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Carsten Timm: Theory of superconductivity

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T<br />

0<br />

AFM<br />

SC<br />

hole doping x<br />

A glance at typical phase diagrams shows that the undoped cuprates tend to be antiferromagnetic. Weak hole<br />

doping or slightly stronger electron doping destroy the antiferromagnetic order, and at larger doping, <strong>superconductivity</strong><br />

emerges. At even larger doping (the “overdoped” regime), <strong>superconductivity</strong> is again suppressed. Also<br />

in many other unconventional superconductors <strong>superconductivity</strong> is found in the vicinity <strong>of</strong> but rarely coexisting<br />

with magnetic order. This is true for most pnictide and heavy-fermion superconductors. The vicinity <strong>of</strong> a<br />

magnetically ordered phase makes itself felt by strong magnetic fluctuations and strong, but short-range, spin<br />

correlations. These are seen as an enhanced spin susceptibility.<br />

At a magnetic second-order phase transition, the static spin susceptibility χ q diverges at q = Q, where Q is<br />

the ordering vector. It is Q = 0 for ferromagnetic order and Q = (π/a, π/a) for checkerboard (Néel) order on<br />

a square lattice. Even some distance from the transition or at non-zero frequencies ν, the susceptibility χ q (ν)<br />

tends to have a maximum close to Q. Far away from the magnetic phase or at high frequencies this remnant <strong>of</strong><br />

magnetic order becomes small. This discussion suggests that the exchange <strong>of</strong> spin fluctuations, which are strong<br />

close to Q, could provide the attractive interaction needed for Cooper pairing.<br />

The Hubbard model<br />

The two-dimensional, single-band, repulsive Hubbard model is thought (by many experts, not by everyone) to be<br />

the simplest model that captures the main physics <strong>of</strong> the cuprates. The Hamiltonian reads, in real space,<br />

H = − ∑ ijσ<br />

t ij c † iσ c jσ + U ∑ i<br />

c † i↑ c i↑c † i↓ c i↓ (12.18)<br />

with U > 0 and, in momentum space,<br />

H = ∑ kσ<br />

ϵ k c † kσ c kσ + U ∑<br />

c † k+q,↑<br />

N<br />

c† k ′ −q,↓ c k ′ ↓c k↑ . (12.19)<br />

kk ′ q<br />

Also, the undoped cuprate parent compounds have, from simple counting, an odd number <strong>of</strong> electrons per unit<br />

cell. Thus for them the single band must be half-filled, while for doped cuprates it is still close to half filling. The<br />

underlying lattice in real space is a two-dimensional square lattice with each site i corresponding to a Cu + ion.<br />

Cu +<br />

O 2−<br />

The transverse spin susceptibility is defined by<br />

χ +− (q, τ) = − ⟨ T τ S + (q, τ) S − (−q, 0) ⟩ , (12.20)<br />

124

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