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Carsten Timm: Theory of superconductivity

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We find a phase transition at T c , below which a macroscopic fraction <strong>of</strong> the particles occupy the same singleparticle<br />

quantum state. This fraction <strong>of</strong> particles is said to form a condensate. While it is remarkable that<br />

Bose-Einstein condensation happens in a non-interacting gas, the BEC is analogous to the condensate in strongly<br />

interacting superfluid He-4 and, with some added twists, in superfluid He-3 and in superconductors.<br />

We can now use the partition function to derive equations <strong>of</strong> state. As an example, we consider the pressure<br />

p = − ∂ϕ<br />

∂V = + ∂<br />

∂V k BT ln Z = k BT<br />

λ 3 g 5/2(y) (3.35)<br />

(ϕ is the grand-canonical potential). We notice that only the excited states contribute to the pressure. The term<br />

− ln(1 − y) from the ground state drops out since it is volume-independant. This is plausible since particles in<br />

the condensate have vanishing kinetic energy.<br />

For T > T c , we can find y and thus p numerically. For T < T c we may set y = 1 and obtain<br />

Remember that for the classical ideal gas at constant volume we find<br />

p = k BT<br />

λ 3 ζ(5/2) ∝ T 5/2 . (3.36)<br />

p ∝ T. (3.37)<br />

For the BEC, the pressure drops more rapidly since more and more particles condense and thus no longer<br />

contribute to the pressure.<br />

17

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