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Carsten Timm: Theory of superconductivity

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we can write the gap matrix in a compact form as<br />

ˆ∆(k) = (∆ k 1 + d(k) · σ) iσ y , (12.63)<br />

where σ is the vector <strong>of</strong> Pauli matrices. The mean-field Hamiltonian H MF is diagonalized by a Bogoliubov<br />

transformation and the gap function ˆ∆(k) is obtained selfconsistently from a gap equation in complete analogy<br />

to the singlet case discussed in Sec. 10.1, except that ˆ∆(k) is now a matrix and that we require four coefficients<br />

u k↑ , u k↓ , v k↑ , v k↓ . We do not show this here explicitly.<br />

A few remarks on the physics are in order, though. The symmetry ˆ∆(−k) = − ˆ∆ T (k) implies<br />

⇒<br />

(∆ −k 1 + d(−k) · σ) iσ y = −i (σ y ) T<br />

} {{ }<br />

(<br />

∆k 1 + d(k) · σ T ) (12.64)<br />

iσ y<br />

∆ −k 1 + d(−k) · σ = σ y ( ∆ k 1 + d(k) · σ T ) σ y<br />

⎛<br />

⎞<br />

= ∆ k 1 + d(k) · ⎝ σy (σ x ) T σ y<br />

σ y (σ y ) T σ y ⎠<br />

⎛<br />

σ y (σ z ) T σ y<br />

⎞<br />

σy σ x σ y<br />

= ∆ k 1 + d(k) · ⎝ −σ y σ y σ y<br />

σ y σ z σ y<br />

⎠<br />

= ∆ k 1 − d(k) · σ. (12.65)<br />

Thus we conclude that ∆ k is even,<br />

whereas d(k) is odd,<br />

∆ −k = ∆ k , (12.66)<br />

d(−k) = −d(k). (12.67)<br />

Hence, the d-vector can never be constant, unlike the single gap in Sec. 10.1. Furthermore, we can expand ∆ k<br />

into even basis functions <strong>of</strong> rotations in real (and k) space,<br />

∆ k = ∆ s ψ s (k) + ∆ dx 2 −y 2<br />

ψ dx 2 −y 2<br />

(k) + ∆ d3z 2 −r 2<br />

ψ d3z 2 −r 2<br />

(k) + ∆ dxy ψ dxy (k) + ∆ dyz ψ dyz (k) + ∆ dzx ψ dzx (k) + . . . ,<br />

(12.68)<br />

and expand (the components <strong>of</strong>) d(k) into odd basis functions,<br />

d(k) = d px ψ px (k) + d py ψ py (k) + d pz ψ pz (k) + . . . (12.69)<br />

For the singlet case we have already considered the basis functions ψ s (k) = 1 for conventional superconductors,<br />

ψ s (k) = cos k x a cos k y a for the pnictides, and ψ dx 2 −y 2<br />

(k) = cos k x a − cos k y a for the cuprates. A typical basis<br />

function for a triplet superconductor would be ψ px = sin k x a. He-3 in the so-called B phase realized at now too<br />

high pressures (see Sec. 2.2) has the d-vector<br />

d(k) = ˆx ψ px (k) + ŷ ψ py (k) + ẑ ψ pz (k), (12.70)<br />

where the basis functions are that standard expressions for p x , p y , and p z orbitals (note that there is no Brillouin<br />

zone since He-3 is a liquid),<br />

√<br />

3<br />

ψ px (k) =<br />

4π sin θ k cos ϕ k , (12.71)<br />

√<br />

3<br />

ψ py (k) =<br />

4π sin θ k sin ϕ k , (12.72)<br />

√<br />

3<br />

ψ pz (k) =<br />

4π cos θ k. (12.73)<br />

This is the so-called Balian-Werthamer state.<br />

134

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