Carsten Timm: Theory of superconductivity
Carsten Timm: Theory of superconductivity
Carsten Timm: Theory of superconductivity
You also want an ePaper? Increase the reach of your titles
YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.
We find a phase transition at T c , below which a macroscopic fraction <strong>of</strong> the particles occupy the same singleparticle<br />
quantum state. This fraction <strong>of</strong> particles is said to form a condensate. While it is remarkable that<br />
Bose-Einstein condensation happens in a non-interacting gas, the BEC is analogous to the condensate in strongly<br />
interacting superfluid He-4 and, with some added twists, in superfluid He-3 and in superconductors.<br />
We can now use the partition function to derive equations <strong>of</strong> state. As an example, we consider the pressure<br />
p = − ∂ϕ<br />
∂V = + ∂<br />
∂V k BT ln Z = k BT<br />
λ 3 g 5/2(y) (3.35)<br />
(ϕ is the grand-canonical potential). We notice that only the excited states contribute to the pressure. The term<br />
− ln(1 − y) from the ground state drops out since it is volume-independant. This is plausible since particles in<br />
the condensate have vanishing kinetic energy.<br />
For T > T c , we can find y and thus p numerically. For T < T c we may set y = 1 and obtain<br />
Remember that for the classical ideal gas at constant volume we find<br />
p = k BT<br />
λ 3 ζ(5/2) ∝ T 5/2 . (3.36)<br />
p ∝ T. (3.37)<br />
For the BEC, the pressure drops more rapidly since more and more particles condense and thus no longer<br />
contribute to the pressure.<br />
17