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Carsten Timm: Theory of superconductivity

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10.5 Ultrasonic attenuation and nuclear relaxation<br />

To conclude the brief survey <strong>of</strong> experimental consequences <strong>of</strong> BCS theory, we discuss the effects <strong>of</strong> time-dependent<br />

perturbations. They will be exemplified by ultrasonic attenuation and nuclear relaxation, which represent two<br />

distinct ways in which quasiparticle interference comes into play. Quite generally, we write the perturbation part<br />

<strong>of</strong> the Hamiltonian as<br />

H 1 = ∑ kk ′ ∑<br />

σσ ′ B k ′ σ ′ kσ c † k ′ σ ′ c kσ , (10.91)<br />

where B k′ σ ′ kσ are matrix elements <strong>of</strong> the perturbation between single-electron states <strong>of</strong> the non-interacting system.<br />

In the superconducting state, we have to express c, c † in terms <strong>of</strong> γ, γ † ,<br />

c k↑ = u k γ k↑ + v k γ † −k,↓ , (10.92)<br />

c k↓ = u k γ k↓ − v k γ † −k,↑ , (10.93)<br />

where we have assumed u −k = u k , v −k = v k . Thus, with σ, σ ′ = ±1,<br />

H 1 = ∑ ∑<br />

) (<br />

)<br />

(u ∗ k ′γ† k ′ σ<br />

+ σ ′ v ∗ ′ k ′γ −k ′ ,−σ ′ u k γ kσ + σv k γ † −k,−σ<br />

kk ′<br />

= ∑ kk ′ ∑<br />

σσ ′ B k′ σ ′ kσ<br />

σσ ′ B k′ σ ′ kσ<br />

(<br />

u ∗ k ′u kγ † k ′ σ ′ γ kσ + σu ∗ k ′v kγ † k ′ σ ′ γ † −k,−σ<br />

+ σ ′ v ∗ k ′u kγ −k′ ,−σ ′γ kσ + σσ ′ v ∗ k ′v kγ −k′ ,−σ ′γ† −k,−σ<br />

)<br />

. (10.94)<br />

It is useful to combine the terms containing B k ′ σ ′ kσ and B −k,−σ,−k ′ ,−σ ′ since both refer to processes that change<br />

momentum by k ′ − k and spin by σ ′ − σ. If the perturbation couples to the electron concentration, which is the<br />

case for ultrasound, one finds simply<br />

B −k,−σ,−k′ ,−σ ′ = B k ′ σ ′ kσ. (10.95)<br />

This is <strong>of</strong>ten called case I. Furthermore, spin is conserved by the coupling to ultrasound, thus<br />

Adding the two terms, we obtain<br />

H ultra = 1 2<br />

∑ ∑<br />

kk ′ σ<br />

B k ′ σkσ<br />

B k′ σ ′ kσ = δ σσ ′ B k′ σkσ. (10.96)<br />

(<br />

u ∗ k ′u kγ † k ′ σ γ kσ + σu ∗ k ′v kγ † k ′ σ γ† −k,−σ<br />

+ σvk ∗ ′u kγ −k′ ,−σγ kσ + vk ∗ ′v kγ −k′ ,−σγ † −k,−σ + u∗ ku k ′γ † −k,−σ γ −k ′ ,−σ<br />

)<br />

− σu ∗ kv k ′γ † −k,−σ γ† k ′ σ − σv∗ ku k ′γ kσ γ −k′ ,−σ + vkv ∗ k ′γ kσ γ † k ′ σ<br />

. (10.97)<br />

Assuming u k , v k , ∆ k ∈ R for simplicity, we get, up to a constant,<br />

H ultra = 1 2<br />

∑ ∑<br />

kk ′ σ<br />

B k′ σkσ<br />

+ σ (u k ′v k + v k ′u k )<br />

[<br />

(<br />

)<br />

(u k ′u k − v k ′v k ) γ † k ′ σ γ kσ + γ † −k,−σ γ −k ′ ,−σ<br />

(γ † k ′ σ γ† −k,−σ + γ −k ′ ,−σγ kσ<br />

)]<br />

. (10.98)<br />

We thus find effective matrix elements B k ′ σkσ(u k ′u k − v k ′v k ) for quasiparticle scattering and B k ′ σkσ σ(u k ′v k +<br />

v k ′u k ) for creation and annihilation <strong>of</strong> two quasiparticles. Transition rates calculated from Fermi’s golden rule<br />

contain the absolute values squared <strong>of</strong> matrix elements. Thus the following two coherence factors will be impor-<br />

102

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