500-year<br />

Acidification<br />

potential<br />

(g SO2-eq./g)<br />

Nutrient enrichment<br />

potential<br />

(g NO3-eq./g)<br />

POCP 4<br />

(g C2H4eq./g)<br />

Ammonia NH3 - - 1.88 3.64 -<br />

Ammonium NH4 + - - - 3.44 -<br />

Benzene C6H6 - - - - 0.2<br />

Carbon monoxide CO 2 2 - - 0.03<br />

Carbon dioxide 1 CO2 1 1 - - -<br />

Hexane<br />

C6H14 - - - - 0.4<br />

Hydrochloric acid HCl - - 0.88 - -<br />

Methane CH4 25 8 - - 0.007<br />

Nitrate NO3 - - - - 1 -<br />

Nitrogen oxide 2<br />

NOx 0.70 1.35 -<br />

Nitrous oxide N2O 320 180<br />

Non-methane vola- NMVOC<br />

- -<br />

tile organic com-<br />

3 3<br />

0.5<br />

pounds 3<br />

Phosphate PO4 3- - - - 10.45 -<br />

Sulphur dioxide SO2 - - 1 -<br />

1<br />

Includes only CO2 of petrochemical origin<br />

2<br />

NOX is calculated as NO2.<br />

3<br />

The NMVOC cover a range of substances, and the present characterisation factors only represent<br />

estimates of average values.<br />

4 Photochemical ozone creation potential<br />

3.4.4 Normalisation – a preparation for interpretation<br />

According to the ISO norm 14040, the impact assessment phase must include the assigning of data to<br />

impact categories (classification) and the modelling of the inventory data within the impact categories<br />

(characterisation). These two steps were described in the Chapters 3.4.2 and 3.4.3.<br />

Further elements, like normalisation, ranking, grouping and weighting, are optional. They are used<br />

to express the results in different ways, which can make the interpretation easier with respect to certain<br />

objectives. While normalisation simply expresses the data using a different reference unit, ranking and<br />

grouping also involve subjective value choices.<br />

There is no specific rule when it makes sense to use normalisation. It is largely a matter of individual<br />

choice and personal preference. In this project, some countries applied normalisation as explained<br />

below. No other optional element has been used.<br />

Normalisation enables the decision maker to assess the environmental impact of a certain fuel regarding<br />

a particular parameter relative to the general environmental situation. Thus the “specific contribution”

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